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公开(公告)号：US06699438B1
公开(公告)日：2004-03-02
申请号：US09327963
申请日：1999-06-08
IPC分类号： B01J818
CPC分类号： B01J8/44 , B01J8/1827 , B01J2208/00274 , Y10S526/901
摘要： Ethylenically unsaturated monomers are polymerized in a gas-phase fluidized-bed reactor comprising a reactor space (1) in the form of a vertical tube, a calming zone (2) adjoining the upper part of the reactor space, a circulated gas line (3), a circulated gas compressor (4), a cooling apparatus (5), a gas distributor plate (6) which forms the lower boundary of the reactor space and, if desired, a flow divider (7), wherein the gas distributor plate (6) has a plurality of gas flow orifices (8) whose outlet sides are widened conically.
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公开(公告)号：US07226565B2
公开(公告)日：2007-06-05
申请号：US10913658
申请日：2004-08-09
IPC分类号： B01J8/18
CPC分类号： B01J8/44 , B01J8/1827 , B01J2208/00274 , Y10S526/901
摘要： Ethylenically unsaturated monomers are polymerized in a gas-phase fluidized-bed reactor comprising a reactor space (1) in the form of a vertical tube, a calming zone (2) adjoining the upper part of the reactor space, a circulated gas line (3), a circulated gas compressor (4), a cooling apparatus (5), a gas distributor plate (6) which forms the lower boundary of the reactor space and, if desired, a flow divider (7), wherein the gas distributor plate (6) has a plurality of gas flow orifices (8) whose outlet sides are widened conically.
摘要翻译： 乙烯基不饱和单体在气相流化床反应器中聚合，该反应器包括垂直管形式的反应器空间（1），毗邻反应器空间上部的平静区（2），循环气体管线 ），循环式气体压缩机（4），冷却装置（5），形成反应器空间的下边界的气体分布板（6）以及如果需要的分流器（7），其中气体分配板 （6）具有多个出口侧锥形扩大的气流孔（8）。
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公开(公告)号：US06903168B2
公开(公告)日：2005-06-07
申请号：US10696428
申请日：2003-10-30
CPC分类号： B01J8/44 , B01J8/1827 , B01J2208/00274 , Y10S526/901
摘要： Ethylenically unsaturated monomers are polymerized in a gas-phase fluidized-bed reactor comprising a reactor space (1) in the form of a vertical tube, a calming zone (2) adjoining the upper part of the reactor space, a circulated gas line (3), a circulated gas compressor (4), a cooling apparatus (5), a gas distributor plate (6) which forms the lower boundary of the reactor space and, if desired, a flow divider (7), wherein the gas distributor plate (6) has a plurality of gas flow orifices (8) whose outlet sides are widened conically.
摘要翻译： 乙烯基不饱和单体在气相流化床反应器中聚合，该反应器包括垂直管形式的反应器空间（1），毗邻反应器空间上部的平静区（2），循环气体管线 ），循环式气体压缩机（4），冷却装置（5），形成反应器空间的下边界的气体分布板（6）以及如果需要的分流器（7），其中气体分配板 （6）具有多个出口侧锥形扩大的气流孔（8）。
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公开(公告)号：US20100261870A1
公开(公告)日：2010-10-14
申请号：US12743116
申请日：2008-12-16
IPC分类号： C08G65/26
CPC分类号： C08G65/2609 , C08G65/2672 , C08G65/2696 , Y02P20/582
摘要： The invention provides a process for preparing polyether alcohols by adding alkylene oxides onto H-functional starter substances, of which at least one is solid at room temperature in a reaction vessel, by feeding the starting components continuously to the reaction vessel, which comprises preparing a paste from the solid starter substance and feeding this paste continuously to the reaction vessel.
