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1.发明授权Bipolar multiple electrolytic cell comprising a diaphragm and electrode for same 失效双极多重电解槽包括隔膜和相同的电极
公开(公告)号：US3941675A
公开(公告)日：1976-03-02
申请号：US454949
申请日：1974-03-26
申请人： Bernd Strasser , Wolfgang Kramer , Luciano Mose , Helmut Hund
发明人： Bernd Strasser , Wolfgang Kramer , Luciano Mose , Helmut Hund
CPC分类号： C25B11/0478 , C25B9/206
摘要： A bipolar multiple electrolytic cell having an alkali-chlorine diaphragm cell for obtaining caustic solution, chlorine and hydrogen in which the titanium metal electrodes act on one side as the anode and on the other as the cathode, the anode side being coated with a metal or metal oxide for activation purposes, and the cathode side having a dense coating of metal alloy of nickel and elements of the Group III or V of the periodic system, which is applied chemically, preferably by employing the so-called "Kanigen" process.
摘要翻译： 一种具有用于获得苛性碱溶液，氯和氢的碱氯隔膜电池的双极多电解槽，其中钛金属电极作为阳极作为一侧，另一面作为阴极，阳极侧涂覆有金属或 金属氧化物用于活化目的，并且阴极侧具有致密的镍金属合金涂层和周期性系统的III或V族元素，其化学施用，优选通过使用所谓的“Kanigen”工艺。
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公开(公告)号：US4017376A
公开(公告)日：1977-04-12
申请号：US542537
申请日：1975-01-20
申请人： Luciano Mose , Wolfgang Kramer , Wolfgang Strewe , Bernd Strasser
发明人： Luciano Mose , Wolfgang Kramer , Wolfgang Strewe , Bernd Strasser
CPC分类号： C25B9/08
摘要： A novel electrolytic cell of the vertical electrode type comprising a novel cathode busbar structure, novel cathode elements and a novel anode base structure which enable the novel electrolytic cell to be designed to operate at high current capacities upward to about 500,000 amperes while maintaining high operating efficiencies. These high current capacities provide for high production capacities which result in high production rates for given cell room floor areas and reduce capital investment and operating costs.
摘要翻译： 一种垂直电极型新型电解槽，包括新颖的阴极母线结构，新颖的阴极元件和新颖的阳极基底结构，使得新型电解池可以设计成在高电流容量下工作在大约500,000安培，同时保持高的工作效率 。 这些高电流能力提供高生产能力，导致给定的房间面积的高生产率，并减少资本投资和运营成本。
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公开(公告)号：US3930978A
公开(公告)日：1976-01-06
申请号：US542650
申请日：1975-01-20
申请人： Wolfgang Strewe , Luciano Mose , Wolfgang Kramer , Bernd Strasser
发明人： Wolfgang Strewe , Luciano Mose , Wolfgang Kramer , Bernd Strasser
CPC分类号： C25B9/045
摘要： A novel circuit of electrolytic cells comprising novel electrolytic cells, novel jumper switches and novel arrangement of the jumper switches referring to the electrolytic cells which enable the novel circuit to be designed to operate at high current capacities upward to about 500,000 amperes while maintaining high operating efficiencies. These high current capacities provide for high production capacities which result in high production rates for given cell room floor areas and reduce capital investment and operating costs.
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公开(公告)号：US4263119A
公开(公告)日：1981-04-21
申请号：US39988
申请日：1979-05-17
申请人： Luciano Mose , Helmut Schurig , Bernd Strasser
发明人： Luciano Mose , Helmut Schurig , Bernd Strasser
CPC分类号： C25B9/20
摘要： An improved anode element for monopolar filter-press electrolysis cells comprises providing said anode element with an integral hollow member positioned above the upper surface of said anode element. Preferably, said hollow member is formed as an integral extension of the electrode frame, said hollow member having an outlet for withdrawing chlorine gas and being adapted to permit continuous fluid contact with said anode element, said hollow member being further adapted to provide sufficient hydrostatic pressure in said anode element for optimal liquid flow through the diaphragm over the entire operating cycle of the electrolysis cell.
