公开(公告)号：US07456308B2

公开(公告)日：2008-11-25

申请号：US10585154

申请日：2004-12-17

申请人： Binh Thanh Nguyen ,  Curtis John Bedbury ,  Roger Edwin Humburg ,  Susan Mary Jacob ,  Sarah Jane Ratcliff ,  John Dennis Waterman

发明人： Binh Thanh Nguyen ,  Curtis John Bedbury ,  Roger Edwin Humburg ,  Susan Mary Jacob ,  Sarah Jane Ratcliff ,  John Dennis Waterman

IPC分类号： C07F7/04

CPC分类号： C07F7/122 ,  C07B49/00

摘要： A Grignard process for preparing phenyl-containing chlorosilane products, in particular diphenylchlorosilanes, is carried out in three embodiments. In the first embodiment, the reactants of the Grignard process are a phenyl Grignard reagent, an ether solvent, a trichlorosilane, and an aromatic hydrocarbon coupling solvent. In the second embodiment, the reactants of the Grignard process are a phenyl Grignard reagent, an ether solvent, a phenylchlorosilane, and an aromatic hydrocarbon coupling solvent. In the third embodiment, the reactants of the Grignard process are a phenyl Grignard reagent, an ether solvent, a trichlorosilane, a phenylchlorosilane, and an aromatic hydrocarbon coupling solvent. In each embodiment, the reactants are present in a particular mole ratio.

摘要翻译： 用于制备含苯基氯硅烷产物，特别是二苯基氯硅烷的格氏法是在三个实施方案中进行的。 在第一实施方案中，格氏法的反应物是苯基格氏试剂，醚溶剂，三氯硅烷和芳族烃偶合溶剂。 在第二实施方案中，格氏法的反应物是苯基格氏试剂，醚溶剂，苯基氯硅烷和芳族烃偶联溶剂。 在第三实施方案中，格氏法的反应物是苯基格氏试剂，醚溶剂，三氯硅烷，苯基氯硅烷和芳烃耦合溶剂。 在每个实施方案中，反应物以特定的摩尔比存在。