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1.发明申请Separation of carbon dioxide from nitrogen utilizing zeolitic imidazolate framework materials 有权使用沸石咪唑盐骨架材料从氮中分离二氧化碳公开(公告)号：US20090214407A1
公开(公告)日：2009-08-27
申请号：US12321751
申请日：2009-01-23
申请人： Sebastian C. Reyes , Jose G. Santiesteban , Zheng Ni , Charanjit S. Paur , Pavel Kortunov , John Zengel , Harry W. Deckman
发明人： Sebastian C. Reyes , Jose G. Santiesteban , Zheng Ni , Charanjit S. Paur , Pavel Kortunov , John Zengel , Harry W. Deckman
IPC分类号： B01D53/62 , B01D53/047 , B01D53/22 , C01B31/20
CPC分类号： B01D53/02 , B01D53/228 , B01D67/0051 , B01D69/141 , B01D71/028 , B01D2253/204 , B01D2256/10 , B01D2257/504 , B01D2325/12 , B01D2325/20 , B01J20/226 , Y02C10/04 , Y02C10/08 , Y02C10/10
摘要： The present invention relates to the selective separation of carbon dioxide (“CO2”) from nitrogen (“N2”) in streams containing both carbon dioxide and nitrogen utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in a process to separate carbon dioxide from combustion gas (e.g., flue gas) streams preferably for sequestration of at least a portion of the carbon dioxide produced in combustion processes.
摘要翻译： 本发明涉及使用沸石咪唑化物骨架（“ZIF”）材料在含有二氧化碳和氮气的物流中从氮气（“N2”）中选择性分离二氧化碳（“CO 2”）。 优选地，待分离的物流以基本上气相的方式进料到本方法中。 在优选的实施方案中，本发明用于将二氧化碳从燃烧气体（例如烟道气）流中分离出来，优选用于封存燃烧过程中产生的二氧化碳的至少一部分。
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2.发明申请Separation of hydrogen from hydrocarbons utilizing zeolitic imidazolate framework materials 有权使用沸石咪唑盐骨架材料从氢气中分离氢气公开(公告)号：US20090211440A1
公开(公告)日：2009-08-27
申请号：US12322363
申请日：2009-01-30
申请人： Sebastian C. Reyes , Jose G. Santiesteban , Zheng Ni , Charanjit S. Paur , Pavel Kortunov , John Zengel , Harry W. Deckman
发明人： Sebastian C. Reyes , Jose G. Santiesteban , Zheng Ni , Charanjit S. Paur , Pavel Kortunov , John Zengel , Harry W. Deckman
CPC分类号： B01D53/228 , B01D53/02 , B01D53/0462 , B01D53/047 , B01D67/0051 , B01D69/141 , B01D71/028 , B01D2253/108 , B01D2253/204 , B01D2256/16 , B01D2256/24 , B01D2257/702 , B01D2325/12 , B01J20/226 , C01B3/503 , C01B3/56 , C01B2203/0233 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/0445 , C01B2203/048 , Y10S95/902
摘要： The present invention relates to the selective separation of hydrogen (“H2”) hydrocarbons in streams containing both hydrogen and hydrocarbons (e.g. methane, ethylene, ethane, propylene, propane, etc.) utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in either a pressure swing adsorption process, a temperature swing adsorption process, or a membrane separations process to separate hydrogen from hydrocarbons present in hydrogen production streams or petrochemical/petroleum refining product streams and intermediate streams.
摘要翻译： 本发明涉及使用沸石咪唑化物骨架（“ZIF”）材料选择性分离含氢和烃（例如甲烷，乙烯，乙烷，丙烯，丙烷等）的物流中的氢（“H 2”）烃。 优选地，待分离的物流以基本上气相的方式进料到本方法中。 在优选实施方案中，本发明用于变压吸附法，变温吸附法或膜分离方法，以将氢气与存在于氢生产流或石化/石油精炼产物流和中间物流中的烃分离。
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公开(公告)号：US07332640B2
公开(公告)日：2008-02-19
申请号：US10699258
申请日：2003-10-31
IPC分类号： C07C7/12
摘要： The present invention is related to a method for kinetically separating a light hydrocarbon mixture comprising at least two components by preferentially adsorbing a first component on a zeolite adsorbent comprising 8-member rings of tetrahedra as the pore opening controlling hydrocarbon diffusion and alkali metal cations balancing a framework charge, wherein a second component is not preferentially adsorbed. The novel process comprises contacting the light hydrocarbon mixture with a zeolite adsorbent having a SiO2/Al2O3 ratio greater than about 50 and less than 200 and further having a diffusion rate at least 50 times greater for the first component as compared to the second component, and then recovering at least one of the first component or the second component.
