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公开(公告)号：US09163174B2
公开(公告)日：2015-10-20
申请号：US13345285
申请日：2012-01-06
申请人： Bert Alleyne , Bin Ma , Alan DeAngelis
发明人： Bert Alleyne , Bin Ma , Alan DeAngelis
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H05B33/10
摘要： Novel phosphorescent heteroleptic iridium complexes with substituted phenylquinoline ligands are provided. The alkyl substitution on the phenylquinoline ligands together with larger alkyl substituents on the acetylacetone-derived ligands produces complexes with improved properties that are useful when incorporated into OLED devices.
摘要翻译： 提供了具有取代苯基喹啉配体的新型磷光荧光铱络合物。 苯基喹啉配体上的烷基取代与乙酰丙酮衍生的配体上较大的烷基取代基一起产生具有改进的性质的复合物，其在掺入OLED器件中时是有用的。
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公开(公告)号：US20130169148A1
公开(公告)日：2013-07-04
申请号：US13345285
申请日：2012-01-06
申请人： Bert Alleyne , Bin Ma , Alan DeAngelis
发明人： Bert Alleyne , Bin Ma , Alan DeAngelis
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H05B33/10
摘要： Novel phosphorescent heteroleptic iridium complexes with substituted phenylquinoline ligands are provided. The alkyl substitution on the phenylquinoline ligands together with larger alkly substituents on the acetylacetone-derived ligands produces complexes with improved properties that are useful when incorporated into OLED devices.
摘要翻译： 提供了具有取代苯基喹啉配体的新型磷光荧光铱络合物。 苯基喹啉配体上的烷基取代与乙酰丙酮衍生的配体上的较大的烷基取代基产生具有改进的性质的复合物，其在掺入OLED器件中时是有用的。
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公开(公告)号：US09512355B2
公开(公告)日：2016-12-06
申请号：US13316162
申请日：2011-12-09
申请人： Bin Ma , Alan DeAngelis , Chuanjun Xia
发明人： Bin Ma , Alan DeAngelis , Chuanjun Xia
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/025 , C09K11/06 , C09K2211/1029 , C09K2211/185 , H01L51/0072 , H01L51/5016 , H01L51/5024 , H01L51/5056 , H01L51/5072 , H01L51/5088 , H01L51/5092 , H01L51/5096 , H05B33/14
摘要： Novel phosphorescent metal complexes containing 2-phenylisoquinoline ligands with at least two substituents on the isoquinoline ring are provided. The disclosed compounds have low sublimation temperatures that allow for ease of purification and fabrication into a variety of OLED devices.
摘要翻译： 提供了含有在异喹啉环上具有至少两个取代基的2-苯基异喹啉配体的新型磷光金属络合物。 所公开的化合物具有低升华温度，其允许易于纯化和制造成各种OLED器件。
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公开(公告)号：US09847495B2
公开(公告)日：2017-12-19
申请号：US14113530
申请日：2012-06-06
申请人： Chun Lin , Chuanjun Xia , Bin Ma , Lichang Zeng , Alan DeAngelis , Edward Barron
发明人： Chun Lin , Chuanjun Xia , Bin Ma , Lichang Zeng , Alan DeAngelis , Edward Barron
CPC分类号： H01L51/0085 , C07F15/0033 , H01L51/0072 , H01L51/50 , H01L51/5012 , H01L51/5016
摘要： Novel heteroleptic iridium carbene complexes are provided, which contain phenyl imidazole moieties. In particular, ligands containing 2,4,6-trisubstituted N-phenyl imidazole fragments have highly desirable properties that make them suitable materials for use in OLED devices.
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5.发明申请5-Substituted 2 Phenylquinoline Complexes Materials for Light Emitting Diode 有权5-取代的2苯基喹啉配合物用于发光二极管的材料公开(公告)号：US20120181511A1
公开(公告)日：2012-07-19
申请号：US13006016
申请日：2011-01-13
申请人： Bin Ma , Alan DeAngelis , Chuanjun Xia , Vadim Adamovich
发明人： Bin Ma , Alan DeAngelis , Chuanjun Xia , Vadim Adamovich
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/1029 , C09K2211/185 , H01L51/5016
摘要： Compounds are provided that comprise a ligand having a 5-substituted 2-phenylquinoline. In particular, the 2-phenylquinoline may be substituted with a bulky alkyl at the 5-position. These compounds may be used in organic light emitting devices, in particular as red emitters in the emissive layer of such devices, to provide devices having improved properties.
摘要翻译： 提供了包含具有5-取代的2-苯基喹啉的配体的化合物。 特别地，2-苯基喹啉可以在5位被大体积烷基取代。 这些化合物可以用于有机发光器件，特别是在这种器件的发射层中的红色发射体，以提供具有改进性能的器件。
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公开(公告)号：US09190621B2
公开(公告)日：2015-11-17
申请号：US13872364
申请日：2013-04-29
申请人： Bin Ma , Alan DeAngelis
发明人： Bin Ma , Alan DeAngelis
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/1029 , C09K2211/185 , H01L51/0081 , H01L51/5016
摘要： Organometallic compounds comprising a phenylquinoline or phenylisoquinoline ligand having the quinoline or isoquinoline linked to the phenyl ring of the phenylquinoline or phenylisoquinoline, respectively, via two carbon atoms. These compounds also comprise a substituent other than hydrogen and deuterium on the quinoline, isoquinoline or linker. These compounds may be used as red emitters in phosphorescent OLEDs. In particular, these compounds may provide stable, narrow and efficient red emission.
