摘要:
1. A PROCESS FOR CATALYTICALLY PRODUCING ORGANIC CYANIDES BY REACTING IN A TWO-PHASE LIQUID REACTION SYSTEM (1) AN AQUEOUS PHASE OF AN AQUEOUS SOLUTION OF AN INORGANIC CYANIDE SELECTED FROM THE GROUP CONSISTING OF ALKALI METAL CYANIDES, ALKALINE EARTH METAL CYANIDES, AND MIXTURES THEREOF, WITH (2) AN ORGANIC PHASE OF AN ORGANIC HALIDE DEFINED BY THE FORMULA RCH2X WHEREIN X IS CHLORINE, BROMINE OR IODINE; AND R IS HYDROGEN; A HALOGEN SUCH AS CHLORINE, BROMINE OR IODINE;
A R''-PHENYL
RADICAL WHEREIN R'' IS HYDROGEN, A C1-C12 ALKYL GROUP, A C1-C12 ALKENYL GROUP, OR A
X-(CH2)N-
GROUP WHEREIN N IS AN INTEGER OF 1 TO 12 AND X IS DEFINED ABOVE; AN ALKYL RADICAL HAVING 1 TO 30 CARBON ATOMS; AN ALKENYL RADICAL HAVING 2 TO 30 CARBON ATOMS; A -R"CR3"'' RADICAL WHEREIN R" IS A DIVALENT SATURATED OR UNSATURATED ALIPHATIC HYDROCARBON GROUP HAVING 1 TO 30 CARBON ATOMS AND EACH R"'' IS HYDROGEN, CHLORINE, BROMINE OR IODINE;
A R''-OOC-(R")A-
RADICAL WHEREIN "A" IS 0 OR 1 AND R" AND R'' ARE AS DEFINED ABOVE; A R''-OOC-CH(-COO-R'')-(R")A-
RADICAL WHEREIN R", "A" AND EACH R'' ARE AS DEFINED ABOVE;
A R''-COO-(R")A-
RADICAL WHEREIN R", "a" AND R'' ARE AS DEFINED ABOVE;
A R""-COO-(R")A-
RADICAL WHEREIN R" AND "A" ARE AS DEFINED ABOVE AND R"" IS A C1-C12 ALKYL GROUP, A PHENYL GROUP OR A PHENYL-SUBSTITUTED C1-C12 ALKYL GROUP; OR
A R""''-O-(R")A-
RADICAL WHEREIN R" AND "A" ARE AS DEFINED ABOVE, AND R""'' IS HYDROGEN, PHENYL, OR A SATURATED OR UNSATURATED C1-C30 ALIPHATIC HYDROCARBON GROUP, IN THE PRESENCE OF AT LEAST 0.01 WEIGHT PERCENT BASED ON THE CYANIDE AND HALIDE REACTANTS, OF ACTIVATED CARBON AT NON-DEGRADATIVE TEMPERATURES OF AT LEAST 25* C.
摘要:
A method for upgrading gasification products produced by the gasification of subterranean carbonaceous deposits and recovered through a well bore by contacting said products with an effective amount of a suitable catalyst positioned in said well bore.
摘要:
A PROCESS FOR CATALYTICALLY EXCHANGING BROMIDE IONS FOR HYDROXYL GROUPS BETWEEN ALIPHATIC BROMIDES AND ALIPHATIC ALCOHOLS WHEREIN THE BROMIDES AND ALCOHOLS ARE REACTED IN THE PRESENCE OF ACTIVATED CARBON, INCLUDING ACTIVATED CHARCOAL.
摘要:
The present invention relates to a method for conducting the reaction between bromoalkanes and inorganic chlorides wherein the reactions are heated in a reaction vessel in the presence of an activated charcoal catalyst.