公开(公告)号：US10556801B2

公开(公告)日：2020-02-11

申请号：US15549905

申请日：2016-02-11

Applicant: BASF SE

Inventor： Mathias Feyen ,  Stefan Maurer ,  Ulrich Mueller ,  Xinhe Bao ,  Weiping Zhang ,  Dirk de Vos ,  Hermann Gies ,  Feng-Shou Xiao ,  Yokoi Toshiyuki ,  Bilge Yilmaz ,  Ryoichi Otomo

IPC: C01B39/46 ,  B01J29/70 ,  C01B39/02 ,  C07C1/20

Abstract: The present invention relates to a method for the preparation of a treated zeolitic material having a BEA framework structure including the steps of: (i) providing a zeolitic material having a BEA framework structure, wherein the BEA framework structure includes YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, and wherein the zeolitic material having a BEA framework structure is obtainable and/or obtained from an organotemplate-free synthetic process; (ii) calcining the zeolitic material provided in step (i) at a temperature of 650° C. or more; and (iii) treating the calcined zeolitic material obtained from step (ii) with an aqueous solution having a pH of 5 or less, as well as to zeolitic materials per se preferably obtainable according to the inventive method and to their use, and to a process for converting oxygenates to olefins employing the inventive zeolitic materials.

公开(公告)号：US20180022611A1

公开(公告)日：2018-01-25

申请号：US15549905

申请日：2016-02-11

Applicant: BASF SE

Inventor： Mathias Feyen ,  Stefan Maurer ,  Ulrich Mueller ,  Xinhe Bao ,  Weiping Zhang ,  Dirk de Vos ,  Hermann Gies ,  Feng-Shou Xiao ,  Yokoi Toshiyuki ,  Bilge Yilmaz ,  Ryoichi Otomo

IPC: C01B39/02 ,  B01J29/70 ,  C07C1/20 ,  C01B39/46

Abstract: The present invention relates to a method for the preparation of a treated zeolitic material having a BEA framework structure comprising the steps of: (i) providing a zeolitic material having a BEA framework structure, wherein the BEA framework structure comprises YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, and wherein the zeolitic material having a BEA framework structure is obtainable and/or obtained from an organotemplate-free synthetic process; (ii) calcining the zeolitic material provided in step (i) at a temperature of 650° C. or more; and (iii) treating the calcined zeolitic material obtained from step (ii) with an aqueous solution having a pH of 5 or less, as well as to zeolitic materials per se preferably obtainable according to the inventive method and to their use, and to a process for converting oxygenates to olefins employing the inventive zeolitic materials.