公开(公告)号：US20150018207A1

公开(公告)日：2015-01-15

申请号：US14383731

申请日：2013-03-11

Applicant: BASF SE

Inventor： Torsten Knieriem ,  Tiziana Chiodo ,  Christopher Koradin ,  Tanja Weber ,  Walter Weishaar

IPC: A01N53/00 ,  A01N25/08

CPC classification number: A01N53/00 ,  A01N25/08 ,  A01N43/90 ,  A01N25/04 ,  A01N2300/00

Abstract: The present invention relates to a method for producing an aqueous suspension concentrate formulation and novel suspension concentrate formulations of the compound of formula I. The method comprises: a) providing an aqueous slurry of coarse particles of the compound of the formula I, where the compound of the formula I is at least partially present in its crystalline form B, which, in an X-ray powder diffractogram at 25° C. and Cu-Kα radiation, shows at least three, preferably at least four, in particular at least 5 or at least 7 or at least 9 or all of the following reflexes, given as 2θ values: 8.0±0.2°, 9.5±0.2°, 10.7±0.2°, 11.0±0.2°, 11.2±0.2°, 11.7±0.2°, 14.2±0.2°, 15.6±0.2°, 16.5±0.2°, 17.7±0.2°, 21.5±0.2°; b) comminuting the coarse particles in the slurry of the compound of formula I, which is at least partially present in its form B, in the presence of the at least one surfactant.

Abstract translation: 本发明涉及一种制备水性悬浮液浓缩物制剂的方法和式I化合物的新型悬浮浓缩物制剂。该方法包括：a）提供式I化合物的粗颗粒的含水浆液，其中化合物 式I的至少一部分至少部分以其结晶形式B存在，其在25℃的X射线粉末衍射图和Cu-Kα辐射中显示出至少三个，优选至少四个，特别是至少5个 或至少7个或至少9个或全部以下反射，以2＆ 值：8.0±0.2°，9.5±0.2°，10.7±0.2°，11.0±0.2°，11.2±0.2°，11.7±0.2°，14.2±0.2°，15.6±0.2°，16.5±0.2°，17.7±0.2 °，21.5±0.2°; b）在存在至少一种表面活性剂的情况下粉碎至少部分以其B形式存在的式I化合物的浆料中的粗颗粒。

公开(公告)号：US09861104B2

公开(公告)日：2018-01-09

申请号：US14383731

申请日：2013-03-11

Applicant: BASF SE

Inventor： Torsten Knieriem ,  Tiziana Chiodo ,  Christopher Koradin ,  Tanja Weber ,  Walter Weishaar

IPC: A01N53/00 ,  A01N25/08 ,  A01N43/90

CPC classification number: A01N53/00 ,  A01N25/08 ,  A01N43/90 ,  A01N25/04 ,  A01N2300/00

Abstract: The present invention relates to a method for producing an aqueous suspension concentrate formulation and novel suspension concentrate formulations of the compound of formula I. The method comprises: a) providing an aqueous slurry of coarse particles of the compound of the formula I, where the compound of the formula I is at least partially present in its crystalline form B, which, in an X-ray powder diffractogram at 25° C. and Cu-Kα radiation, shows at least three, preferably at least four, in particular at least 5 or at least 7 or at least 9 or all of the following reflexes, given as 2θ values: 8.0±0.2°, 9.5±0.2°, 10.7±0.2°, 11.0±0.2°, 11.2±0.2°, 11.7±0.2°, 14.2±0.2°, 15.6±0.2°, 16.5±0.2°, 17.7±0.2°, 21.5±0.2°; b) comminuting the coarse particles in the slurry of the compound of formula I, which is at least partially present in its form B, in the presence of the at least one surfactant.

公开(公告)号：US09980481B2

公开(公告)日：2018-05-29

申请号：US14389970

申请日：2013-03-27

Applicant: BASF SE

Inventor： Torsten Knieriem ,  Klaus Kolb ,  Payam Michael Miraki Ardestani

IPC: A01N25/12 ,  A01N37/38 ,  A01N37/42 ,  A01N43/84

CPC classification number: A01N25/12 ,  A01N37/38 ,  A01N37/42 ,  A01N43/84 ,  A01N25/04

Abstract: The present invention relates to a method for preparing granules comprising the steps of A) preparing an adjuvanted slurry by milling an aqueous composition Al containing a pesticide and a silica absorbent to yield a pesticidal slurry, and adding an adjuvant to the pesticidal slurry; and B) granulating the adjuvanted slurry, wherein the granulation comprises a fluidized bed granulation or sprouted bed granulation. It further relates to granules obtainable be said method comprising 1 to 30 wt % of the pesticide, 10 to 35 wt % of the adjuvant, 8 to 30 wt % of the silica absorbent, and wherein the weight ratio of the silica gel to the adjuvant is from 2/1 to 1/3,5, and finally to a method for controlling phytopathogenic fungi and/or undesired plant growth and/or undesired attack by insects or mites and/or for regulating the growth of plants, where the granules obtainable by said method are allowed to act on the particular pests, their habitat or the plants to be protected from the particular pest, the soil and/or on undesired plants and/or the useful plants and/or their habitat.

公开(公告)号：US20150080217A1

公开(公告)日：2015-03-19

申请号：US14389970

申请日：2013-03-27

Applicant: BASF SE

Inventor： Torsten Knieriem ,  Klaus Kolb ,  Payam Michael Miraki Ardestani

IPC: A01N25/12 ,  A01N37/42 ,  A01N43/84

CPC classification number: A01N25/12 ,  A01N37/38 ,  A01N37/42 ,  A01N43/84 ,  A01N25/04

Abstract: The present invention relates to a method for preparing granules comprising the steps of A) preparing an adjuvanted slurry by milling an aqueous composition Al containing a pesticide and a silica absorbent to yield a pesticidal slurry, and adding an adjuvant to the pesticidal slurry; and B) granulating the adjuvanted slurry, wherein the granulation comprises a fluidized bed granulation or sprouted bed granulation. It further relates to granules obtainable be said method comprising 1 to 30 wt % of the pesticide, 10 to 35 wt % of the adjuvant, 8 to 30 wt % of the silica absorbent, and wherein the weight ratio of the silica gel to the adjuvant is from 2/1 to 1/3,5, and finally to a method for controlling phytopathogenic fungi and/or undesired plant growth and/or undesired attack by insects or mites and/or for regulating the growth of plants, where the granules obtainable by said method are allowed to act on the particular pests, their habitat or the plants to be protected from the particular pest, the soil and/or on undesired plants and/or the useful plants and/or their habitat.

Abstract translation: 本发明涉及一种制备颗粒的方法，包括以下步骤：A）通过研磨含有农药和二氧化硅吸收剂的含水组合物A1制备佐剂浆料，得到杀虫剂浆液，并向杀虫剂中加入佐剂; 和B）对佐剂化的浆料进行造粒，其中造粒包括流化床造粒或发芽床制粒。 所述方法还涉及所述方法，所述方法包括1至30wt％的农药，10至35wt％的助剂，8至30wt％的二氧化硅吸收剂，并且其中硅胶与佐剂的重量比 是从2/1至1 / 3,5，最后是一种用于控制植物病原真菌和/或不期望的植物生长和/或不期望的昆虫或螨攻击和/或用于调节植物生长的方法，其中颗粒可获得 允许通过所述方法对特定害虫，其栖息地或植物进行保护以免受特定害虫，土壤和/或不期望的植物和/或有用植物和/或其栖息地的影响。