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公开(公告)号:US20190330389A1
公开(公告)日:2019-10-31
申请号:US16311255
申请日:2017-06-22
Applicant: BOREALIS AG
Inventor: Irfan Saeed , Katri Nikkilä , Kalle Kallio
IPC: C08F6/02 , C08F2/06 , C08F4/6592
Abstract: A process for the offline deactivation of at least one single site catalyst comprising contacting said catalyst with a deactivating agent selected from an aprotic low molecular weight carbonyl group containing organic compound or an aprotic low molecular weight orthoester or an aprotic low molecular weight acetal compound.
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公开(公告)号:US09670293B2
公开(公告)日:2017-06-06
申请号:US14914501
申请日:2014-10-22
Applicant: BOREALIS AG
Inventor: Alexander Reznichenko , Noureddine Ajellal , Pascal Castro , Irfan Saeed
IPC: C08F4/649 , C08F4/6592 , C08F10/00 , C08F4/659
CPC classification number: C08F10/00 , C08F4/649 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F2410/01 , C08F10/06 , C08F110/06 , C08F2500/12 , C08F210/16 , C08F210/14 , C08F110/02 , C08F2500/01
Abstract: Process for the preparation of a solid catalyst system comprising the steps of preparing a liquid clathrate comprising a mixing of an aluminoxane, an aromatic compound and an organo-silicon compound, wherein the mol-ratio between the organo-silicon compound and aluminum of the aluminoxane is below 0.1, mixing said liquid clathrate with an organometallic compound obtaining a liquid mixture, and precipitating the solid catalyst system out of said liquid mixture by adding a saturated aliphatic compound to said mixture liquid.
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公开(公告)号:US11560440B2
公开(公告)日:2023-01-24
申请号:US16499514
申请日:2018-03-28
Applicant: BOREALIS AG
Inventor: Luigi Maria Cristoforo Resconi , Noureddine Ajellal , Anna Fait , Irfan Saeed , Maria Ranieri , David Quin , Vyatcheslav V. Izmer , Dmitry S. Kononovich , Oleg Samsonov , Alexander Z. Voskoboynikov
IPC: C08F210/16 , C08F4/6592 , C08F4/642
Abstract: Catalyst system, the catalyst system comprising (i) at least one metallocene complex of formula (I) wherein Mt1 is Hf, X is a sigma-donor ligand, R1, R2, R3 are the same or different from each other and can be hydrogen or a saturated linear or branched C1-C10 alkyl, whereby the alkyl group can optionally contain up to 2 heteroatoms belonging to groups 14-16 of the periodic table, or R1 and R2 or R2 and R3 can form a ring having 4 to 6 C-atoms and 1 to 3 double bonds, R4 and R5 are the same or different from each other and can be saturated linear or branched C1-C10 alkyl, C5-C10 aryl, C6-C20 alkylaryl or C6-C20 arylalkyl groups, which can optionally contain up to 2 heteroatoms belonging to groups 14-16 of the periodic table, n can be 1 to 5, Ar is a C6-C20-aryl or -heteroaryl group, which can be unsubstituted or substituted by 1 to 5 linear or branched C1-C10 alkyl group(s), and (ii) an aluminoxane cocatalyst and (iii) optionally an aluminium alkyl compound AI(R7)3, with R7 being a linear or branched C2-C8-alkyl group.
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公开(公告)号:US09556295B2
公开(公告)日:2017-01-31
申请号:US14783668
申请日:2014-04-28
Applicant: Borealis AG
Inventor: Irfan Saeed , Esa Kokko , Paivi Waldvogel , Marja Mustonen , Thomas Garoff
IPC: B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60 , C08F4/44 , C08F2/00 , C08F210/08 , C08F210/16
CPC classification number: C08F210/08 , C08F210/16 , C08F2500/12 , C08F2500/18 , C08F4/651 , C08F4/6555 , C08F4/025
Abstract: Procatalyst comprising an inorganic support, a chlorine compound carried on said support, a magnesium compound carried on said support, a titanium compound carried on said support, and a compound comprising two oxygen containing rings, wherein said two rings are linked via a bridge selected from the group consisting of carbon bridge, silicon bridge, ethane-1.2-diyl bridge, ethene-1,2-diyl bridge, alkylaminomethyl bridge and imine bridge.
