摘要:
Multilayered barrier film products providing gas and moisture barrier properties. The film products comprise at least a first polymer film having low permeability to moisture and a heterogeneous polymer blend film containing a gas barrier polymer and a second polymer distributed in the gas barrier polymer, so as to allow the heterogeneous polymer blend film to adhere to the first polymer film. A method for the preparation of multilayered barrier film products includes the steps of forming a gas barrier polymer film from a heterogeneous polymer blend containing a gas barrier polymer and a second polymer and, bonding a moisture barrier polymer film to at least one side of the gas barrier polymer film. The method can be practiced utilizing conventional coextrusion equipment.
摘要:
A polyamide is produced by polymerizing at least one of an alpha, beta-unsaturated carboxylic acid and ammonia, an ammonium salt of an alpha, beta-unsaturated carboxylic acid, an alpha, beta-unsaturated nitrile and water, a beta-amino propionic acid or alkyl derivative thereof and an alpha, beta-unsaturated amide and ammonia in the presence of a catalyst comprising a pentaammine cobalt (III) complex.
摘要:
Nylon-type polyamides are produced by the polycondensation of a non-wholly aromatic diacid and diamine in the presence of a poly(ethylene oxide) matrix.
摘要:
The process for manufacturing a spinnable polyamide from a dinitrile, a diamine, water and a catalyst is improved by using as a catalyst a metal salt of an oxygenated phosphorus compound. For example, high quality nylon-6,6 is manufactured by contacting adiponitrile, hexamethylene diamine, water and disodium phosphite at an elevated temperature and pressure.
摘要:
A polymer blend comprises a high nitrile polymer and a compatible polyolefin functionalized with an unsaturated compound selected from the group consisting of unsaturated carboxylic acids, esters, anhydrides and imides. Such blends can be used to form films and membranes having improved thermal, mechanical and optical properties. The blend combines the low oxygen permeability of high nitrile polymers with the low water vapor permeability of the polyolefins and are, therefore, useful in the packaging industry. A method for forming blends of high nitrile polymers with polyolefins includes the step of functinalizing a polyolefin prepared from a monoolefin having from 2 to about 6 carbon atoms with an unsaturated compound selected from the group consisting of unsaturated carboxylic acids, esters, anhydrides and imides and blending from about 99 to 1 parts by weight of the functionalized polyolefin with from about 1 to 99 parts by weight of the high nitrile polymer.
摘要:
A polyamide is produced by polymerizing at least one of alpha, beta unsaturated carboxylic acid, an ammonium salt of an alpha, beta unsaturated carboxylic acid, an alpha, beta unsaturated nitrile and water, a beta-amino propionic acid or alkyl derivative thereof and an alpha, beta unsaturated amide and ammonia in the presence of a catalyst containing cobalt. Preferred catalysts comprise cobaltous carboxylates and cobaltic salts of the enol of beta-di-ketones.
摘要:
A process for the stabilization of indene against discoloration comprising adding to the indene a minor amount of an insoluble compound selected from the group consisting of neutral, acidic and basic inorganic salts, inorganic acids and organic acids.
摘要:
A process for fabricating multilayered high barrier film products providing gas and moisture barrier properties is provided. The film products comprise at least a first polymer film having low permeability to moisture and a polymer blend film containing a gas barrier polymer and a second polymer functionalized for compatibility with the gas barrier polymer and so as to allow the polymer blend film to adhere to the first polymer film. A method for the preparation of multilayered high barrier film products includes the steps of forming a gas barrier polymer film from a polymer blend containing a gas barrier polymer and a second polymer and, bonding a moisture barrier polymer film to at least one side of the gas barrier film.