摘要翻译： 本发明涉及一种用于动态分离含有至少两种组分的轻质烃混合物的方法，该轻质烃混合物优先吸附在包含八元环四面体的沸石吸附剂上的第一组分，作为开孔控制烃扩散和碱金属阳离子平衡 框架电荷，其中第二组分不被优先吸附。 该新方法包括使轻质烃混合物与沸石吸附剂接触，所述沸石吸附剂具有大于约50或更小的SiO 2 / Al 2 O 3 并且与第二组分相比，第一组分的扩散速率至少为50倍，然后回收第一组分或第二组分中的至少一种。
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公开(公告)号：US06441252B1
公开(公告)日：2002-08-27
申请号：US09991831
申请日：2001-11-14
申请人： Doron Levin , Jose G. Santiesteban
发明人： Doron Levin , Jose G. Santiesteban
IPC分类号： C07C3708
CPC分类号： C07C37/08 , C07C45/53 , Y02P20/127 , Y10S203/06 , C07C49/08 , C07C39/04
摘要： An apparatus for producing phenol and acetone from cumene hydroperoxide comprises a reactive distillation column comprising at its upper portion a distillation column and at its lower portion a catalyst bed.
摘要翻译： 用于由氢过氧化枯烯生产苯酚和丙酮的装置包括反应性蒸馏塔，其上部部分包含蒸馏塔，其下部包含催化剂床。
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公开(公告)号：US06224748B1
公开(公告)日：2001-05-01
申请号：US08169107
申请日：1993-12-20
IPC分类号： C10G4702
CPC分类号： C07C5/2724 , B01J21/06 , B01J21/066 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/652 , B01J23/6527 , C01G25/02 , C01P2002/54 , C07C5/2791 , C10G2400/10 , C07C9/00 , C07C9/16
摘要： A process for hydrocracking heavy, high aromatic content feeds, such as cycle oil, using a catalyst composition containing a hydrogenation/dehydrogenation component, such as a noble metal, and an acidic solid component including a Group IVB metal oxide modified with an oxyanion of a Group VIB metal.
摘要翻译： 使用包含氢化/脱氢组分如贵金属的催化剂组合物和包含用氧阴离子改性的IVB族金属氧化物的酸性固体组分加氢裂化重质，高芳族化合物进料如循环油的方法， VIB族金属。
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公开(公告)号：US06169215A
公开(公告)日：2001-01-02
申请号：US09275749
申请日：1999-03-25
IPC分类号： C07C3708
CPC分类号： B01J23/002 , B01J23/30 , B01J23/881 , B01J23/888 , B01J37/03 , B01J2523/00 , C07C37/08 , C07C45/53 , Y02P20/52 , B01J2523/48 , B01J2523/68 , B01J2523/842 , B01J2523/69 , C07C39/04
摘要： A process for producing phenol and acetone from cumene hydroperoxide is described in which the cumene hydroperoxide is contacted with a solid-acid catalyst produced by calcining a source of a Group IVB metal oxide with a source of an oxyanion of a Group VIB metal at a temperature of at least 400°C.
摘要翻译： 描述了由氢过氧化枯烯生产苯酚和丙酮的方法，其中氢过氧化枯烯与通过煅烧ⅣB族金属氧化物源与VIB族金属氧化物源的温度在一定温度下煅烧而制得的固体酸催化剂接触 至少400℃。
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公开(公告)号：US5608133A
公开(公告)日：1997-03-04
申请号：US551873
申请日：1995-10-23
IPC分类号： B01J23/30 , B01J21/06 , B01J23/24 , C07B61/00 , C07C2/02 , C07C2/14 , C07C11/02 , C10G50/00 , C10G50/02 , C10G69/12 , C10L1/16 , C10L10/08 , C10M107/02
CPC分类号： B01J21/066 , B01J21/06 , B01J23/24 , C07C2/14 , C10G50/00 , C10G50/02 , C10G69/126 , C07C2521/06 , C07C2527/00
摘要： There is provided a catalytic oligomerization process. The process involves the use of a catalyst comprising an acidic solid. The acidic solid may comprise a Group IVB metal oxide, such as zirconia, modified with an oxyanion of a Group VIB metal, such as tungsten. The oligomers produced by this process may be hydrogenated to produce thermally stable lubricants and lubricant additives, gasoline and diesel.
