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公开(公告)号:US20230099196A1
公开(公告)日:2023-03-30
申请号:US17862478
申请日:2022-07-12
Applicant: Corning Incorporated
Inventor: Benjamin Jean-Baptiste Francois Burger
Abstract: A liquid lens including (i) a first liquid and a second liquid disposed within a containment region, the first liquid and the second liquid forming an interface between the first liquid and the second liquid; (ii) an electrode; and (iii) an insulating layer separating the electrode from the first liquid and the second liquid, the insulating layer comprising a polymeric material and a slippery omniphobic covalently attached liquid that is chemically bonded to the polymeric material, the slippery omniphobic covalently attached liquid providing a surface contacting one or more of the first liquid and the second liquid. The polymeric material of the insulating layer can be a poly(para-xylylene). The slippery omniphobic covalently attached liquid can include units of a silicone or polyolefin, each unit individually bound to a repeating unit of the polymeric material. A liquid lens where the insulating layer has a quality factor at least 200.
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公开(公告)号:US20220252861A1
公开(公告)日:2022-08-11
申请号:US17621732
申请日:2020-06-24
Applicant: Corning Incorporated
Inventor: Jerome René Broutin , Benjamin Jean-Baptiste Francois Burger , Aude Contet , Géraldine Denise Juliette Malet-Vasseur , Nicolas Gilbert Jose Samper
Abstract: Electrowetting optical devices can comprise a first electrode at least partially circumscribing a first optical window and a second electrode at least partially circumscribing a second optical window. The second optical window may be aligned with the first optical window in a direction of the optical axis. A central region may be defined by a projection of a footprint of the second optical window. An interface between a first liquid and a second liquid that may be disposed within a containment region may form a lens. In some embodiments, a thickness of a second dielectric portion at least partially circumscribing the central region may be greater than a thickness of a thirst dielectric portion within the central region. In some embodiments, a capacitance per area of the device upon application of a maximum operating voltage may be in a range from about 0.1 pF/mm2 to about 3.5 pF/mm2.
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公开(公告)号:US11204492B2
公开(公告)日:2021-12-21
申请号:US16734704
申请日:2020-01-06
Applicant: CORNING INCORPORATED
Abstract: An electrowetting optical device is provided. The electrowetting optical device includes a conductive liquid and a non-conductive liquid. The non-conductive fluid includes a naphthalene based compound having Formula (I), Formula (II), and/or Formula (III): where R1, R2, and R3 are individually alkyl, aryl, alkoxy, or aryloxy groups; X includes carbon, silicon, germanium, tin, lead, and combinations thereof; and Z includes oxygen, sulfur, selenium, tellurium, polonium, and combinations thereof. The conductive liquid may additionally include a transmission recovery agent having Formula (IV) and/or Formula (V): where R4 is an alkyl, fluoroalkyl, aryl, alkoxy, or aryloxy group. The electrowetting optical device additionally includes a dielectric surface in contact with both the conductive and non-conductive liquids where the conductive and non-conductive liquids are non-miscible.
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公开(公告)号:US12204091B2
公开(公告)日:2025-01-21
申请号:US17621732
申请日:2020-06-24
Applicant: Corning Incorporated
Inventor: Jerome René Broutin , Benjamin Jean-Baptiste Francois Burger , Aude Contet , Géraldine Denise Juliette Malet-Vasseur , Nicolas Gilbert Jose Samper
Abstract: Electrowetting optical devices can comprise a first electrode at least partially circumscribing a first optical window and a second electrode at least partially circumscribing a second optical window. The second optical window may be aligned with the first optical window in a direction of the optical axis. A central region may be defined by a projection of a footprint of the second optical window. An interface between a first liquid and a second liquid that may be disposed within a containment region may form a lens. In some embodiments, a thickness of a second dielectric portion at least partially circumscribing the central region may be greater than a thickness of a thirst dielectric portion within the central region. In some embodiments, a capacitance per area of the device upon application of a maximum operating voltage may be in a range from about 0.1 pF/mm2 to about 3.5 pF/mm2.
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公开(公告)号:US20240069245A1
公开(公告)日:2024-02-29
申请号:US18446100
申请日:2023-08-08
Applicant: CORNING INCORPORATED
Inventor: Benjamin Jean-Baptiste Francois Burger , Patrick Jean
Abstract: A liquid lens including a first liquid comprising a polyfluoroaromatic compound represented by formula (I): Fx—(aromatic)—Y—R1. “x” is within a range of from 2 to 5. Y is one of CH2, Si(Alk)2, Ge(Alk)2, O, and S. “Alk” is a linear aliphatic chain. R1 is any organic group, but can be one of a linear aliphatic chain, a cycloaliphatic, a fluorocycloaliphatic, and an aromatic residue. “Aromatic” is any six carbon aromatic ring. Examples of the chemical compound represented by formula (I) include butylpentafluorobenzene; dimethylnonafluorohexylpentafluorophenylsilane; trimethylpentafluorophenylgennane; butoxypentafluorobenzene; cyclopentoxypentafluorobenzene; 1-n-octyloxypentafluorobenzene; cyclooctyloxypentafluorobenzene; 1-n-dodecyloxypentafluorobenzene; cyclopentylpentafluorophenylsulfide; phenoxypentafluorobenzene; 2,4-difluoroanisole; and heptafluoropentyloxypentafluorobenzene. The first liquid has a density in a range of from 0.95 g/mL to 1.35 g/mL (at 20° C.). The liquid lens further includes a second liquid that forms an interface with the first liquid. The second liquid can be substantially free of water.
