-
1.发明授权Organo - polysiloxane compositions convertible into elastomers at room temperature 失效有机 - 多晶硅组合物可在室温下转化成弹性体
公开(公告)号：US3560442A
公开(公告)日：1971-02-02
申请号：US3560442D
申请日：1968-10-01
Applicant: BAYER AG
Inventor： GOLITZ HANS DIETRICH , SCHWABE PETER , SIMMLER WALTER
CPC classification number: C08L83/04 , C08G77/16 , Y10S528/901 , C08L2666/44
Abstract: NOVEL CROSS-LINKING AGENTS ARE DISCLOSED WHICH CAN BE COMBINED WITH PLASTICALLY SHAPABLE ORGANO-POLYSILOXANES; THE RESULTING NOVEL MIXTURES OR COMPOSITIONS BEING STORAGE STABLE UNDER EXCLUSION OF ALL MOISTURE. THE CROSSLINKING REACTION TAKES PLACE ON EXPOSURE OF THE COMPOSITIONS TO WATER, ATMOSPHERIC HUMIDITY SUFFICING, AT TEMPERATAURES BELOW 50*C. THE COMPOSITIONS ARE ESPECIALLY ADAPTED TO BE USED FOR THE FILLING OF JOINTS AND AS SEALING MATERIALS IN THE BUILDING INDUSTRY. THE ELASTOMERS RESULTING THEREFROM HAVE AN INCREASED ADHESION TO THE SUBSTRATE SAVING THE EXPENDITURE OF PRIMING. THE NOVEL COMPOSITIONS COMPRISE: (A) AN A,W-DIHYDROXY-POLY-(DIMETHYL-SILOXANE) WHICH, IN ADDITION TO ITS DIORGANO-SILOXANE UNITS, MAY CONTAIN UP TO 10 MOL-PERCENT OF SILOXANE UNITS HAVING THE FORMULA CH3SIO3/2, AND MAY BE ADMIXED WITH FILLERS AND AN A,W-BIS-(TRIMETHYL-SILOXY) - POLY - (DIMETHYL-SILOXANE); AND (B) A CROSS-LINKING AGENT HAVING THE FORMULA
(RO-)3SI-CH(R'')-N(R")-R''"
IN WHICH R IS AN ALKYL RADICAL WITH 1 TO 4 CARBON ATOMS; R'' IS A HYDROGEN ATOM, AN ALKYL RADICAL WITH 1 TO 6 CARBON ATOMS OR A PHENYL RADICAL; R" IS A HYDROGEN ATOM OR A METHYL RADICAL; AND R''" IS A HYDROGEN ATOM, AN ALKYL, CYCLOALKYL, AMINOALKYL, (METHYLAMINO)-ALKYL OR (DIMETHYLAMINO)-ALKYL RADICAL WITH 1 TO 6 CARBON ATOMS IN ITS ALKYL GROUP, OR A RADICAL HAVING THE FORMULA (RO-)3SICH(R'')-OR THE FORMULA
(RO-)3SI-CH(R'')-N(R")-CH2CH-
公开(公告)号：US3676478A
公开(公告)日：1972-07-11
申请号：US3676478D
申请日：1969-11-26
Applicant: BAYER AG
Inventor： GOLITZ HANS DIETRICH , DEGENER EBERHART , OERTEL GUNTER , SCHMELZER HANS-GEORG , SIMMLER WALTER
CPC classification number: C08G77/26 , C07F7/182 , C08G18/10 , Y10S516/07 , C08G18/289
Abstract: New organosilyl- and carbamate-modified urea derivatives have the formula IN WHICH R and R'' are monovalent hydrocarbon radicals, R'''' and R'''''' are hydrogen atoms or monovalent hydrocarbon radicals, Q'' is a bivalent hydrocarbon radical, Q is a monovalent to hexavalent hydrocarbon radical, a is 0, 1, 2 or 3, n is 2, 3 or 4, b is zero or an integer from 1 to 200, and c is the valency number of Q. These urea derivatives are prepared by reacting at a temperature of from -20* to 150* C an aminoalkyl-silane derivative of the formula WITH AN ISOCYANATE-MODIFIED CARBAMIC ACID ESTER OF THE FORMULA The products are to be used as priming agents imparting adhesion to synthetic resins on siliceous surfaces, as surfactants and as intermediates for organo-polysiloxane resins.
