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公开(公告)号：US4568786A
公开(公告)日：1986-02-04
申请号：US709143
申请日：1985-03-07
摘要： Olefin upgrading in plural reactors can achieve conversion of lower olefinic feedstock, such as propene, butene, etc., to valuable heavy hydrocarbons containing a lubricant fraction of high viscosity index. Other fuel products, such as (C.sub.10 -C.sub.20) distillate, gasoline and LPG may also be recovered as products. In a preferred process for converting lower olefinic feed to heavier hydrocarbons by contacting the feed with a shape selective medium pore acidic zeolite catalyst at elevated temperature and pressure the catalyst surface is rendered relatively inactive by adding to the olefinic feed an inactivating amount of a sterically-hindered organic base, whereby the catalyst is selectively surface-deactivated, to produce substantially linear heavier hydrocarbons rich in C.sub.10.sup.+ olefins. In the preferred multi-stage process the olefinic feed comprises C.sub.2 -C.sub.8 olefins and the catalyst employed in each stage comprises aluminosilicate having a silica-to-alumina mole ratio of at least 12 and a constraint index of about 1 to 12.
摘要翻译： 在多个反应器中的烯烃升级可以实现将低级烯烃原料如丙烯，丁烯等转化成含有高粘度指数的润滑剂部分的有价值的重烃。 其他燃料产品，如（C10-C20）馏出物，汽油和LPG也可作为产品回收。 在优选的方法中，通过使进料与形状选择性中孔孔酸性沸石催化剂在升高的温度和压力下接触来将低级烯烃进料转化成较重的烃，通过向烯烃进料中加入灭活量的空间位阻，使催化剂表面相对无活性， 受阻的有机碱，其中催化剂被选择性地表面失活，以产生富含C10 +烯烃的基本上线性的较重的烃。 在优选的多级方法中，烯烃进料包含C 2 -C 8烯烃，并且在每个阶段中使用的催化剂包含二氧化硅与氧化铝的摩尔比至少为12，约束指数为约1至12的硅铝酸盐。
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公开(公告)号：US5095165A
公开(公告)日：1992-03-10
申请号：US496836
申请日：1990-03-21
IPC分类号： C07C41/30 , C07C67/293 , C07C67/475 , C10M107/10 , C10M143/08
CPC分类号： C10M143/08 , C07C41/30 , C07C67/293 , C07C67/475 , C10M107/10
摘要： The invention discloses that hydrocarbon lubricants containing olefinic unsaturation participate in an olefin metathesis reaction with alkenes containing polar functional groups to provide an equilibrium mixture containing hydrocarbon lubricants containing the polar groups of the alkenes. The discovery is particularly applicable to the functionalization of near linear lubricants prepared from the oligomerization of propylene using surface deactivated zeolite or lubricants prepared by the oligomerization of C.sub.6 -C.sub.20 alpha olefins using coordination catalyst. Functionalized groups can be incorporated that impart a wide range of properties to the lubricant such as anti-wear or anti-corrosion resistance, or improve the compatibility of the lubricant with other additives.
摘要翻译： 本发明公开了含有烯属不饱和键的烃类润滑剂参与与含有极性官能团的烯烃进行烯烃复分解反应，以提供含有含有烯烃极性基团的烃类润滑剂的平衡混合物。 该发现特别适用于使用表面失活沸石或通过使用配位催化剂使C6-C20α烯烃低聚制备的润滑剂从丙烯低聚制备的近线性润滑剂的功能化。 可以引入赋予润滑剂广泛性能的功能性基团，例如抗磨损或抗腐蚀性，或提高润滑剂与其它添加剂的相容性。
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公开(公告)号：US4520221A
公开(公告)日：1985-05-28
申请号：US598139
申请日：1984-04-09
IPC分类号： C10G57/02 , B01J29/00 , B01J29/40 , B01J29/65 , B01J29/70 , C07B61/00 , C07C1/00 , C07C2/12 , C07C67/00 , C10G50/00 , C10G50/02 , C07C2/02
摘要： High VI lubes in high yields are obtained when lower or light olefins are polymerized over a ZSM-5 type catalyst the surface acidity of which has been inactivated by treatment with a suitable base material.
摘要翻译： 当低级或轻质烯烃在ZSM-5型催化剂上聚合时，获得高产率的高VI润滑剂，其表面酸度通过用合适的基材处理而失活。
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