摘要:
A process unit for the zeolite-catalyzed conversion of light refinery olefins from an FCC unit such as ethylene, propylene, and butylene to gasoline boiling range motor fuels comprises at least two sequential, serially connected reactors connected in parallel to a fractionation section with at one or two fractionators for separating the reactor effluents into product fraction with an optional recycle stream or streams. The configurations according to this scheme allow the adjustment of reactor temperature and/or pressure and/or space velocity to be based on the reactivities of the olefin compounds present in the LPG streams so that the gasoline produced in each reactor will be separated immediately, to reduce over-polymerization of the gasoline in the low severity reactor and to ensure that gasoline formed in the low severity reactor will not be sent to the higher severity reactor e.g. with a higher reactor temperature, where excessive polymerization to undesirable higher molecular with products may take place.
摘要:
Bromine reactive hydrocarbon contaminants are removed from aromatic streams by first providing an aromatic feedstream having a negligible diene level. The feedstream is contacted with an acid active catalyst composition under conditions sufficient to remove mono-olefins. An aromatic stream may be pretreated to remove dienes by contacting the stream with clay, hydrogenation or hydrotreating catalyst under conditions sufficient to substantially remove dienes but not mono-olefins.
摘要:
A process for reducing the Bromine Index of a hydrocarbon feed containing bromine-reactive contaminants that has improved cycle length and utilizes a crystalline molecular sieve catalyst. The process is carried out by contacting the hydrocarbon feed under conversion conditions with a catalyst shaped in the form of an elongated aggregate comprising a crystalline molecular sieve having a MWW or *BEA framework type. The shortest cross-sectional dimension of the elongated aggregate is less about 1/10 inch (2.54 millimeters).
摘要:
Bromine reactive hydrocarbon contaminants are removed from aromatic streams by first providing an aromatic feedstream having a negligible diene level. The feedstream is contacted with an acid active catalyst composition under conditions sufficient to remove mono-olefins. An aromatic stream may be pretreated to remove dienes by contacting the stream with clay, hydrogenation or hydrotreating catalyst under conditions sufficient to substantially remove dienes but not mono-olefins.
摘要:
A process for reducing the Bromine Index of a hydrocarbon feed containing bromine-reactive contaminants that has improved cycle length and utilizes a crystalline molecular sieve catalyst. The process is carried out by contacting the hydrocarbon feed under conversion conditions with a catalyst shaped in the form of an elongated aggregate comprising a crystalline molecular sieve having a MWW or *BEA framework type. The shortest cross-sectional dimension of the elongated aggregate is less about 1/10 inch (2.54 millimeters).