Abstract translation: 新的有机甲硅烷基和氨基甲酸酯改性的脲衍生物具有下式：其中R和R'是一价烃基，R“和R”'是氢原子或一价烃基，Q'是二价烃基，Q是 一价至六价烃基，a为0,1,2或3，n为2,3或4，b为0或1〜200的整数，c为Q的化合价数。
-
公开(公告)号：US3673233A
公开(公告)日：1972-06-27
申请号：US3673233D
申请日：1969-12-02
Applicant: BAYER AG
Inventor： GOLITZ HANS DIETRICH , SIMMLER WALTER
IPC: C07F7/18
CPC classification number: C07F7/182 , Y10S516/07
Abstract: New organosilyl-modified carbamic acid esters have the formula IN WHICH R, R'' and R'''''' are monovalent hydrocarbon radicals, R'''' is a hydrogen atom a methyl radical or a phenyl radical, Q is a monovalent to hexavalent hydrocarbon radical having up to 6 carbon atoms, a is 0, 1, 2 or 3, n is 2, 3 or 4, b is zero or an integer from 1 to 200, and c is the valency number of Q. These carbamic acid derivates are prepared by reacting at a temperature of from 20* to 150* C., an aminomethyl-silane derivative of the formula WITH A CHLOROFORMIC ACID ESTER OF THE FORMULA IN THE PRESENCE OF A TERTIARY AMINE. The products are to be used as priming agents imparting adhesion to synthetic resins on siliceous surfaces, as surfactants and as intermediates for organo-polysiloxane resins.
Abstract translation: 新的有机甲硅烷基改性的氨基甲酸酯具有下式：其中R，R'和R“'是一价烃基，R”是氢原子，甲基或苯基，Q是一价至六价烃基， 最多6个碳原子，a为0,1,2或3，n为2,3或4，b为0或1至200的整数，c为Q的化合价数。
-
公开(公告)号：US3663586A
公开(公告)日：1972-05-16
申请号：US3663586D
申请日：1970-10-16
Applicant: BAYER AG
Inventor： GOLITZ HANS DIETRICH , MERTEN RUDOLF , NOLL WALTER , SIMMLER WALTER
CPC classification number: C08G77/28 , C07F7/10 , C07F7/1868 , C08L83/04 , C08L2666/44
Abstract: NOVEL CYCLIC THIOUREA DERIVATIVES CONTAINING SILICON ATOMS HAVE THE GENERAL FORMULA
WHEREIN R IS A HYDROCARBON RADICAL OPTIONALLY BEING INTERRUPTED BY OXYGEN ATOMS IN ETHER LINKAGES, R'' AND R" (SAME OR DIFFERENT) ARE HYDROCARBON RADICALS, HALOHYDROCARBON RADICALS, CYANOHYDROCARBON RADICALS, OR ALKOXY RADICALS, AND R''" IS A HYDROCARBON RADICAL. THE COMPOUNDS ARE USEFUL AS CROSS-LINKING AGENTS AND AS INTERMEDOATES FOR CARBOFUNCTIONAL SILOXANES. THESE 2,5-DIAZA-3-SILACYCLOPENTATHIONES CAN BE PRODUCED, ACCORDING TO THE INVENTION, BY REACTING AN AMINOMETHYLALKOXYSILANE OF THE GENERAL FORMULA
R"''-NH-CH2-SI(-R'')(-R")-O-X
(R'', R" AND R''" AS ABOVE; X =ALKYL) AT A TEMPERATURE BETWEEN 0 AND 250*C. WITH AN ISOTHIOCYANATE OF THE GENERAL FORMULA RNCS (R AS ABOVE) AND RECOVERING THE PRODUCT BY DISTILLATION UNDER REDCUED PRESSURE OR BY FILTRATION. THESE PRODUCTS ARE SUITABLE AS INTERMEDIATES FOR CARBOFUNCTIONAL ORGANOPOLYSILOXANES AND AS CROSS-LINKING AGENTS IN WATER-REACTIVE ORGANOPOLYSILOXANE PREPARATIONS.
