Solid polymeric electrolytes for lithium batteries
    1.
    发明申请
    Solid polymeric electrolytes for lithium batteries 有权
    用于锂电池的固体高分子电解质

    公开(公告)号:US20040053137A1

    公开(公告)日:2004-03-18

    申请号:US10311644

    申请日:2003-09-19

    Abstract: Novel conductive polyanionic polymers and methods for their preparion are provided. The polyanionic polymers comprise repeating units of weakly-coordinating anionic groups chemically linked to polymer chains. The polymer chains in turn comprise repeating spacer groups. Spacer groups can be chosen to be of length and structure to impart desired electrochemical and physical properties to the polymers. Preferred embodiments are prepared from precursor polymers comprising the Lewis acid borate tri-coordinated to a selected ligand and repeating spacer groups to form repeating polymer chain units. These precursor polymers are reacted with a chosen Lewis base to form a polyanionic polymer comprising weakly coordinating anionic groups spaced at chosen intervals along the polymer chain. The polyanionic polymers exhibit high conductivity and physical properties which make them suitable as solid polymeric electrolytes in lithium batteries, especially secondary lithium batteries.

    Abstract translation: 提供了新的导电聚阴离子聚合物及其制备方法。 聚阴离子聚合物包含与聚合物链化学连接的弱配位阴离子基团的重复单元。 聚合物链依次包含重复的间隔基团。 间隔基团可以选择为长度和结构以赋予聚合物所需的电化学和物理性质。 优选实施方案由包含与选定配体三配位的路易斯酸硼酸盐的前体聚合物制备,并重复间隔基以形成重复的聚合物链单元。 这些前体聚合物与选择的路易斯碱反应以形成聚阴离子聚合物,其包含沿着聚合物链以选定间隔间隔的弱配位阴离子基团。 聚阴离子聚合物表现出高导电性和物理性能,使其适用于锂电池,特别是二次锂电池中的固体聚合物电解质。

    Polythiophenes and devices thereof
    2.
    发明申请
    Polythiophenes and devices thereof 有权
    聚噻吩及其装置

    公开(公告)号:US20030166829A1

    公开(公告)日:2003-09-04

    申请号:US10042360

    申请日:2002-01-11

    Abstract: A polythiophene wherein the monomer segments thereof contain 1 wherein A is a side chain; B is hydrogen or a side chain; and D is a divalent segment, and wherein the number of A-substituted thienylene units (I) in the monomer segments is from about 1 to about 10, the number of B-substituted thienylene units (II) is from 0 to about 5, and the number of divalent segments D is 0 or 1.

    Abstract translation: 聚噻吩,其中单体链段含有其中A是侧链; B是氢或侧链; D是二价段,单体链段中的A取代的亚噻吩基单元(I)的数量为约1至约10,B-取代的亚噻吩基单元(II)的数目为0至约5, 并且二价段D的数目为0或1。

    THERMOSET AND CERAMIC CONTAINING SILICON AND BORON
    4.
    发明申请
    THERMOSET AND CERAMIC CONTAINING SILICON AND BORON 有权
    热固性陶瓷和含有硅和陶瓷的陶瓷

    公开(公告)号:US20040132945A1

    公开(公告)日:2004-07-08

    申请号:US10254938

    申请日:2002-09-26

    CPC classification number: C08G79/08

    Abstract: A thermoset polymer has a repeating unit comprising at least one crosslinking group having at least one unsaturated carbon-carbon bond and at least two crosslinking bonds, at least one borate group, at least one silyl group and/or at least one siloxyl group. The thermoset polymer of the present invention may be prepared by reacting a first compound having at least one alkynyl group, and at least one group selected from silyl groups and siloxyl groups, with a second compound selected from boric acid, hydrocarbon boronic acid, hydrocarbon borate, and pyroboric acid under reaction conditions sufficient to crosslink a sufficient number of alkyne bonds to form the thermoset polymer. The thermoset polymer of the present invention possesses both the processability of an organic polymer and the thermal and oxidative stability of an inorganic polymer. The thermoset polymer of the present invention may be further processed into a ceramic material by pyrolysis.