摘要翻译： 用于单极压滤电解槽的改进的阳极元件包括提供所述阳极元件，所述阳极元件设置在所述阳极元件的上表面上方的整体中空构件。 优选地，所述中空构件形成为电极框架的整体延伸部，所述中空构件具有用于抽出氯气的出口并且适于允许与所述阳极元件的连续流体接触，所述中空构件还适于提供足够的静水压力 在所述阳极元件中，用于在电解池的整个操作循环中使液体流过隔膜。
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公开(公告)号：US4256562A
公开(公告)日：1981-03-17
申请号：US40018
申请日：1979-05-17
申请人： Luciano Mose , Helmut Schurig , Bernd Strasser
发明人： Luciano Mose , Helmut Schurig , Bernd Strasser
CPC分类号： C25B9/20
摘要： A unitary filter press cell circuit is described. The circuit comprises a plurality of individual electrolytic cells mounted on a support structure positioned parallel to the longitudinal axis of the cell circuit. The longitudinal support structure is comprised of the electrolyte inlet conduits for the cell circuit and the electrolysis product outlet conduits for the cell circuit. The composite unit, cells and support structure, may be moved as a single unit, suitably by hoisting, facilitating the removal from service of a faulty circuit and the subsequent substitution with a replacement circuit. The longitudinal support structure is suitably comprised of conduits or headers for catholyte, anolyte, the anodic products and the cathodic products of the cells in the circuit. Although the conduits may be round or oval in cross-section, conduits of a rectangular cross-section are preferred. In a preferred embodiment, the conduits for the anodic and cathodic products, mixtures of gases and liquids, are preferably of a larger capacity than required for the passage of solely liquid products, thus facilitating a separation of the gaseous and liquid products within the conduit. For example, in the case of the electrolysis of sodium chloride, wherein the anodic product from the individual cells is chlorine gas and aqueous sodium chloride and the cathodic product is hydrogen and an aqueous sodium hydroxide solution, the larger capacity of the cell product outlet conduits facilitates separation of the chlorine product from the brine solution and the hydrogen product from the caustic solution.
摘要翻译： 描述了一体式压滤单元电路。 该电路包括安装在平行于电池电路的纵向轴线定位的支撑结构上的多个独立的电解池。 纵向支撑结构包括用于电池电路的电解液入口导管和用于电池电路的电解产品出口导管。 复合单元，电池和支撑结构可以通过提升而适当地移动为单个单元，从而有助于故障电路的去除以及随后的替换电路的替代。 纵向支撑结构适用于阴极电解液，阳极电解液的导管或集管，电路中的电池的阳极产物和阴极产物。 虽然导管的横截面可以是圆形或椭圆形，但是优选的是矩形横截面的导管。 在优选实施例中，用于阳极和阴极产品的导管，气体和液体的混合物优选地比单独的液体产物通过所需的容量更大，从而有利于气体和液体产物在导管内的分离。 例如，在电解氯化钠的情况下，其中来自各个电池的阳极产物是氯气和氯化钠水溶液，阴极产物是氢气和氢氧化钠水溶液，电池产品出口导管的容量越大 促进氯产物与盐水溶液和氢产物从苛性碱溶液中的分离。
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公开(公告)号：US4207165A
公开(公告)日：1980-06-10
申请号：US39992
申请日：1979-05-17
申请人： Luciano Mose , Helmut Schurig , Bernd Strasser
发明人： Luciano Mose , Helmut Schurig , Bernd Strasser
CPC分类号： C25B9/20
摘要： An improved electrolytic cell of the filter press type in which the electrode gap may initially be set and accurately maintained during assembly of the cell units is described. The cell units consist of a planar anode mounted in a peripheral anode frame, a planar cathode mounted in a peripheral cathode frame, a barrier, such as a diaphragm or membrane, positioned between the anode and cathode, a spacer member and at least one gasket member positioned between the edges of the anode and cathode frames. The total gasket width in an uncompressed state is greater than the thickness of the spacer member. Upon assembly of the unit, the gasket member is compressed forming a gas and liquid seal. The thickness of the spacer member determines the space between the anode and cathode frame members and, consequently, the space or gap between the anodes and cathodes mounted in the frame members.
摘要翻译： 描述了一种改进的压滤型电解槽，其中电极间隙最初可以在组装单元期间被设定和精确地保持。 电池单元由安装在外围阳极框架中的平面阳极，安装在外围阴极框架中的平面阴极，位于阳极和阴极之间的屏障（例如隔膜或膜）组成，隔离构件和至少一个垫圈 位于阳极和阴极框架的边缘之间的构件。 在未压缩状态下的总垫片宽度大于间隔件的厚度。 在组装单元时，垫圈构件被压缩形成气体和液体密封。 间隔构件的厚度确定了阳极和阴极框架构件之间的空间，因此确定了安装在框架构件中的阳极和阴极之间的空间或间隙。
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公开(公告)号：US4196069A
公开(公告)日：1980-04-01
申请号：US39996
申请日：1979-05-17
申请人： Luciano Mose , Helmut Schurig , Bernd Strasser
发明人： Luciano Mose , Helmut Schurig , Bernd Strasser
CPC分类号： C25B9/20
摘要： The present invention provides an electrolyte feed system for feeding an individual supply of electrolyte to electrolytic cells in a filter press cell circuit. The system includes a primary electrolyte feed line, having one closed end and a plurality of outlets, or orifices, therein spaced along the length of the line. The primary feed line is encased in a larger, secondary feed line. The secondary feed line has a plurality of outlets, or orifices, therein spaced along its length corresponding to the outlets in the primary feed line. In a preferred embodiment, the feed lines are circular in cross-section and are in the form of pipes or tubes. The outlets in the primary and secondary feed lines are spacedly aligned, and the outlets in the secondary feed line are communicatively connected with the electrolyte inlets in the cell compartments of the individual cells in the cell circuit. Preferably, the outlets in the secondary feed line and the inlets in the cell compartments are approximately the same size and the outlets in the primary feed line are substantially smaller.In operation, a supply of electrolyte enters the system through the primary feed line and initially fills both the primary feed line and the secondary feed line. The incoming electrolyte is jetted through the smaller outlets of the primary feed line, through the internal space between the primary and secondary feed lines, through the outlets in the secondary feed line and into the electrolyte compartments. The relatively small openings of the outlets in the primary feed line minimize the adverse effect that a drop in pressure in the electrolytic source line would have on the electrolyte level in the electrolyte in the electrolyte compartment of the cell circuit. If the outlets in the primary feed line do become clogged, the electrolyte compartments receive a supply of electrolyte from the secondary feed line.