S=C-
Patent Agency Ranking
公开(公告)号：US3927042A
公开(公告)日：1975-12-16
申请号：US36477673
申请日：1973-05-29
Applicant: BAYER AG
Inventor： GOLITZ HANS DIETRICH , WAGNER KUNO , QUIRING BERND , NOLL WALTER
IPC: C07F7/18 , C08L83/04 , C07D303/46
CPC classification number: C07F7/1804 , C08L83/04 , C08L2666/44
Abstract: New carbofunctional organosilanes which may be regarded as alkoxysilyl- and glycidyl ether-substituted carbamate-modified urea derivatives having the formula
are obtained by reacting an aminomethyl-alkoxysilane of the formula
with an epoxy-organo-isocyanate of the formula
at a temperature below 50*C. In these formulae R is alkyl; R'' is alkyl, cyclohexyl or phenyl; R'''' is alkylene or cycloalkylene; n is 1, 2 or 3. The products are utilizable for priming silicious surfaces and for cross-linking convertible organopolysiloxanes.Abstract translation: 可以被认为是具有式R'OOCH 3的烷氧基甲硅烷基和缩水甘油醚取代的氨基甲酸酯改性的脲衍生物的新的官能团有机硅烷|平行平行|（RO-）nSi（CH 3）3-n-CH 2 -NC-NH-R' 通过使式（RO-）nSi（CH3）3-n-CH2-NH | R'的氨基甲基 - 烷氧基硅烷反应获得“-NH-CO-CH-CH 2 -CH 2 | CH 2 -CH-CH 2 -O 在低于50℃的温度下与式OCN-R“-NH-CO-CH-CH 2 -CH 2 -O-CH 2 -CH-CH 2 PARALLEL | ANGLE OCH 3 O的环氧有机异氰酸酯反应。在这些式中，R是 烷基; R'是烷基，环己基或苯基; R“是亚烷基或亚环烷基; n为1,2或3。
-
公开(公告)号：US3895043A
公开(公告)日：1975-07-15
申请号：US30319272
申请日：1972-11-02
Applicant: BAYER AG
Inventor： WAGNER KUNO , OERTEL GUNTER , GOLITZ HANS DIETRICH , QUIRING BERND
CPC classification number: C07F7/182 , C08G18/10 , C08G18/289
Abstract: This invention discloses a silyl-substituted urea derivative of controlled reactivity, high storage stability and which improve the properties of the cross-linked end products obtained by the prior art. The silyl-substituted urea comprises the general formula:
WHEREIN R represents a C1-C18 alkyl, C4-C14 cycloalkyl or a phenyl radical, R'' represents a C1-C10 alkyl, C4-C10 cycloalkyl or C6-C10 aryl radical which may be halogenated or cyano-substituted, R'''' represents a hydrogen atom or a methyl or phenyl radical; R'''''' represents a hydrogen atom or a C1-C18 alkyl, C4-C14 cycloalkyl or C6-C14 aryl radical which may be halogenated or cyano-substituted; Q'' represents an alkyl radical containing from 4 to 12 carbon atoms with a valency of (b + 1) or a C4-C14 cycloalkyl, C7-C15 arylalkyl, C6-C14 aryl or C8 alkylaryl radical, all of which radicals have a valency of (b + 1); Q represents a c-valent radical which has been obtained by the removal of C HX groups from a compound with a molecular weight of 200 to 150,000, preferably from 4000 to 80,000, which contains ester, amide, urethane, thioether, acetal, urea, hydrazodicarbonamide, hydrazide and/or carbonate groups and may also contain additional ether groups; A 0, 1 OR 2; B 1 TO 7, PREFERABLY 1 OR 2; C 1 TO 8, PREFERABLY 2 OR 3 AND X O, S, NH or N-Y- (Y C1-C8 alkyl radicals).Abstract translation: 本发明公开了具有受控反应性，高储存稳定性和改进现有技术获得的交联终产物性能的甲硅烷基取代的脲衍生物。
