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12 条记录 (耗时 0.008 秒)

    Process for preparing cyano-compounds
    2.
    发明授权
    Process for preparing cyano-compounds 失效
    制备氰基化合物的方法

    公开(公告)号：US3725458A

    公开(公告)日：1973-04-03

    申请号：US3725458D

    申请日：1971-11-17

    申请人： CONTINENTAL OIL CO

    发明人： STARKS C

    IPC分类号： C07C17/08 ,  C07C17/20 ,  C07C121/06

    CPC分类号： C07C253/14 ,  C07C17/08 ,  C07C17/206 ,  C07C19/075 ,  C07C19/01

    摘要： A process for the preparation of terminally substituted cyanocompounds from 1-alkenes. The process involves the preparation of a 1-bromoalkane from the reaction of the 1-alkene and HBr in the presence of an initiator followed by a catalyzed halogen exchange reaction with HC1 wherein a 1-chloroalkane is formed and HBr is regenerated. The 1-chloroalkane is then reacted with a cyanide containing compound in the presence of an organic quaternary salt catalyst to produce the desired terminally substituted cyanocompound, a 1-cyanoalkane.

    摘要翻译： 从1-烯烃制备末端取代的氰基化合物的方法。 该方法包括在引发剂存在下由1-烯烃和HBr反应制备1-溴烷烃，然后与形成1-氯代烷烃和HBr再生的HC1的催化卤化物交换反应。 然后在有机季盐催化剂的存在下，使含1-氰基的氰基化合物与含氰化合物反应，生成所需的末端取代的氰基化合物1-氰基烷烃。

    Distillation of a haloalkyl-cyanide with a nitrile
    3.
    发明授权
    Distillation of a haloalkyl-cyanide with a nitrile 失效
    一种含有羟基烷基的氰化物与NITRILE的蒸馏

    公开(公告)号：US3725207A

    公开(公告)日：1973-04-03

    申请号：US3725207D

    申请日：1970-05-27

    申请人： HALCON INTERNATIONAL INC

    发明人： GOLDEN R

    IPC分类号： B01D3/34 ,  C07C20060101 ,  C07C121/06

    CPC分类号： C07C17/386

    摘要： Alkylene nitriles having the formula X-CH2-CHR-CN may be purified by distillation by maintaining a concentration of 1 to 5 mol percent of CH2 CRCN in the distillation zone during the distillation. R may be hydrogen or a lower alkyl and X a chloro-, iodo- or bromo-group.

    摘要翻译： 具有式X-CH 2 -CHR-CN的亚烷基腈可以在蒸馏期间通过蒸馏在蒸馏区中保持1至5mol％的CH 2 = CRCN的浓度进行蒸馏来纯化。 R可以是氢或低级烷基，X是氯，碘或溴基。

    Production of organic cyanides
    7.
    发明授权
    Production of organic cyanides 失效
    生产有机氰化物

    公开(公告)号：US3839399A

    公开(公告)日：1974-10-01

    申请号：US29506572

    申请日：1972-10-04

    申请人： CONTINENTAL OIL CO

    发明人： STARKS C ,  JOHNSON M ,  YANG K

    IPC分类号： C07C121/06

    CPC分类号： C07C255/00 ,  C07C253/14

    摘要： 1. A PROCESS FOR CATALYTICALLY PRODUCING ORGANIC CYANIDES BY REACTING IN A TWO-PHASE LIQUID REACTION SYSTEM (1) AN AQUEOUS PHASE OF AN AQUEOUS SOLUTION OF AN INORGANIC CYANIDE SELECTED FROM THE GROUP CONSISTING OF ALKALI METAL CYANIDES, ALKALINE EARTH METAL CYANIDES, AND MIXTURES THEREOF, WITH (2) AN ORGANIC PHASE OF AN ORGANIC HALIDE DEFINED BY THE FORMULA RCH2X WHEREIN X IS CHLORINE, BROMINE OR IODINE; AND R IS HYDROGEN; A HALOGEN SUCH AS CHLORINE, BROMINE OR IODINE;

