公开(公告)号：US09315590B2

公开(公告)日：2016-04-19

申请号：US13709446

申请日：2012-12-10

申请人： COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN ,  MICHELIN RECHERCHE ET TECHNIQUE S.A. ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  ECOLE POLYTECHNIQUE

发明人： Guillaume Cortial ,  Pascal Le Floch ,  Francois Nief ,  Julien Thuilliez

IPC分类号： C08F4/50 ,  C08F4/52 ,  C08F4/46 ,  C08L15/00 ,  C08F236/08 ,  C08F236/06

CPC分类号： C08F4/50 ,  C08F4/463 ,  C08F4/52 ,  C08F136/06 ,  C08F236/06 ,  C08F236/08 ,  C08K3/04 ,  C08L15/00 ,  C08F4/545 ,  C08L19/006 ,  C08F36/04

摘要： The present invention relates to a novel catalytic system for polymerization, and more particularly for preparing conjugated diene polymers bearing a polar function at the chain end. This catalytic system is based on a metal salt of a rare-earth metal and, as alkylating agent, an organometallic compound based on a metal belonging to the 2nd column or the 13th column of the Periodic Table, capable of transferring a polar function to the diene elastomer during the conjugated diene polymerization step. The novel catalytic system makes it possible to reduce the steps for synthesizing a chain-end functionalized elastomer, while ensuring optimal functionalization, advantageously close or equal to 100%.

摘要翻译： 本发明涉及一种用于聚合的新型催化体系，更具体地说涉及在链末端制备具有极性官能团的共轭二烯聚合物。 该催化体系基于稀土金属的金属盐，并且作为烷基化剂，基于属于周期表第二列或第十三列的金属的有机金属化合物，其能够将极性官能团转移到 二烯烃弹性体。 新颖的催化体系使得有可能减少合成链端官能化弹性体的步骤，同时确保最佳官能化，有利地接近或等于100％。

公开(公告)号：US10266553B2

公开(公告)日：2019-04-23

申请号：US15528688

申请日：2015-12-11

申请人： COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN ,  MICHELIN RECHERCHE ET TECHNIQUE, S.A. ,  UNIVERSITE CLAUDE BERNARD LYON 1 ,  CENTRE NATIONAL DE LA RECHERCE SCIENTIFIQUE ,  CPE LYON FORMATION CONTINUE ET RECHERCHE

发明人： Guillaume Cortial ,  Julien Thuilliez ,  Christophe Boisson ,  Franck D'Agosto ,  Sébastien Norsic

IPC分类号： C07F7/08 ,  C08F10/02

摘要： A compound and the use thereof to prepare a functional or telechelic polyolefin is provided. The compound has the following formula (II): Y((CH2)p—B′)m  (II), wherein m=2 or 3; Y being an alkaline earth metal or zinc when m=2, Y being aluminum when m=3; B′ being selected from the group comprising N(SiMe3)2; N(SiMe2CH2CH2SiMe2); C6F5; C3F7; C6F13; para-C6H4—NMe2; para-C6H4—O-Me; para-C6H4—N(SiMe3)2; and CH(OCH2CH2O); and p being an integer from 0 to 50.