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公开(公告)号:US20210231943A1
公开(公告)日:2021-07-29
申请号:US17056605
申请日:2019-05-20
Applicant: CORNING INCORPORATED
Inventor: Robert Alan Bellman , Benjamin Jean-Baptiste Francois Burger , Michelle Dawn Fabian , Timothy Edward Myers
Abstract: An electrowetting optical device is provided. The electrowetting optical device includes a first window, a second window, and a cavity disposed between the first window and the second window. The electrowetting optical device additionally includes a first liquid and a second liquid disposed within the cavity, the first liquid and the second liquid substantially immiscible with each other and having different refractive indices such that an interface between the first liquid and the second liquid defines a variable lens. The electrowetting optical device also includes a common electrode in electrical connection with the first liquid and a driving electrode disposed on a sidewall of the cavity and insulated from the first liquid and the second liquid by an insulating polymer dielectric layer. The insulating polymer dielectric layer may be formed using initiated chemical vapor deposition (iCVD).
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公开(公告)号:US20190293920A1
公开(公告)日:2019-09-26
申请号:US16375124
申请日:2019-04-04
Applicant: Corning Incorporated
Abstract: An electrowetting optical device is provided. The electrowetting optical device includes a conductive liquid and a non-conductive liquid. The non-conductive fluid includes a naphthalene based compound having Formula (I), Formula (II), and/or Formula (III): where R1, R2, and R3 are individually alkyl, aryl, alkoxy, or aryloxy groups; X includes carbon, silicon, germanium, tin, lead, and combinations thereof; and Z includes oxygen, sulfur, selenium, tellurium, polonium, and combinations thereof. The conductive liquid may additionally include a transmission recovery agent having Formula (IV) and/or Formula (V): where R4 is an alkyl, fluoroalkyl, aryl, alkoxy, or aryloxy group. The electrowetting optical device additionally includes a dielectric surface in contact with both the conductive and non-conductive liquids where the conductive and non-conductive liquids are non-miscible.
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公开(公告)号:US20240168280A1
公开(公告)日:2024-05-23
申请号:US18382270
申请日:2023-10-20
Applicant: CORNING INCORPORATED
Inventor: Jerome René Broutin , Benjamin Jean-Baptiste Francois Burger , Frederic Jean Jacques Laune , Géraldine Denise Juliette Malet-Vasseur
CPC classification number: G02B26/005 , G02B3/14
Abstract: An electrowetting optical device includes a conductive liquid, a non-conductive liquid, and a substrate. The conductive liquid is buffered to an acidic pH. The conductive liquid and the non-conductive liquid are immiscible. The substrate includes a dielectric topcoat. The conductive liquid and the non-conductive liquid are in contact with the dielectric topcoat. The dielectric topcoat is a plasma-deposited organosilane precursor having the molecular formula SiOxCyHz.
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公开(公告)号:US20230124449A1
公开(公告)日:2023-04-20
申请号:US17912215
申请日:2021-03-15
Applicant: CORNING INCORPORATED
Abstract: A liquid lens can include a cavity between first and second windows, first and second liquids in the cavity, and a variable interface between the liquids, thereby forming a variable lens. The liquid lens can be operable to adjust a shape of the variable interface at an operating temperature less than a melting point of the first liquid. A liquid composition of the first liquid can include at least 65 wt. % water, at most 31 wt. % of a freezing point reducing agent, at most 20 wt. % of an alkali metal salt, a melting point of greater than or equal to −10° C., a viscosity of at most 1.3 cSt, measured at a temperature of 20° C., a refractive index, measured at a wavelength of 589.3 nm, of at most 1.4, and/or an Abbe number of at least 45. A volume of the cavity can be at most 10 μL.
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公开(公告)号:US20220099862A1
公开(公告)日:2022-03-31
申请号:US17426914
申请日:2020-01-23
Applicant: CORNING INCORPORATED
Inventor: Benjamin Jean-Baptiste Francois Burger
Abstract: A liquid lens can include a lens body forming a cavity with a conducting liquid and an insulating liquid disposed therein, the conducting liquid substantially immiscible with the insulating liquid to define an interface between the conducting and insulating liquids. The conducting liquid can include an ionic compound of either a dicyanamide anion and a cation counterion, or a tricyanomethanide anion and a cation counterion, the dicyanamide anion having the formula the tricyanomethanide anion having the formula and the cation counterion is one of an imidazolium, a pyrrolidininium, a piperidinium, a phosphonium, a pyridinium, a pyrrolinium or a sulfonium cation. The ionic compound of the conducting liquid can be N-methyl-N-ethylpyrrolidinium dicyanamide, l-ethyl-3-methylimidazolium dicyanamide, 1-butyl-1-methylpyrrolidinium tricyanomethanide, or 1-ethyl-3-methylimidazolium tricyanomethanide, among others. The conducting liquid can have transmittance of at least 50% over a thickness of 1 mm for electromagnetic waves having wavelength of 1550 n.
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