Abstract translation: 主催化剂包括无机载体,载持在所述载体上的氯化合物,载持在所述载体上的镁化合物,载于所述载体上的钛化合物和包含两个含氧环的化合物,其中所述两个环通过选自以下的桥连接: 由碳桥,硅桥,乙烷-1,2-二桥,乙烯-1,2-二桥,烷基氨基甲基桥和亚胺桥组成。
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公开(公告)号:US20160060372A1
公开(公告)日:2016-03-03
申请号:US14783668
申请日:2014-04-28
Applicant: BOREALIS AG
Inventor: Irfan Saeed , Esa Kokko , Paivi Waldvogel , Marja Mustonen , Thomas Garoff
IPC: C08F210/08
CPC classification number: C08F210/08 , C08F210/16 , C08F2500/12 , C08F2500/18 , C08F4/651 , C08F4/6555 , C08F4/025
Abstract: Procatalyst comprising an inorganic support, a chlorine compound carried on said support, a magnesium compound carried on said support, a titanium compound carried on said support, and a compound comprising two oxygen containing rings, wherein said two rings are linked via a bridge selected from the group consisting of carbon bridge, silicon bridge, ethane-1.2-diyl bridge, ethene-1,2-diyl bridge, alkylaminomethyl bridge and imine bridge.
Abstract translation: 主催化剂包括无机载体,载持在所述载体上的氯化合物,载持在所述载体上的镁化合物,载于所述载体上的钛化合物和包含两个含氧环的化合物,其中所述两个环通过选自以下的桥连接: 由碳桥,硅桥,乙烷-1,2-二桥,乙烯-1,2-二桥,烷基氨基甲基桥和亚胺桥组成。
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公开(公告)号:US11965052B2
公开(公告)日:2024-04-23
申请号:US18111025
申请日:2023-02-17
Applicant: BOREALIS AG
Inventor: Irfan Saeed , Esa Kokko , Mika Salo , Sanjay Rastogi , Dario Romano , Sara Ronca
CPC classification number: C08F4/6492 , C08F2/001 , C08F4/025 , C08F4/6546 , C08F4/6555 , C08F110/02 , C08L23/06 , C08F2500/01 , C08F2500/12 , C08F2500/26 , C08F2500/34 , C08F2500/35 , C08L2203/16 , C08L2207/068 , C08L2314/02
Abstract: A process for the preparation of an ultra-high molecular weight ethylene homopolymer having a MFR21 of 0.01 g/10 min or less, said process comprising:
(I) prepolymerising at least ethylene at a temperature of 0 to 90° C. in the presence of a heterogeneous Ziegler Natta catalyst to prepare an ethylene prepolymer having an Mw of 40,000 to 600,000 g/mol; and thereafter in the presence of the prepolymer and said catalyst;
(II) polymerising ethylene at a temperature of 55° C. or less, such as 20 to 55° C., to prepare said UHMW ethylene homopolymer;
wherein the UHMW ethylene homopolymer comprises up to 8 wt. % of said prepolymer.-
公开(公告)号:US11680114B2
公开(公告)日:2023-06-20
申请号:US17261317
申请日:2019-07-18
Applicant: BOREALIS AG
Inventor: Irfan Saeed , Esa Kokko , Mika Salo , Sanjay Rastogi , Dario Romano , Sara Ronca
CPC classification number: C08F4/6492 , C08F4/025 , C08F4/6546 , C08F4/6555 , C08F110/02 , C08L23/06 , C08F2500/01 , C08F2500/12 , C08F2500/26 , C08F2500/34 , C08F2500/35 , C08L2203/16 , C08L2207/068
Abstract: A process for the preparation of an ultra-high molecular weight ethylene homopolymer having a MFR21 of 0.01 g/10 min or less, said process comprising: (I) prepolymerising at least ethylene at a temperature of 0 to 90° C. in the presence of a heterogeneous Ziegler Natta catalyst to prepare an ethylene prepolymer having an Mw of 40,000 to 600,000 g/mol; and thereafter in the presence of the prepolymer and said catalyst; (II) polymerising ethylene at a temperature of 55° C. or less, such as 20 to 55° C., to prepare said UHMW ethylene homopolymer; wherein the UHMW ethylene homopolymer comprises up to 8 wt. % of said prepolymer.
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公开(公告)号:US10982019B2
公开(公告)日:2021-04-20
申请号:US16311255
申请日:2017-06-22
Applicant: BOREALIS AG
Inventor: Irfan Saeed , Katri Nikkilä , Kalle Kallio
IPC: C08F2/00 , C08F2/38 , C08F4/6592 , C08F6/02 , C08F2/06
Abstract: A process for the offline deactivation of at least one single site catalyst comprising contacting said catalyst with a deactivating agent selected from an aprotic low molecular weight carbonyl group containing organic compound or an aprotic low molecular weight orthoester or an aprotic low molecular weight acetal compound.
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公开(公告)号:US20190144583A1
公开(公告)日:2019-05-16
申请号:US16310550
申请日:2017-06-12
Applicant: BOREALIS AG
Inventor: Girish Suresh Galgali , Irfan Saeed , Jarmo Kela
IPC: C08F210/16 , C08F2/00 , C08L23/08
Abstract: New bi- or multimodal polyethylene terpolymer made with a metallocene catalyst having a narrow molecular weight distribution and enhanced rheological properties, i.e. specific ratio of complex viscosity at 0.01 rad/s to the viscosity at 100 rad/s measured at 190° C. and a specific shear thinning behaviour.
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