    Abstract translation: 热固性聚合物具有包含至少一个具有至少一个不饱和碳 - 碳键和至少两个交联键,至少一个硼酸酯基,至少一个甲硅烷基和/或至少一个硅氧烷基的交联基团的重复单元。 本发明的热固性聚合物可以通过使具有至少一个炔基的第一化合物和至少一种选自甲硅烷基和硅氧烷基的基团与选自硼酸,烃硼酸,硼酸氢硼酸的第二化合物反应来制备 和焦硼酸在足以交联足够数量的炔键以形成热固性聚合物的反应条件下进行。 本发明的热固性聚合物具有有机聚合物的加工性和无机聚合物的热和氧化稳定性。 本发明的热固性聚合物可以通过热解进一步加工成陶瓷材料。

    (Partially) conjugated polymer process for its preparation and use in electroluminescent devices
    5.
    发明申请
    (Partially) conjugated polymer process for its preparation and use in electroluminescent devices 有权
    (部分)共轭聚合物方法,用于其在电致发光器件中的制备和应用

    公开(公告)号:US20040077824A1

    公开(公告)日:2004-04-22

    申请号:US10468719

    申请日:2003-10-14

    Abstract: A polymer for use in an optical device comprising one or more regions, where the or each region comprises (i) a first structural unit having general formula I: where mnull1 or 2 and which contains at least one substituent, and the at least one substituent is selected from the group consisting of an alkyl, alkoxy, aryl, aryloxy, heteroaryl and heteroaryloxy groups, each of which may be further substituted; and (ii) a second structural unit Ar selected from the group consisting of heteroaryl, triarylamine and/or 2,7-fluorenyl; such that where mnull1 the or each region comprises a unit having general formula II: wherein, the at least one substituent has a molecular weight of less than 300.

    Abstract translation: 一种用于包括一个或多个区域的光学器件的聚合物,其中所述或每个区域包含(i)具有通式I的第一结构单元:其中m = 1或2,并且其包含至少一个取代基,并且至少 一个取代基选自烷基,烷氧基,芳基,芳氧基,杂芳基和杂芳氧基,其中每一个可以进一步被取代; 和(ii)选自杂芳基,三芳基胺和/或2,7-芴基的第二结构单元Ar; 使得当m = 1时,该区域或每个区域包含具有通式II的单元:其中,所述至少一个取代基具有小于300的分子量。

    Conductive polymeric compositions for lithium batteries
    7.
    发明申请
    Conductive polymeric compositions for lithium batteries 有权
    锂电池用导电聚合物组合物

    公开(公告)号:US20040054126A1

    公开(公告)日:2004-03-18

    申请号:US10311643

    申请日:2003-09-03

    Abstract: Novel chain polymers comprising weakly basic anionic moieties chemically bound into a polyether backbone at controllable anionic separations are presented. Preferred polymers comprise orthoborate anions capped with dibasic acid residues, preferably oxalato or malonato acid residues. The conductivity of these polymers is found to be high relative to that of most conventional salt-in-polymer electrolytes. The conductivity at high temperatures and wide electrochemical window make these materials especially suitable as electrolytes for rechargeable lithium batteries.

    Abstract translation: 提出了包含弱碱性阴离子部分的新型链状聚合物,其以可控的阴离子分离化学键合到聚醚主链中。 优选的聚合物包括用二元酸残基(优选草酸或丙二酸残基)封端的原硼酸根阴离子。 发现这些聚合物的电导率相对于大多数常规的聚合物电解质的电导率高。 在高温和宽电化学窗口的电导率使这些材料特别适合用作可再充电锂电池的电解质。

    Process for manufacturing boron nitride fibres from borylborazines
    8.
    发明申请
    Process for manufacturing boron nitride fibres from borylborazines 失效
    硼硼烷制造氮化硼纤维的工艺

    公开(公告)号:US20040044162A1

    公开(公告)日:2004-03-04

    申请号:US10347452

    申请日:2003-01-21

    Abstract: The aim of the present invention is a process for manufacturing boron nitride fibres, in particular continuous boron nitride fibres with good mechanical properties, which may be used for producing ceramic composite materials such as BN/BN composites, thermostructural parts or antenna radomes. It provides and uses a precursor polymer of formula (I) below: 1 in which n is a whole number, R1 and R2, identical or different, represent independently an alkyl group, and R3 represents an amino group, a hydrogen atom, an alkyl, a cycloalkyl or a boryl.

    Abstract translation: 本发明的目的是制备氮化硼纤维,特别是具有良好机械性能的连续氮化硼纤维的方法,其可用于制备陶瓷复合材料如BN / BN复合材料,热结构部件或天线天线罩。 它提供并使用下式(I)的前体聚合物:其中n是整数,R 1和R 2相同或不同,独立地表示烷基,R 3表示氨基 基团,氢原子,烷基,环烷基或硼基。

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