摘要:
Copolyester with improved transition temperature, melting temperature and crystallinity including units derived from lactic acid and isosorbide, where the ratio of lactic acid to isosorbide ranges from 99:1 to 50:50.
摘要:
A process for the synthesis of 100% optically pure L(+)-lactide catalyzed by zinc and tin metal catalysts of less than 150 micron particle size is disclosed. The L-lactide obtained was further purified to obtain lactide of 100% optical purity and acid impurities less than 10 meq/kg.
摘要:
A process for the synthesis of 100% optically pure L(+)-lactide catalyzed by zinc and tin metal catalysts of less than 150 micron particle size is disclosed. The L-lactide obtained was further purified to obtain lactide of 100% optical purity and acid impurities less than 10 meq/kg.
摘要:
Copolyester with improved transition temperature, melting temperature and crystallinity including units derived from lactic acid and isosorbide, where the ratio of lactic acid to isosorbide ranges from 99:1 to 50:50.
摘要:
The present invention relates to novel N-Poly (alkenyl) acryl amides of formula (1) where in m=1-8, n=2-100 and to a process for preparation thereof and process for preparation thereof by reacting an unsaturated poly(olefin) of the formula CnH2m where n and m are as given above with acrylonitrile in presence of an acid catalyst.
摘要:
A novel compound bearing urethane linkage of formula as shown herebelow, which is an adduct of ricinoleic ester and isocyanate, useful as a plasticizer for polyvinylchloride (PVC) and a process for the preparing the compound bearing urethane linkage by reacting fatty acid esters bearing hydroxyl groups with an organic isocyanate in die presence of a catalyst at a temperature in the range of 30.degree.-100.degree. C. ##STR1##
摘要:
The present invention relates to novel N-Poly (alkenyl) acryl amides of formula (1) wherein m=1-8, n=2-100 and to a process for preparation thereof and process for preparation thereof by reacting an unsaturated poly(olefin) of the formula CnH2m where n and m are as given above with acrylonitrile in presence of an acid catalyst.
摘要:
A novel compound bearing urethane linkage of formula as shown herebelow, which is an adduct of ricinoleic ester and isocyanate, useful as a plasticizer for polyvinylchloride (PVC) and a process for the preparing the compound bearing urethane linkage by reacting fatty acid esters bearing hydroxyl groups with an organic isocyanate in the presence of a catalyst at a temperature in the range of 30°-100° C.
摘要:
A process for the preparation of mono-alkylcarbonate of bisphenols of the formula ##STR1## wherein R.sub.1 represents ispropylidene, hexa-fluoroisopropylidene, cyclohexane, sulphone, ketone, ether, phthaline, phthalimide and R.sub.2 represents an alkyl group with 1-8 carbon atoms the alkyl group being ethyl, propyl, butyl, hexyl, isopropyl, iso-butyl, tert-butyl, cyclohexyl which comprises reacting bisphenols of the formula ##STR2## where R.sub.1 represents ispropylidene, hexa-fluoroisopropylidene, cyclohexane, sulphone, ketone, ether, phthaline, phthalimide with dialkylcarbonates in presence of a catalyst selected from organometallic compounds of tin and titanium under inert atmosphere at a temperature in the range of 80.degree.-150.degree.C.
摘要:
This invention relates to a process for the production of 3,3′,4,4′-tetraminobiphenyl (TAB) of formula (1) from non-carcinogenic raw materials, employing Suzuki type biaryl coupling as the key step. More particularly, it relates to a three steps process for the production of TAB comprising biaryl aryl coupling of 2-nitro-4-bromoacetamide (NBA) of formula (2) catalyzed by sulfilimine based palladacycles as catalysts followed by the basic hydrolysis of acetyl group and the reduction of nitro groups with conventional reducing agents.