POLYMERISATION PROCESS
    4.
    发明申请
    POLYMERISATION PROCESS 有权
    聚合过程

    公开(公告)号:US20150337060A1

    公开(公告)日:2015-11-26

    申请号:US14436914

    申请日:2013-10-17

    申请人: BOREALIS AG

    IPC分类号: C08F110/06

    摘要: A process for the preparation of a propylene homopolymer comprising polymerising propylene in the presence of a catalyst comprising: (i) a metallocene complex of a group (IV) metal said metallocene comprising at least two cyclopentadienyl type ligands; (ii) a boron cocatalyst; and (iii) an aluminoxane cocatalyst; said catalyst being in solid form, preferably in solid particulate form, and being free from an external carrier; preferably wherein the melting point of the propylene polymer is controlled by adjusting the amount of or nature of the boron cocatalyst.

    摘要翻译: 一种制备丙烯均聚物的方法,包括在催化剂存在下聚合丙烯,所述催化剂包含:(i)金属茂族金属茂金属,所述茂金属包含至少两个环戊二烯基型配体; (ii)硼助催化剂; 和(iii)铝氧烷助催化剂; 所述催化剂为固体形式,优选为固体颗粒形式,并且不含外部载体; 优选其中丙烯聚合物的熔点通过调节硼助催化剂的量或性质来控制。

    Polymerisation process
    6.
    发明授权
    Polymerisation process 有权
    聚合过程

    公开(公告)号:US09469708B2

    公开(公告)日:2016-10-18

    申请号:US14436914

    申请日:2013-10-17

    申请人: BOREALIS AG

    摘要: A process for the preparation of a propylene homopolymer comprising polymerizing propylene in the presence of a catalyst comprising: (i) a metallocene complex of a group (IV) metal said metallocene comprising at least two cyclopentadienyl type ligands; (ii) a boron cocatalyst; and (iii) an aluminoxane cocatalyst; said catalyst being in solid form, preferably in solid particulate form, and being free from an external carrier; preferably wherein the melting point of the propylene polymer is controlled by adjusting the amount of or nature of the boron cocatalyst.

    摘要翻译: 一种制备丙烯均聚物的方法,包括在催化剂存在下聚合丙烯,所述催化剂包含:(i)金属组(IV)金属茂金属,所述茂金属包含至少两个环戊二烯基型配体; (ii)硼助催化剂; 和(iii)铝氧烷助催化剂; 所述催化剂为固体形式,优选为固体颗粒形式,并且不含外部载体; 优选其中丙烯聚合物的熔点通过调节硼助催化剂的量或性质来控制。

    Asymmetrical Ligands
    7.
    发明申请
    Asymmetrical Ligands 审中-公开
    不对称配体

    公开(公告)号:US20160024123A1

    公开(公告)日:2016-01-28

    申请号:US14876328

    申请日:2015-10-06

    申请人: BOREALIS AG

    IPC分类号: C07F7/08 C08F10/06

    摘要: A ligand of formula (I′) wherein L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-20-hydrocarbyl, tri(C1-20-alkyl)silyl, C6-20-aryl, C7-20-arylalkyl or C7-20-alkylaryl; R2 and R2′ are each independently a C1-20 hydrocarbyl radical; R5′ is a C1-20 hydrocarbyl group; R6, R6′, R7 and R7′ are each independently hydrogen or a C1-20 hydrocarbyl group; Ar and Ar′ are independently an aryl or heteroaryl group having up to 20 carbon atoms; each R1 is a C1-20 hydrocarbyl group or two R1 groups on adjacent carbon atoms taken together can form a fused 5 or 6 membered non aromatic ring with the Ar group; and each R4 is a C1-20 hydrocarbyl group; and the dotted lines represent a double bond present in between carbons 1 and 2 or 2 and 3 of the indenyl ring.

    摘要翻译: 式(I')的配体,其中L是选自-R'2C-,-R'2C-CR'2-,-R'2Si-,-R'2Si-SiR'2,-R 其中每个R'独立地为氢原子,C 1-20烃基,三(C 1-20烷基)甲硅烷基,C 6-20 - 芳基,C 7-20 - 芳基烷基或C 7-20 - 烷基芳基; R2和R2'各自独立地为C1-20烃基; R5'是C1-20烃基; R6,R6',R7和R7'各自独立地为氢或C1-20烃基; Ar和Ar'独立地为具有至多20个碳原子的芳基或杂芳基; 每个R 1是C 1-20烃基或相邻碳原子上的两个R 1基团可以与Ar基团形成稠合的5或6元非芳族环; 并且每个R 4是C 1-20烃基; 虚线表示存在于茚基环的碳1和2或2和3之间的双键。