摘要翻译： 包含分别通过两个碳原子与苯基喹啉或苯基异喹啉的苯环连接的喹啉或异喹啉的苯基喹啉或苯基异喹啉配体的有机金属化合物。 这些化合物还包含喹啉，异喹啉或连接体上除氢和氘之外的取代基。 这些化合物可以用作磷光OLED中的红色发射体。 特别地，这些化合物可以提供稳定，窄而有效的红色发射。
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7.发明授权5-substituted 2 phenylquinoline complexes materials for light emitting diode 有权用于发光二极管的5-取代的2-苯基喹啉络合物材料公开(公告)号：US09130177B2
公开(公告)日：2015-09-08
申请号：US13006016
申请日：2011-01-13
申请人： Bin Ma , Alan DeAngelis , Chuanjun Xia , Vadim Adamovich
发明人： Bin Ma , Alan DeAngelis , Chuanjun Xia , Vadim Adamovich
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/1029 , C09K2211/185 , H01L51/5016
摘要： Compounds are provided that comprise a ligand having a 5-substituted 2-phenylquinoline. In particular, the 2-phenylquinoline may be substituted with a bulky alkyl at the 5-position. These compounds may be used in organic light emitting devices, in particular as red emitters in the emissive layer of such devices, to provide devices having improved properties.
摘要翻译： 提供了包含具有5-取代的2-苯基喹啉的配体的化合物。 特别地，2-苯基喹啉可以在5位被大体积烷基取代。 这些化合物可以用于有机发光器件，特别是在这种器件的发射层中的红色发射体，以提供具有改进性能的器件。
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公开(公告)号：US20130328019A1
公开(公告)日：2013-12-12
申请号：US13542868
申请日：2012-07-06
申请人： Chuanjun Xia , Bin Ma , Alan DeAngelis
发明人： Chuanjun Xia , Bin Ma , Alan DeAngelis
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1029 , C09K2211/1044 , C09K2211/185 , H01L51/0085 , H01L51/0087 , H01L51/5016 , H05B33/14
摘要： Compounds comprising the formula L1L2MX wherein L1, L2, and X are distinct bidentate ligands that form an octahedral complex on the metal M, wherein M is a metal with an atomic weight greater than 40. Compounds of this formula are sublimated more facilely than octahedral metal complexes where L1, L2, and X are not distinct bidentate ligands. Organic light emitting devices are also described wherein the emissive layer may comprise a host material containing an emissive molecule of formula L1L2MX, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including iridium complexes of the formula L1L2IrX wherein L1, L2, and X are distinct bidentate ligands.
摘要翻译： 包含式L1L2MX的化合物，其中L1，L2和X是在金属M上形成八面体配合物的不同二齿配体，其中M是原子量大于40的金属。该式的化合物比八面体金属更容易升华 其中L1，L2和X不是明显的二齿配体的络合物。 还描述了有机发光器件，其中发射层可以包含含有式L1L2MX的发射分子的主体材料，该分子适于在跨异质结构施加电压时发光，并且发射分子选自磷光 有机金属络合物，包括式L1L2IrX的铱络合物，其中L1，L2和X是不同的二齿配体。
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公开(公告)号：US09812656B2
公开(公告)日：2017-11-07
申请号：US14113533
申请日：2012-06-06
申请人： Chun Lin , Chuanjun Xia , Bin Ma , Lichang Zeng , Alan DeAngelis , Edward Barron
发明人： Chun Lin , Chuanjun Xia , Bin Ma , Lichang Zeng , Alan DeAngelis , Edward Barron
CPC分类号： H01L51/0085 , C07F15/0033 , H01L51/0072 , H01L51/50 , H01L51/5012 , H01L51/5016
摘要： Novel heteroleptic iridium carbene complexes are provided. The complexes have lower-than expected sublimation temperatures, which is beneficial for the processing of these materials in solid state applications. Selective substitution of the ligands provides for phosphorescent compounds that are suitable for use in a variety of OLED devices. The carbene complexes can also be used as materials in a hole blocking layer and/or an electron transport layer to improve device performance.
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公开(公告)号：US09670404B2
公开(公告)日：2017-06-06
申请号：US13542868
申请日：2012-07-06
申请人： Chuanjun Xia , Bin Ma , Alan DeAngelis
发明人： Chuanjun Xia , Bin Ma , Alan DeAngelis
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1029 , C09K2211/1044 , C09K2211/185 , H01L51/0085 , H01L51/0087 , H01L51/5016 , H05B33/14
摘要： Compounds comprising the formula L1L2MX wherein L1, L2, and X are distinct bidentate ligands that form an octahedral complex on the metal M, wherein M is a metal with an atomic weight greater than 40. Compounds of this formula are sublimated more facilely than octahedral metal complexes where L1, L2, and X are not distinct bidentate ligands. Organic light emitting devices are also described wherein the emissive layer may comprise a host material containing an emissive molecule of formula L1L2MX, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including iridium complexes of the formula L1L2IrX wherein L1, L2, and X are distinct bidentate ligands.
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