    A R''-PHENYL

    RADICAL WHEREIN R'' IS HYDROGEN, A C1-C12 ALKYL GROUP, A C1-C12 ALKENYL GROUP, OR A

    X-(CH2)N-

    GROUP WHEREIN N IS AN INTEGER OF 1 TO 12 AND X IS DEFINED ABOVE; AN ALKYL RADICAL HAVING 1 TO 30 CARBON ATOMS; AN ALKENYL RADICAL HAVING 2 TO 30 CARBON ATOMS; A -R"CR3"'' RADICAL WHEREIN R" IS A DIVALENT SATURATED OR UNSATURATED ALIPHATIC HYDROCARBON GROUP HAVING 1 TO 30 CARBON ATOMS AND EACH R"'' IS HYDROGEN, CHLORINE, BROMINE OR IODINE;

    A R''-OOC-(R")A-

    RADICAL WHEREIN "A" IS 0 OR 1 AND R" AND R'' ARE AS DEFINED ABOVE;
    A R''-OOC-CH(-COO-R'')-(R")A-

    RADICAL WHEREIN R", "A" AND EACH R'' ARE AS DEFINED ABOVE;

    A R''-COO-(R")A-

    RADICAL WHEREIN R", "a" AND R'' ARE AS DEFINED ABOVE;

    A R""-COO-(R")A-

    RADICAL WHEREIN R" AND "A" ARE AS DEFINED ABOVE AND R"" IS A C1-C12 ALKYL GROUP, A PHENYL GROUP OR A PHENYL-SUBSTITUTED C1-C12 ALKYL GROUP; OR

    A R""''-O-(R")A-

    RADICAL WHEREIN R" AND "A" ARE AS DEFINED ABOVE, AND R""'' IS HYDROGEN, PHENYL, OR A SATURATED OR UNSATURATED C1-C30 ALIPHATIC HYDROCARBON GROUP, IN THE PRESENCE OF AT LEAST 0.01 WEIGHT PERCENT BASED ON THE CYANIDE AND HALIDE REACTANTS, OF ACTIVATED CARBON AT NON-DEGRADATIVE TEMPERATURES OF AT LEAST 25* C.

    Cyanomethyl substituted derivatives of dihalophenylcyclopropane
    8.
    发明授权
    Cyanomethyl substituted derivatives of dihalophenylcyclopropane 失效
    二羟基苯酚的氰基取代衍生物

    公开(公告)号：US3598857A

    公开(公告)日：1971-08-10

    申请号：US3598857D

    申请日：1968-09-30

    申请人： OLIN MATHIESON

    发明人： BRUSON HERMAN A ,  PLANT HOWARD L

    IPC分类号： C07C17/32 ,  C07C23/18 ,  C08K5/16 ,  C07C121/06 ,  C07C121/66

    CPC分类号： C07C17/32 ,  C07C23/18 ,  C08K5/16 ,  C08L23/06

    摘要： HALOMETHYL SUBSTITUTED DERIVATIVES OF DIHALOPHENYLCYCLOPROPANES HAVING THE FORMULA:

    1-(X"-CH2)N-(PHENYLENE)-,1-R,2-X,2-X''-CYCLOPROPANE

    WHEREIN X,X'',X" ARE EACH SELECTED FROM THE GROUP CONSISTING OF CHLORINE, BROMINE, IODINE, R IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN OR ALKYL OF FROM 1 TO 5 INCLUSIVE CARBON ATOMS AND N IS AN INTERGER OF FROM 1 TO 2 INCLUSIVE; ARE PREPARED BY REACTING FORMALDEHYDE AND AN ACID, SUCH AS HYDROBROMIC ACID, WITH A DICHLOROCARBENE ADDUCT OF STYRENE. IN THE SECOND PHASE THE HALOMTHYL DERIVATIVES ARE REACTED WITH AN ALKALI METAL CYANIDE TO FORM CYANOMETHYL SUBSTITUTED DERIVATIVES OF THE DIHALOPHENYLCYCLOPROPANES. THE COMPOUNDS, WHICH CONTAIN A HIGH PERCENTAGE OF HALOGEN, ARE USEFUL AS FIRE RETARDANTS FOR PLASTIC MATERIALS SUCH ASS POLYETHYLENE AND, IN ADDITION, THE CYANOMETHYL DERIVATIVES ARE VALUBLE SOIL FUNGICIDES AND HERBICIDES.