-
公开(公告)号：US3658864A
公开(公告)日：1972-04-25
申请号：US3658864D
申请日：1970-01-26
Applicant: BAYER AG
Inventor： GOLITZ HANS DIETRICH , SIMMLER WALTER
CPC classification number: C08G77/26 , C07F7/184 , C08G77/388 , C08G77/46 , Y10S516/07
Abstract: NEW ORGANOSILOXANE-MODIFIED CARBAMIC ACID ESTERS COMPRISE AT LEAST ONE STRUCTURAL UNIT OF THE FORMULA
(O(3-M/2)-SI(-R'')M-CH(-R")-N(-R"'')-COO-(CNH2N-O)B)C-Q
AND OPTIONALLY FURTHER STRUCTURAL UNITS OF THE FORMULA R''A-SI-O/4-A WHEREIN HOWEVER AT LEAT ONE OF EVERY THOUSAND STRUCTURAL UNITS CORRESPONDS TO THE FIRST OF THE ABOVE FORMULAE. IN THESE FORMULAE R'' AND R" ARE MONOVALENT HYDROCARBON RADICALS OF UP TO 10 CARBON ATOMS, R" IS A HYDROGEN ATOM, AMETHYL RADICAL OR A PHENYL RADICAL. Q IS A MONOVALENT TO HEXAVALENT HYDROCARBON RADICAL HAVING UP TO 6 CARBON ATOMS, M IS 0, 1 OR 2, N IS 2, 3 OR 4, A IS 0, 1, 2 OR 3, B IS ZERO OR AN INTEGER FROM 1 TO 200, AND C IS THE VALENCY NUMBER OF Q. THESE CARBAMIC ACID DERIVATIVES ARE PREPARED EITHER BY HYDROLYZING A CORESPONDING, ALKOXYSILY-SUBSTIUTED CARBAMIC ACID ESTER, OPTIONALLY IN ADMIXTURE WITH HYDROCABON-SUBSTITUTED ALKOXYSILANES, OR BY REACTING A CORRESPONDING AMINOMETHYL-SUBSTITUTED POLYSILOXANE WITH A CHLOROFORMIC ACID ESTER OF THE FORMULA (CL-COO-(CNH2N-O)B)C-Q IN THE PRESENCE OF A TERTIARY AMINE. THE PRODUCTS ARE TO BE USED AS PRIMING AGENTS IMPARTING ADHESION TO SYNTHETIC RESINS ON SILICEOUS SURFACES, AS SURFACTANTS AND AS INTERMEDIATES FOR ORGANO-POLYSIOLOXANE RESINS.-
公开(公告)号：US3657303A
公开(公告)日：1972-04-18
申请号：US3657303D
申请日：1970-01-28
Applicant: BAYER AG
Inventor： GOLITZ HANS DIETRICH , DEGENER EBERHART , OERTEL GUNTER , SCHMELZER HANS-GEORG , SIMMLER WALTER
CPC classification number: C07F7/182 , C07F7/0854 , C08G77/26 , Y10S516/07 , Y10T428/31663
Abstract: NEW ORGANOSILOXANE- AND CARBAMATE-MODIFIED UREA DERIVATIVES COMPRISE AT LEAST ONE STRUCTURAL UNIT OF THE FORMULA
(O(3-M/2)-SI(-R'')M-CH(-R")-N(-R"'')-CO-NH-Q-NH-COO-(CNH2N-
O)B)C-Q
AND OPTIONALLY FURTHER STRUCTURAL UNITS OF THE FORMULA
(R'')A-SI-O(4-A/2)
