摘要:
The method comprises photopolymerizing by means of a light radiation of the visible and/or near UV field of a composition free of mineral particles, comprising at least one photopolymerizable monomer and at least one photoinitiator selected amongst suberone derivatives and mixtures of α-diketone and an organic peroxide. Application to the manufacture of ophthalmic lenses.
摘要:
A radically polymerizable composition comprising: a first component A comprising at least an oligomer having at least two radically polymerizable functions and the homopolymer of which has a glass transition temperature (Tg) lower than 50° C., such a component being able to result through polymerization in a (co)polymer having a glass transition temperature (Tg) equal to or lower than 50° C., preferably equal to or lower than 0° C. and more preferably ranging from −50° C. to −10C, said oligomer accounting for more than 15%, preferably at least 20% of the total weight of the polymerizable monomers present in the composition; and a second component B comprising at least a (meth)acrylic monomer having at least one H link promoting group, such a (meth)acrylic monomer accounting for at least 15% of the total weight of the polymerizable monomers and oligomers present in the composition when such a monomer is a methacrylic monomer and at least 35% of the total weight of such polymerizable monomers and oligomers present in the composition when such a monomer is an acrylic monomer.
摘要:
The invention is a composition comprising: 40 to 95 parts by weight of one or several monomers (I) of formula (a) wherein: R1 and R2 represent H or CH; A represents a divalent radical of formula (b) or (c) wherein m1 and m2 represent each an integer ranging between 2 and 6; and 5 to 50 parts by weight of a monomer (II) comprising at least a urethane unit and at least two (meth)acrylate functions. The invention is useful for making optical and ophthalmic articles.
摘要:
The invention is a composition comprising: 40 to 95 parts by weight of one or several monomers (I) of formula (a) wherein: R1 and R2 represent H or CH; A represents a divalent radical of formula (b) or (c) wherein m1 and m2 represent each an integer ranging between 2 and 6; and 5 to 50 parts by weight of a monomer (II) comprising at least a urethane unit and at least two (meth)acrylate functions. The invention is useful for making optical and ophthalmic articles.
摘要:
The compositions comprise: (a) at least 40 parts by weight, preferably at least 50 parts by weight, of at least one thio(meth)acrylate monomer, (b) at least one high Abbe number monomer, (c) at the most 20 parts by weight, preferably at the most 15 parts by weight and more preferably 10 parts by weight of an aromatic polyvinyl monomer, and (d) at least one polythiol, for 100 parts by weight of (a), (b), (c) and (d). Application for the manufacture of optical lenses.
摘要:
A radically polymerizable composition comprising: a first component A comprising at least an oligomer having at least two radically polymerizable functions and the homopolymer of which has a glass transition temperature (Tg) lower than 50° C., such a component being able to result through polymerization in a (co)polymer having a glass transition temperature (Tg) equal to or lower than 50° C., preferably equal to or lower than 0° C. and more preferably ranging from −50° C. to −10 C., said oligomer accounting for more than 15%, preferably at least 20% of the total weight of the polymerizable monomers present in the composition; and a second component B comprising at least a (meth)acrylic monomer having at least one H link promoting group, such a (meth)acrylic monomer accounting for at least 15% of the total weight of the polymerizable monomers and oligomers present in the composition when such a monomer is a methacrylic monomer and at least 35% of the total weight of such polymerizable monomers and oligomers present in the composition when such a monomer is an acrylic monomer.
摘要:
A lens has at least one insert (16, 28), which defines an optical path. For manufacturing the lens, the insert is first bonded to an overmould (36). A polymer (44) is then moulded in a mould (42, 36) formed on one of its faces from the overmould. After moulding, the overmould may be preserved and form part of the lens, if necessary after surface grinding. The overmould may also be separated from the lens; in this case, the lens is machined, removing at least part of the inserts. The lens obtained has an insert in a reproducible position, with an entrance or exit surface inducing no optical distortion.