Elemental sulfur dissolution and solvation

    公开(公告)号:US11572514B2

    公开(公告)日:2023-02-07

    申请号:US17494470

    申请日:2021-10-05

    Abstract: Methods for preventing elemental sulfur deposition from a hydrocarbon fluid is disclosed. A mercaptan is added to a hydrocarbon fluid that has elemental sulfur and reacted with the elemental sulfur to produce a disulfide and hydrogen sulfide. Amines and/or surfactants can assist with the process. Secondary reactions between the disulfide and the elemental sulfur result in a polysulfide and a solvated sulfur-disulfide complex. The disulfide, hydrogen sulfide, polysulfide and solvated sulfur-disulfide complex do not deposit, and can optionally be removed.

    Elemental sulfur analysis in fluids

    公开(公告)号:US11719684B2

    公开(公告)日:2023-08-08

    申请号:US17062281

    申请日:2020-10-02

    CPC classification number: G01N33/287 G01N21/75 Y10T436/109163 Y10T436/188

    Abstract: Robust methods for quantitating the amount of elemental sulfur in a fluid whereby a caustic solution is mixed with the fluid, and the elemental sulfur present in the fluid reacts to form a colored solution that can be compared to a series of standards. The methods can be performed in a laboratory or the field and allow for real time feedback. Once the concentration of the elemental sulfur is known, appropriate methods of treatment can proceed. Test kits for performing the methods in the field are also described.

    Elemental sulfur dissolution and solvation

    公开(公告)号:US11814588B2

    公开(公告)日:2023-11-14

    申请号:US18150280

    申请日:2023-01-05

    Abstract: Methods for preventing elemental sulfur deposition from a hydrocarbon fluid is disclosed. A mercaptan is added to a hydrocarbon fluid that has elemental sulfur and reacted with the elemental sulfur to produce a disulfide and hydrogen sulfide. Amines and/or surfactants can assist with the process. Secondary reactions between the disulfide and the elemental sulfur result in a polysulfide and a solvated sulfur-disulfide complex. The disulfide, hydrogen sulfide, polysulfide and solvated sulfur-disulfide complex do not deposit, and can optionally be removed.

    Method for the dissolution of amorphous dithiazines

    公开(公告)号:US12129437B2

    公开(公告)日:2024-10-29

    申请号:US17494673

    申请日:2021-10-05

    Abstract: The invention relates to the dissolution of amorphous dithiazine (a-DTZ) or polythioformaldehyde or other polymeric by-products of the treatment of hydrocarbon products (a-DZT) to remove them from surfaces. These are solids that build up on surfaces of processing plant and are resistant to most chemical treatment. The treatment requires treating the surface with an effective amount of a mercaptan or an amine. Surfactants to keep the dissolved a-DTZ or other components from redepositing elsewhere are also described, as is the use of hydrogen sulfide to add in removal by mercaptans.

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