WHEREIN HOWEVER AT LEAST ONE OF A THOUSAND STRUCTURAL UNITS CORRESPONDS TO THE FIRST OF THE ABOVE FORMULAE. IN THESE FORMULAE R'' IS A M ONOVALENT HYDROCARBON RADICAL, R" AND R" ARE HYDROGEN ATOMS OR MONOVALENT HYDROCARBON RADICALS, Q'' IS A BIVALENT HYDROCARBON RADICAL, Q IS A MONOVALENT TO HEXAVALENT HYDROCARBON RADICAL, M IS 0, 1 OR 2, N IS 2, 3 OR 4, A IS 0, 1, 2 OR 3, B IS ZERO OR AN INTERGER FROM 1 TO 200, AND C IS THE VALENCY NUMBER OF Q. THESE UREA DERIVATIVES ARE PREPARED EITHER BY HYDROLYZING A CORRESPONDING ALKOXYSILYL-SUBSTITUTED CARBAMATEMODIFIED UREA DERIVATIVE, OPTIONALLY IN ADMIXTURE WITH HYDROCARBON-SUBSTITUTED ALKOXYSILANES, OR BY REACTING A CORRESPONDING AMINOLKYL-SUBSTITUTED POLYSILOXANE WITH AN ISOCYANATE-MODIFIED CARBAMIC ACID ESTER OF THE FORMULA
(O-CN-Q''-NH-COO-(CNH2N-O)B)C-Q
THE PRODUCTS ARE TO BE USED AS PRIMING AGENTS IMPARTING ADHESION TO SYNTHETIC RESINS ON SILICEOUS SURFACES, AS SURFACTANTS AND AS INTERMEDIATES FOR ORGANO-POLYSILOXANE RESINS.-
公开(公告)号：US3621047A
公开(公告)日：1971-11-16
申请号：US3621047D
申请日：1969-09-11
Applicant: BAYER AG
Inventor： GOLITZ HANS DIETRICH , SIMMLER WALTER , SCHWABE PETER
CPC classification number: C07F7/1836 , C08G77/16 , C08L83/04 , Y10S528/901 , C08L2666/44
Abstract: Novel cross-linking agents are disclosed which can be combined with plastically shapable organopolysiloxanes; the resulting novel mixtures or compositions being storage stable under exclusion of all moisture. The cross-linking reaction takes place on exposure of the compositions to water, atmospheric humidity sufficing, at temperatures below 50* C. The compositions are especially adapted to be used for the filling of joints and as sealing materials in the building industry. The elastomers resulting therefrom have an increased adhesion to the substrate saving the expenditure of priming, and are transparent. The novel compositions comprise: A. an Alpha , omega -dihydroxy-poly-(diorgano-siloxane) which, in addition to its diorganosiloxane units, may contain up to 10 mol-percent of siloxane units having the formula CH3SiO3/2, and may be admixed with fillers and an Alpha , omega -bis(trimethyl-siloxy)-poly-(diorgano-siloxane); and B. a cross-linking agent having the formula ((RO-)3Si-CH(R''))nNQ3 n IN WHICH N IS 2 OR 3, R is an alkyl radical with 1 to 4 carbon atoms, R'' is a hydrogen atom, an alkyl radical with 1 to 6 carbon atoms, a cyclohexyl radical a phenyl radical, and Q is an alkyl or alkenyl radical with 2 to 4 carbon atoms, an aralkyl radical with 7 to 10 carbon atoms, a dimethylaminoalkyl radical with 2 to 4 carbon atoms in its alkylene group, or a methoxy- or ethoxyethyl or -propyl radical.
-
-
-
-
-
-
-
-
Search Results
9
records
(took 0.026 seconds)
