公开(公告)号：US3914272A

公开(公告)日：1975-10-21

申请号：US37123073

申请日：1973-07-02

申请人： CONTINENTAL OIL CO

发明人： STARKS CHARLES M ,  PORTWOOD JR OWEN

IPC分类号： C07C17/093 ,  C07C303/26 ,  C07C309/72 ,  C07C143/68

CPC分类号： C07C303/26 ,  C07C17/093 ,  C07C309/72

摘要： A process for exchanging alkyl moieties between compounds comprising reacting a lower alkyl arylsulfonate with a higher alkyl halide in the presence of an organic quaternary salt. The process is useful in converting the higher alkyl group of the starting halide to the corresponding alcohols by first employing the process of the invention to convert the higher alkyl group to the corresponding arylsulfonate followed by hydrolysis to produce the higher alkanols.

摘要翻译： 一种用于在化合物之间交换烷基部分的方法，包括在有机季盐存在下使低级烷基芳基磺酸盐与高级烷基卤化物反应。 该方法可用于将起始卤化物的高级烷基转化为相应的醇，首先采用本发明的方法将高级烷基转化为相应的芳基磺酸酯，然后水解制备高级链烷醇。