Process for the preparation of mono-alkylcarbonate of bisphenols
    8.
    发明授权
    Process for the preparation of mono-alkylcarbonate of bisphenols 失效
    制备双酚单烷基碳酸酯的方法

    公开(公告)号:US5627301A

    公开(公告)日:1997-05-06

    申请号:US219497

    申请日:1994-03-29

    IPC分类号: C07C68/06

    CPC分类号: C07C68/06

    摘要: A process for the preparation of mono-alkylcarbonate of bisphenols of the formula ##STR1## wherein R.sub.1 represents ispropylidene, hexa-fluoroisopropylidene, cyclohexane, sulphone, ketone, ether, phthaline, phthalimide and R.sub.2 represents an alkyl group with 1-8 carbon atoms the alkyl group being ethyl, propyl, butyl, hexyl, isopropyl, iso-butyl, tert-butyl, cyclohexyl which comprises reacting bisphenols of the formula ##STR2## where R.sub.1 represents ispropylidene, hexa-fluoroisopropylidene, cyclohexane, sulphone, ketone, ether, phthaline, phthalimide with dialkylcarbonates in presence of a catalyst selected from organometallic compounds of tin and titanium under inert atmosphere at a temperature in the range of 80.degree.-150.degree.C.

    摘要翻译: 制备式IMAMA的双酚的单烷基碳酸酯的方法,其中R1表示亚丙基,六氟异亚丙基,环己烷,砜,酮,醚,邻苯二甲酰亚胺,邻苯二甲酰亚胺,R 2表示具有1-8个碳原子的烷基 烷基是乙基,丙基,丁基,己基,异丙基,异丁基,叔丁基,环己基,其包括使式IMAMA的双酚反应其中R1表示亚丙基,六氟异亚丙基,环己烷,砜,酮,醚,邻苯二甲酰 邻苯二甲酰亚胺与二烷基碳酸酯在催化剂存在下,在惰性气氛下,在80-150℃的温度范围内,选自锡和钛的有机金属化合物。