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公开(公告)号:US11572514B2
公开(公告)日:2023-02-07
申请号:US17494470
申请日:2021-10-05
Applicant: CONOCOPHILLIPS COMPANY
Inventor: Jay Locklear , David P. Cope
Abstract: Methods for preventing elemental sulfur deposition from a hydrocarbon fluid is disclosed. A mercaptan is added to a hydrocarbon fluid that has elemental sulfur and reacted with the elemental sulfur to produce a disulfide and hydrogen sulfide. Amines and/or surfactants can assist with the process. Secondary reactions between the disulfide and the elemental sulfur result in a polysulfide and a solvated sulfur-disulfide complex. The disulfide, hydrogen sulfide, polysulfide and solvated sulfur-disulfide complex do not deposit, and can optionally be removed.
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公开(公告)号:US11719684B2
公开(公告)日:2023-08-08
申请号:US17062281
申请日:2020-10-02
Applicant: CONOCOPHILLIPS COMPANY
Inventor: Jay Locklear , Clinton Crowe
CPC classification number: G01N33/287 , G01N21/75 , Y10T436/109163 , Y10T436/188
Abstract: Robust methods for quantitating the amount of elemental sulfur in a fluid whereby a caustic solution is mixed with the fluid, and the elemental sulfur present in the fluid reacts to form a colored solution that can be compared to a series of standards. The methods can be performed in a laboratory or the field and allow for real time feedback. Once the concentration of the elemental sulfur is known, appropriate methods of treatment can proceed. Test kits for performing the methods in the field are also described.
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公开(公告)号:US11814588B2
公开(公告)日:2023-11-14
申请号:US18150280
申请日:2023-01-05
Applicant: CONOCOPHILLIPS COMPANY
Inventor: Jay Locklear , David P. Cope
CPC classification number: C10G29/28 , C11D3/34 , C10G2300/202 , C10G2300/207 , C10G2300/4075
Abstract: Methods for preventing elemental sulfur deposition from a hydrocarbon fluid is disclosed. A mercaptan is added to a hydrocarbon fluid that has elemental sulfur and reacted with the elemental sulfur to produce a disulfide and hydrogen sulfide. Amines and/or surfactants can assist with the process. Secondary reactions between the disulfide and the elemental sulfur result in a polysulfide and a solvated sulfur-disulfide complex. The disulfide, hydrogen sulfide, polysulfide and solvated sulfur-disulfide complex do not deposit, and can optionally be removed.
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公开(公告)号:US12129437B2
公开(公告)日:2024-10-29
申请号:US17494673
申请日:2021-10-05
Applicant: CONOCOPHILLIPS COMPANY
Inventor: Jay Locklear , David P. Cope
CPC classification number: C10G29/28 , C11D3/34 , C10G2300/202 , C10G2300/207 , C10G2300/4075
Abstract: The invention relates to the dissolution of amorphous dithiazine (a-DTZ) or polythioformaldehyde or other polymeric by-products of the treatment of hydrocarbon products (a-DZT) to remove them from surfaces. These are solids that build up on surfaces of processing plant and are resistant to most chemical treatment. The treatment requires treating the surface with an effective amount of a mercaptan or an amine. Surfactants to keep the dissolved a-DTZ or other components from redepositing elsewhere are also described, as is the use of hydrogen sulfide to add in removal by mercaptans.
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公开(公告)号:US11719082B2
公开(公告)日:2023-08-08
申请号:US17530299
申请日:2021-11-18
Applicant: CONOCOPHILLIPS COMPANY
Inventor: Ramesh Sharma , Travis Dinsdale , Amber J. Taylor , Babajide Kolade , Jay Locklear
CPC classification number: E21B43/2406 , C02F1/66 , C02F5/025 , C02F2001/007
Abstract: A method and system generate steam for SAGD operation wherein steam generator blowdown water is acidified, cooled and clarified before reuse. Acid Clarification Treatment, or “ACT”, mitigates organic fouling in Once-Through Stream Generators. Lab tests quantitatively and qualitatively show that ACT reduces Total organic carbon (TOC) and ‘bad actors’ TOC, respectively, in blowdown streams.
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公开(公告)号:US12025606B2
公开(公告)日:2024-07-02
申请号:US17746077
申请日:2022-05-17
Applicant: CONOCOPHILLIPS COMPANY
Inventor: Jay Locklear , Molly Merritt
CPC classification number: G01N33/2823 , G01N27/06
Abstract: The invention relates to a system and method for analyzing drilling fluid from a drilling rig for accessing subterranean hydrocarbons. The system and method involve analysis for chloride by replacing conventional chemical titration with electrical conductivity titration.
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公开(公告)号:US11199078B2
公开(公告)日:2021-12-14
申请号:US15170338
申请日:2016-06-01
Applicant: CONOCOPHILLIPS COMPANY
Inventor: Ramesh Sharma , Travis Dinsdale , Amber J. Taylor , Babajide Kolade , Jay Locklear
Abstract: A method and system generate steam for SAGD operation wherein steam generator blowdown water is acidified, cooled and clarified before reuse. Acid Clarification Treatment, or “ACT”, mitigates organic fouling in Once-Through Stream Generators. Lab tests quantitatively and qualitatively show that ACT reduces Total organic carbon (TOC) and ‘bad actors’ TOC, respectively, in blowdown streams.
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