POLYMER PREPARATION
    1.
    发明申请
    POLYMER PREPARATION 审中-公开
    聚合物制备

    公开(公告)号:US20030040595A2

    公开(公告)日:2003-02-27

    申请号:US10090474

    申请日:2002-03-04

    Abstract: Abstract of DisclosureA process for preparing a conjugated polymer, which comprises polymerizing in a reaction mixture (a) an aromatic monomer having at least two reactive boron derivative groups selected from a boronic acid group, a boronic ester group and a borane group, and an aromatic monomer having at least two reactive halide functional groups; or (b) an aromatic monomer having one reactive halide functional group and one reactive boron derivative group selected from a boronic acid group, a boronic ester group and a borane group, wherein the reaction mixture comprises a catalytic amount of a palladium catalyst, and an organic base in an amount sufficient to convert the reactive boron derivative groups into -B(OH)3- anions.

    Abstract translation: 一种共轭聚合物的制备方法,其包括在反应混合物中聚合(a)具有至少两个选自硼酸基团的反应性硼衍生物基团的芳族单体, ,硼酸酯基和硼烷基,以及具有至少两个反应性卤化物官能团的芳族单体; 或(b)具有一个反应性卤化物官能团和一个选自硼酸基团,硼酸酯基团和硼烷基团的反应性硼衍生物基团的芳族单体,其中反应混合物包含催化量的钯催化剂,和 有机碱的量足以将活性硼衍生物基团转化为-B(OH)3-阴离子。

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