摘要翻译： 本发明提供了一种制备聚醚醇的方法，其通过将氧化烯加入到H官能起始物质中，其中至少一种在室温下在反应容器中为固体，通过将起始组分连续地加入到反应容器中，其包括制备 从固体起始物质中糊化并将该糊剂连续地送入反应容器。
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公开(公告)号：US07485764B2
公开(公告)日：2009-02-03
申请号：US10526936
申请日：2003-09-18
申请人： Hans Peter Rath , Stephan Hueffer , Gabriele Lang , Arno Lange , Eckard Schauss
发明人： Hans Peter Rath , Stephan Hueffer , Gabriele Lang , Arno Lange , Eckard Schauss
IPC分类号： C07C2/02 , C08F2/00 , C08F4/14 , C08F110/10
CPC分类号： C08F10/10 , C08F110/10 , C08F4/14 , C08F2500/03 , C08F2500/02
摘要： A process for the preparation of polyisobutene containing at least 75 mol % of terminal vinylidene groups, in which isobutene or an isobutene-containing hydrocarbon mixture is polymerized in the liquid phase in the presence of a boron trifluoride complex catalyst having the composition a(BF3):b(Co1):c(Co2) where Co1 is at least one tertiary alcohol, Co2 is at least one compound selected from water, primary alcohols, secondary alcohols, dialkyl ethers, alkanecarboxylic acids and phenols, the ratio c:b is from 0.9 to 1.8 and the ratio (b+c):a is from 0.9 to 3.0, is described.
摘要翻译： 一种制备含有至少75mol％末端亚乙烯基的聚异丁烯的方法，其中异丁烯或含异丁烯的烃混合物在液相中在三氟化硼配合物催化剂存在下聚合，其组成为β- line-formula description =“In-line Formulas”end =“lead”？> a（BF3）：b（Co1）：c（Co2）<？in-line-formula description =“In-line Formulas”end = 尾部“→”，其中Co1为至少一种叔醇，Co 2为选自水，伯醇，仲醇，二烷基醚，链烷羧酸和酚中的至少一种化合物，c：b为0.9至1.8， （b + c）：a为0.9〜3.0。
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公开(公告)号：US5932684A
公开(公告)日：1999-08-03
申请号：US948070
申请日：1997-10-09
申请人： Andreas Deckers , Eckard Schauss
发明人： Andreas Deckers , Eckard Schauss
IPC分类号： C08F210/02 , C07C45/00
CPC分类号： C08F210/02
摘要： A process for preparing keto-functional polyethylene waxes having a molecular weight of from 150 to 1000 g/mol by telomerization of ethylene with aldehydes at from 500 to 5000 bar and from 100 to 280.degree. C., wherein ethylene and aldehyde are employed in a molar ration of from 5:1 to 50:1.
摘要翻译： 通过乙烯与500-5000巴和100-280℃的醛的聚合来制备分子量为150-1000g / mol的酮官能聚乙烯蜡的方法，其中乙烯和醛用于 摩尔比为5：1至50：1。
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公开(公告)号：US20080214762A1
公开(公告)日：2008-09-04
申请号：US11994417
申请日：2006-07-11
申请人： Andreas Bode , Uwe Rachwalsky , Friedrich Sauer , Eckard Schauss , Marco-Christian Volland , Thomas Wettling
发明人： Andreas Bode , Uwe Rachwalsky , Friedrich Sauer , Eckard Schauss , Marco-Christian Volland , Thomas Wettling
CPC分类号： B01F3/1221 , B01F7/00758 , B01J19/1806 , C08F110/10 , C08F2/01 , C08F4/14 , C08F2500/03
摘要： The present invention relates to a process for preparing polyisobutenes by polymerizing isobutene in the presence of a Lewis acid catalyst in liquid organic phase, terminating the reaction by admixing the organic phase with an aqueous terminator in a dynamic mixer which has a rotationally symmetric mixing chamber formed from one circumferential wall and two end walls, and a mixing rotor driven such that it rotates therein, the organic phase being introduced through a first inlet orifice provided in the circumferential wall and the aqueous terminator via a second inlet orifice provided in the circumferential wall, and removing a finely dispersed mixture of the organic phase and of the terminator through an outlet orifice provided in the circumferential wall and feeding it to a phase separation. The process serves to prepare high-reactivity polyisobutenes and/or polyisobutenes with narrow molecular weight distribution.