摘要翻译： 本发明提供一种用于在压滤单元电路中向电解槽供给单独的电解液的电解液供给系统。 该系统包括主要电解液供给管线，其具有一个封闭端和沿管线长度间隔开的多个出口或孔口。 主馈线被封装在更大的二次进料管线中。 二次进料管线具有多个出口或孔，其中沿着其长度对应于主进料管线中的出口间隔开。 在一个优选实施例中，进料管线是横截面为圆形，呈管或管的形式。 初级和二级进料管线中的出口间隔地对齐，并且次级进料管线中的出口与单元电路中各个单元的单元室中的电解质入口连通地连接。 优选地，二次进料管线中的出口和单元室中的入口大致相同的尺寸，并且主进料管线中的出口基本上较小。 在操作中，电解液的供应通过初级进料管线进入系统，并且初始地填充主进料管线和次级进料管线。 输入的电解质通过主进料管线的较小出口通过主进料管线和第二进料管线之间的内部空间，通过第二进料管线中的出口并进入电解质室中。 主馈线中的出口相对较小的开口最小化电解源线中的压力下降对电池电路的电解质隔室中的电解质中的电解质水平的不利影响。 如果主馈线中的出口堵塞，则电解质隔室从二次馈电线接收电解液供应。
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公开(公告)号：US4342630A
公开(公告)日：1982-08-03
申请号：US179903
申请日：1980-08-20
申请人： Wolfgang Strewe , Luciano Mose , Bernd Strasser
发明人： Wolfgang Strewe , Luciano Mose , Bernd Strasser
摘要： Electrolytic cells demonstrate improved performance through use of an internal brine distribution system. A brine distributor located in the interior of the cell and positioned either at the cell bottom or above the cell's electrodes has individual brine outlets for feeding electrolyte directly to each of the cell's anolyte compartments for electrolysis. By comparison with conventional brine feed systems, e.g. cell top feed, the internal brine distributor produces higher purity gas, e.g. chlorine, at reduced power consumption and higher current efficiencies.
摘要翻译： 电解池通过使用内部盐水分配系统表现出改善的性能。 位于细胞内部并位于细胞底部或细胞电极上方的盐水分配器具有单独的盐水出口，用于将电解质直接供给到每个电池的阳极电解液室用于电解。 与常规盐水进料系统相比，例如， 内部盐水分配器产生更高纯度的气体，例如， 氯，功耗降低，电流效率更高。
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公开(公告)号：US4299681A
公开(公告)日：1981-11-10
申请号：US118560
申请日：1980-02-04
申请人： Luciano Mose , Helmuth Schurig , Bernd Strasser
发明人： Luciano Mose , Helmuth Schurig , Bernd Strasser
CPC分类号： C25B9/206
摘要： Hydrochloric acid electrolyzers serve to decompose hydrochloric acid to hydrogen and chlorine with the aid of electric current.
摘要翻译： 盐酸电解槽用于借助电流将盐酸分解成氢和氯。
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公开(公告)号：US4253932A
公开(公告)日：1981-03-03
申请号：US39991
申请日：1979-05-17
申请人： Luciano Mose , Helmut Schurig , Bernd Strasser
发明人： Luciano Mose , Helmut Schurig , Bernd Strasser
CPC分类号： C25B9/206
摘要： A unitary frame and membrane assembly particularly useful in a filter press electrolytic cell arrangement is provided by the present invention. The assembly comprises a rigid, peripheral frame member having separable peripheral frame portions. A permselective membrane member is positioned between the separable peripheral frame portions, and the membrane member and frame portions are secured together to form a unitary frame and membrane assembly. The present assembly is adapted for use as the barrier component in electrolytic cells which utilize a separatory membrane barrier between the cell electrodes.
摘要翻译： 本发明提供了一种特别适用于压滤机电解槽装置的整体框架和膜组件。 组件包括具有可分离的外围框架部分的刚性的外围框架构件。 透视膜构件位于可分离的外围框架部分之间，并且膜构件和框架部分固定在一起以形成整体框架和膜组件。 本发明的组件适用于在电池中使用隔离膜屏障的电解槽中的屏障组件。
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