摘要翻译： 提供催化低聚方法。 该方法包括使用包含酸性固体的催化剂。 酸性固体可以包含用VIB族金属如钨的氧阴离子改性的IVB族金属氧化物，例如氧化锆。 通过该方法生产的低聚物可以被氢化以产生热稳定的润滑剂和润滑剂添加剂，汽油和柴油。
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公开(公告)号：US5543036A
公开(公告)日：1996-08-06
申请号：US167108
申请日：1993-12-16
IPC分类号： B01J21/06 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/652 , C01G25/02 , C07C5/27 , C10G67/04 , C10G17/00 , C10G17/095 , C10G45/04
CPC分类号： B01J21/06 , B01J21/066 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/652 , B01J23/6527 , C01G25/02 , C07C5/2724 , C07C5/2791 , C01P2002/54 , C10G2400/10
摘要： A process for hydrotreating a hydrocarbon feedstock, such as light cycle oil, using a catalyst composition containing a hydrogenation/dehydrogenation component and an acidic solid component including a Group IVB metal oxide modified with an oxyanion of a Group VIB metal. The hydrotreating process removes contaminants, such as sulfur and/or nitrogen, from the feedstock.
摘要翻译： 使用包含氢化/脱氢组分的催化剂组合物和包含用VIB族金属的氧阴离子改性的IVB族金属氧化物的酸性固体组分对烃原料如轻质循环油进行加氢处理的方法。 加氢处理工艺从原料中除去污染物，如硫和/或氮。
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9.发明授权Double bond isomerization of olefin-containing feeds with minimal oligomerization using permanently surface acidity deactivated zeolite catalysts 失效使用永久表面酸性失活的沸石催化剂，使含烯烃进料的双键异构化以最小的低聚反应
公开(公告)号：US5304695A
公开(公告)日：1994-04-19
申请号：US20947
申请日：1993-02-22
IPC分类号： C07C5/25
CPC分类号： C07C5/2518
摘要： A method is disclosed for the double bond isomerization of alpha olefin-containing feeds, e.g., conversion of 1-butene-containing hydrocarbon streams to 2-butene-rich product streams, wherein oligomer by-products are minimized. The process uses a catalyst composition comprising a zeolite whose surface has been at least partially deactivated for acid catalyzed reactions by treatment with an aluminum chelating agent, e.g., oxalic acid, which possesses an average cross section diameter greater than that of the zeolite pores.
摘要翻译： 公开了用于含α烯烃的进料的双键异构化的方法，例如将含1-丁烯的烃流转化为富含2-丁烯的产物流，其中低聚物副产物最小化。 该方法使用包含沸石的催化剂组合物，其表面已经通过用铝螯合剂（例如草酸）处理而至少部分失活以进行酸催化反应，所述铝螯合剂例如草酸的平均截面直径大于沸石孔的平均截面直径。
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10.发明授权Double bond isomerization of olefin-containing feeds with minimal oligomertization using surface acidity deactivated zeolite catalysts 失效使用表面酸性去活化沸石催化剂的含极少量含有烯烃的进料双重结合异构化
公开(公告)号：US5237120A
公开(公告)日：1993-08-17
申请号：US813717
申请日：1991-12-27
CPC分类号： B01J29/06 , B01J29/7042 , B01J29/7046 , B01J31/0254 , C07C5/2518 , B01J2229/123 , B01J2229/34 , B01J2231/52 , B01J29/40 , B01J29/65
摘要： A method is disclosed for the double bond isomerization of alpha olefin-containing feeds, e.g., conversion of 1-butene-containing hydrocarbon streams to 2-butene-rich product streams, wherein oligomer by-products are minimized. The process uses a catalyst composition comprising a zeolite whose surface has been at least partially deactivated for acid catalyzed reactions by chemisorption of a surface-deactivating agent, e.g., collidine, which possesses an average cross section diameter greater than that of the zeolite pores.
摘要翻译： 公开了用于含α烯烃的进料的双键异构化的方法，例如将含1-丁烯的烃流转化为富含2-丁烯的产物流，其中低聚物副产物最小化。 该方法使用包含沸石的催化剂组合物，所述催化剂组合物的表面已被至少部分失活用于酸催化反应，通过化学吸附具有大于沸石孔的平均截面直径的表面活性剂例如可力丁，可力丁等。
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