公开(公告)号：US20130225820A1

公开(公告)日：2013-08-29

申请号：US13860604

申请日：2013-04-11

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun DING ,  Albert P. MASINO ,  Joel L. MARTIN ,  Youlu YU

IPC: C07F11/00

CPC classification number: C07F11/00 ,  B01D71/26 ,  B01J31/00 ,  C07F17/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/03 ,  C08J5/18 ,  C08F4/69 ,  C08F4/78 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26

Abstract: A catalyst system comprising a half-sandwich chromium complex, an activator support and an optional cocatalyst. A compound of formula Cp′Cr(Cl)2(Ln), where Cp′ is η5-C5H4CH2CH2CH═CH2 and Ln is pyridine, THF or diethylether. A compound of formula Cp″Cr(Cl)2(Ln), where Cp″ is η5-C5H4C(Me)2CH2CH2CH═CH2 and Ln is pyridine, THF or diethylether.

Abstract translation: 包含半夹心铬复合物，活化剂载体和任选的助催化剂的催化剂体系。 式Cp'Cr（Cl）2（Ln）的化合物，其中Cp'是eta5-C5H4CH2CH2CH = CH2，Ln是吡啶，THF或乙醚。 式Cp''Cr（Cl）2（Ln）的化合物，其中Cp“是eta5-C5H4C（Me）2CH2CH2CH = CH2，Ln是吡啶，THF或二乙醚。

公开(公告)号：US20140275462A1

公开(公告)日：2014-09-18

申请号：US13799471

申请日：2013-03-13

Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP

Inventor： Qing YANG ,  Max P. MCDANIEL ,  Joel L. MARTIN ,  Tony R. CRAIN ,  Steve M. WHARRY ,  Carlos A. CRUZ ,  Jared L. BARR ,  Youlu YU

IPC: C08F10/02

Abstract: An ethylene polymer having a density greater than about 0.930 g/ml and a level of long chain branching ranging from about 0.001 LCB/103 carbons to about 1.5 LCB/103 carbons as determined by SEC-MALS. An ethylene polymer having a level of short chain branching ranging from about 0 to about 10 mol. % and a level of long chain branching ranging from about 0.001 LCB/103 carbons to about 1.5 LCB/103 carbons as determined by SEC-MALS. An ethylene polymer having a polydispersity index ranging from about 8 to about 25 and a level of long chain branching ranging from about 0.001 LCB/103 carbons to about 1.5 LCB/103 carbons as determined by SEC-MALS.

Abstract translation: 通过SEC-MALS测定的密度大于约0.930g / ml的乙烯聚合物和长链支化水平为约0.001LCB / 103碳至约1.5LCB / 103碳。 具有约0至约10mol的短链支化水平的乙烯聚合物。 ％和水平的长链支化范围为约0.001 LCB / 103碳至约1.5 LCB / 103碳，由SEC-MALS确定。 通过SEC-MALS测定的具有约8至约25的多分散指数和长链支化水平从约0.001LCB / 103碳至约1.5LCB / 103碳的乙烯聚合物。