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    Preparation of bridged metallocene complexes
    4.
    发明授权
    Preparation of bridged metallocene complexes 失效
    桥联茂金属络合物的制备

    公开(公告)号：US5831106A

    公开(公告)日：1998-11-03

    申请号：US648704

    申请日：1996-05-16

    申请人： Franz Langhauser ,  David Fischer ,  Gunther Schweier ,  Hans-Herbert Brintzinger ,  Hans-Robert-Hellmuth Damrau

    发明人： Franz Langhauser ,  David Fischer ,  Gunther Schweier ,  Hans-Herbert Brintzinger ,  Hans-Robert-Hellmuth Damrau

    IPC分类号： C07F17/00 ,  C07F7/08 ,  C07F3/02 ,  C07F7/28 ,  C07F7/30

    CPC分类号： C07F17/00

    摘要： A process for preparing metallocene complexes of the general ##STR1## in which the substituents have the following meanings: M is titanium, zirconium, hafnium, vanadium, niobium or tantalum, X is fluorine, chlorine, bromine, iodine, hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl or --OR.sup.5, where R.sup.5 is C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl, alkylaryl, aryl-alkyl, fluoroalkyl or fluoroaryl with, in each case, 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R.sup.1 to R.sup.4 and R.sup.6 to R.sup.9 are hydrogen, C.sub.1 -C.sub.10 -alkyl, 5- to 7-membered cycloalkyl which can in turn carry C.sub.1 -C.sub.10 -alkyls as substituents, or C.sub.6 -C.sub.15 -aryl or aryl-alkyl, it also being possible where appropriate for two adjacent radicals together to be cyclic groups having 4 to 15 carbon atoms, or Si(R.sup.10).sub.3 with R.sup.10 being C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl or C.sub.3 -C.sub.10 -cyclo-alkyl, ##STR2## where Z is silicon, germanium, tin or carbon, and R.sup.11,R.sup.12, R.sup.13 and R.sup.14 are hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.3 -C.sub.10 -cycloalkyl or C.sub.6 -C.sub.15 -aryl, it also being possible where appropriate for two adjacent radicals together to be cyclic groups having 4 to 15 carbon atoms, which comprises reacting compounds of the general formula II ##STR3## where Q is beryllium, magnesium, calcium, strontium or barium, and L.sup.1 and L.sup.2 are Lewis bases with compounds of the general formula III ##STR4## where R.sup.15 and R.sup.16 are C.sub.1 -C.sub.10 -alkyl, C.sub.3 -C.sub.10 -cycloalkyl or C.sub.6 -C.sub.15 -aryl.

    摘要翻译： 制备一般化合物的茂金属络合物的方法，其中取代基具有以下含义：M是钛，锆，铪，钒，铌或钽，X是氟，氯，溴，碘，氢，C1- C 1 -C 15 - 芳基或-OR 5，其中R 5是C 1 -C 10 - 烷基，C 6 -C 15 - 芳基，烷基芳基，芳基 - 烷基，氟代烷基或氟代芳基，在每种情况下，在 芳基中的烷基和6至20个碳原子，R 1至R 4和R 6至R 9为氢，C 1 -C 10 - 烷基，5-至7-元环烷基，其又可携带C1-C10-烷基作为取代基，或 C 6 -C 15 - 芳基或芳基 - 烷基时，两个相邻的基团一起可以是具有4至15个碳原子的环状基团，或者具有R 10的Si（R 10）3是C 1 -C 10烷基，C 6 -C 15 芳基或C 3 -C 10 - 环烷基，其中Z是硅，锗，锡或碳，R 11，R 12，R 13和R 14是氢，C 1 -C 10 - 烷基，C 3 -C 10 - 环烷基或C 6 -C 10 - C15-芳基，它也是可能的 其中适当地将两个相邻的基团一起作为具有4至15个碳原子的环状基团，其包括使Q为铍，镁，钙，锶或钡的通式II II的化合物与L1和L2反应 路易斯碱与通式III的化合物III，其中R 15和R 16是C 1 -C 10 - 烷基，C 3 -C 10 - 环烷基或C 6 -C 15 - 芳基。