摘要翻译： 本发明涉及通过在路易斯酸催化剂存在下在液态有机相中聚合异丁烯来制备聚异丁烯的方法，通过在具有旋转对称的混合室形成的动态混合器中混合有机相与水性终止剂来终止反应 从一个圆周壁和两个端壁以及被驱动使得其在其中旋转的混合转子，有机相通过设置在周壁中的第一入口孔和设置在周向壁中的第二入口孔引入， 并通过设置在周壁上的出口孔除去有机相和终止剂的微细分散的混合物并将其送入相分离。 该方法用于制备具有窄分子量分布的高反应性聚异丁烯和/或聚异丁烯。
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公开(公告)号：US06458904B1
公开(公告)日：2002-10-01
申请号：US09485767
申请日：2000-02-17
IPC分类号： C08F464
CPC分类号： C08F10/00 , C08F4/63908 , C08F4/63916 , C08F4/63922 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/63912 , C08F2500/12 , C08F2500/03
摘要： A catalyst composition suitable for the (co)polymerization of alk-1-enes is obtainable by mixing a metallocene complex with a C3-C20-alk-1-ene in an inert solvent, reacting the resulting mixture in a controlled manner with a compound capable of forming metallocenium ions and diluting the resulting mixture with an inert nonpolar, essentially aliphatic solvent, and also, if desired, applying the catalyst composition to a particulate support material.
摘要翻译： 适用于烯-1-烯的（共）聚合的催化剂组合物可通过在惰性溶剂中将茂金属配合物与C 3 -C 20烷-1-烯进行混合而获得，将所得混合物以控制的方式与化合物 能够形成金属茂离子并用惰性非极性基本上脂族的溶剂稀释所得混合物，并且如果需要，将催化剂组合物施加到颗粒状载体材料上。
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公开(公告)号：US06444607B1
公开(公告)日：2002-09-03
申请号：US09423113
申请日：1999-11-02
IPC分类号： B01J3138
CPC分类号： C08F10/00 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F110/02 , Y10S526/943 , C08F4/65908 , C08F2500/12 , C08F2500/03 , C08F2500/23
摘要： A catalyst solution for polymerizing &agr;-olefins is obtainable by reacting a metallocene compound with an activator compound which can react with the metallocene compound so as to displace a ligand from the central atom and stabilize the resulting cationic complex by a non-coordinating anion as an ion pair, adding one or more &agr;-olefins in a molar ratio of metallocene compound: &agr;-olefins of from 1:1 und 1:100 and mixing with at least 10 parts by volume of an aliphatic hydrocarbon.
摘要翻译： 用于聚合α-烯烃的催化剂溶液可通过使茂金属化合物与可与金属茂化合物反应的活化剂化合物反应以使配位体从中心原子置换并通过非配位阴离子稳定得到的阳离子络合物得到 离子对，加入一种或多种摩尔比为1：1和1：100的茂金属化合物：α-烯烃的α-烯烃，并与至少10体积份的脂族烃混合。
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10.发明授权
公开(公告)号：US5880233A
公开(公告)日：1999-03-09
申请号：US957321
申请日：1997-11-06
申请人： Andreas Deckers , Eckard Schauss , Roger Klimesch , Wilhelm Weber
发明人： Andreas Deckers , Eckard Schauss , Roger Klimesch , Wilhelm Weber
IPC分类号： C08F2/00 , C08F4/38 , C08F210/02
CPC分类号： C08F210/02
摘要： Copolymers of ethylene with .alpha.,.beta.-unsaturated carboxylic acids are prepared at from 50.degree. to 250.degree. C. and from 500 to 5000 bar in a stirred autoclave having a length/diameter ratio greater than 5:1 by a process in which the monomer mixtures are fed into the autoclave in at least two part-streams, the first part-stream being passed into the autoclave at the beginning of the autoclave pipe and the second part-stream being introduced at a position which is a distance away from the beginning which corresponds to 25-50% of the total length and the amount of the .alpha.,.beta.-unsaturated carboxylic acids in the first part-stream is from 20 to 90% less than the average amount in the further part-streams and a peroxide polymerization initiator having a lower decomposition temperature, or a mixture of peroxide polymerization initiators having a lower average decomposition temperature, than that of the initiators in the further part-streams is passed in with the first part-stream.
摘要翻译： 乙烯与α，β-不饱和羧酸的共聚物在50至250℃和500至5000巴的条件下通过一种方法制备，所述搅拌高压釜的长度/直径比大于5:1，其中单体 将混合物以至少两部分流进料到高压釜中，第一部分物流在高压釜管道的开始处被送入高压釜中，并且将第二部分物流引入远离开始位置的位置 其对应于总长度的25-50％，并且第一部分流中的α，β-不饱和羧酸的量比另外的部分流中的平均量少20至90％，并且过氧化物聚合 具有较低分解温度的引发剂或具有较低平均分解温度的过氧化物聚合引发剂的混合物比其它部分流中的引发剂的引发剂与第一部分流一起进入。
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