公开(公告)号：US5437803A

公开(公告)日：1995-08-01

申请号：US96061

申请日：1993-07-22

申请人： Charles Cane ,  John Crawford ,  Patrick S. O'Connor

发明人： Charles Cane ,  John Crawford ,  Patrick S. O'Connor

IPC分类号： C10M125/10 ,  C10M125/14 ,  C10M125/18 ,  C10M129/08 ,  C10M129/10 ,  C10M129/16 ,  C10M129/38 ,  C10M129/54 ,  C10M129/70 ,  C10M135/10 ,  C10M159/12 ,  C10M159/20 ,  C10M159/22 ,  C10M159/24 ,  C10M177/00 ,  C10N10/04 ,  C10N20/02 ,  C10N40/25 ,  C10N70/00

CPC分类号： C10M159/24 ,  C10M159/12 ,  C10M159/20 ,  C10M159/22

摘要： A process for the production of a lubricating oil additive concentrate which process comprises reacting at elevated temperaturecomponent (A) a defined acid or derivative thereof,component (B) a calcium base added either in a single addition or in a plurality of additions at intermediate points during the reaction,component (C) at least one compound which is (i) water, (ii) a polyhydric alcohol having 2 to 4 carbon atoms, (iii) a di- (C.sub.3 or C.sub.4) glycol, (iv) a tri (C.sub.2 -C.sub.4) glycol, (v) a mono- or poly-alkylene glycol alkyl ether of the formula (I)R(OR.sup.1).sub.x OR.sup.2 (I) wherein R is a C.sub.1 to C.sub.6 alkyl group, R.sup.1 is an alkylene group, R.sup.2 is hydrogen or a C.sub.1 to C.sub.6 alkyl group and x is an integer from 1 to 6, (vi) a C.sub.1 to C.sub.20 monohydric alcohol, (vii) a C.sub.1 to C.sub.20 ketone, (viii) a C.sub.1 to C.sub.10 carboxylic acid ester, or (ix) a C.sub.1 to C.sub.20 ether,component (D) a lubricating oil,component (E) a defined carboxylic acid or derivative in an amount up to 60% by weight of the total weight of component (A) and component (E), said total weight of component (A) and component (E) being that required to satisfy an equivalent ratio of component (B) to component (A) plus component (E) of not greater than one.

摘要翻译： 一种用于生产润滑油添加剂浓缩物的方法，该方法包括在升高的温度下使组分（A）与所定义的酸或其衍生物，组分（B）在中间加入或加入多个添加物中的钙碱 （C）至少一种化合物，其为（i）水，（ii）具有2至4个碳原子的多元醇，（iii）二（C 3或C 4）二醇，（iv） 三（C 2 -C 4）二醇，（v）式（I）R（OR 1）x OR 2（I）的单 - 或多 - 亚烷基二醇烷基醚，其中R是C1至C6烷基，R1是亚烷基 ，R2为氢或C1〜C6烷基，x为1〜6的整数，（vi）C1〜C20一元醇，（vii）C1〜C20酮，（viii）C1〜C10羧酸酯 ，或（ix）C1至C20醚，组分（D）润滑油，组分（E）定量的羧酸或衍生物，其量高达组分（A）和化合物（A）的总重量的60重量％ 组分（A）和组分（E）的总重量是组分（B）与组分（A）的加入量与组分（E）的当量比不大于1所需的总重量。

公开(公告)号：US6090759A

公开(公告)日：2000-07-18

申请号：US991546

申请日：1997-12-16

申请人： Charles Cane ,  John Crawford ,  Sean Patrick O'Connor

发明人： Charles Cane ,  John Crawford ,  Sean Patrick O'Connor

IPC分类号： C10M159/22

CPC分类号： C10M159/20 ,  C10M159/22 ,  C10M2201/082 ,  C10M2203/10 ,  C10M2207/021 ,  C10M2207/022 ,  C10M2207/04 ,  C10M2207/046 ,  C10M2207/122 ,  C10M2207/126 ,  C10M2209/108 ,  C10N2210/02 ,  C10N2230/04 ,  C10N2230/52 ,  C10N2270/02

摘要： An additive concentrate suitable for incorporation into a finished lubricating oil composition is disclosed. The additive concentrate comprises:(a) a lubricating oil, and(b) a lubricating oil soluble sulphurized or non-sulphurized alkaline earth metal hydrocarbyl phenate modified by incorporation from 2 to less than 40% by weight based on the weight of said concentrate of either (i) at least one carboxylic acid having the formula: ##STR1## wherein R is a C.sub.10 to C.sub.24 alkyl or alkenyl group and R.sup.1 is either hydrogen, a C.sub.1 to C.sub.4 alkyl group or a --CH.sub.2 --COOH group, or an anhydride, acid chloride or ester thereof or (ii) a di- or polycarboxylic acid containing from 36 to 100 carbon atoms or an anhydride, acid chloride or ester thereof, said concentrate having a TBN greater than 300, and a viscosity at 100.degree. C. of less than 1,000 cSt. A process for making the foregoing concentrate is disclosed. A finished lubricating oil composition containing the foregoing concentrate is also disclosed.

摘要翻译： 公开了适于掺入成品润滑油组合物中的添加剂浓缩物。 添加剂浓缩物包括：（a）润滑油，和（b）润滑油可溶的硫化或非硫化碱土金属的烃基酚盐，其通过以所述浓缩物的重量计2至小于40重量％ （i）至少一种具有下式的羧酸：其中R是C 10至C 24烷基或烯基，R 1是氢，C 1至C 4烷基或-CH 2 -COOH基，或者酸酐，酰氯 或其酯或（ii）含有36至100个碳原子的二羧酸或多羧酸或其酸酐，酰氯或其酯，所述浓缩物的TBN大于300，而在100℃下的粘度小于 1,000 cSt 公开了制备上述浓缩物的方法。 还公开了含有上述浓缩物的成品润滑油组合物。

公开(公告)号：US5433871A

公开(公告)日：1995-07-18

申请号：US157336

申请日：1993-11-23

申请人： Sean P. O'Connor ,  John Crawford ,  Charles Cane

发明人： Sean P. O'Connor ,  John Crawford ,  Charles Cane

IPC分类号： C10M125/00 ,  C10M125/10 ,  C10M125/14 ,  C10M125/18 ,  C10M129/08 ,  C10M129/10 ,  C10M129/16 ,  C10M129/38 ,  C10M129/54 ,  C10M129/70 ,  C10M135/10 ,  C10M159/20 ,  C10M159/22 ,  C10M159/24 ,  C10M177/00 ,  C10N10/04 ,  C10N20/02 ,  C10N40/25 ,  C10N70/00

CPC分类号： C10M159/24 ,  C10M159/20 ,  C10M159/22 ,  C10M2201/082 ,  C10M2201/10 ,  C10M2207/021 ,  C10M2207/022 ,  C10M2207/04 ,  C10M2207/046 ,  C10M2207/08 ,  C10M2207/122 ,  C10M2207/126 ,  C10M2207/281 ,  C10M2209/108 ,  C10N2210/02 ,  C10N2230/04 ,  C10N2230/52 ,  C10N2270/02

摘要： A process for the production of a lubricating oil additive concentrate having a TBN greater than 300 which process comprises reacting at elevated temperaturecomponent (A) a defined mixture selected from defined sulphurized or non-sulphurized acids or calcium salts thereof,component (B) an alkaline earth metal base added either in a single addition or in a plurality of additions at intermediate points during the reaction,component (C) at least one compound which is (i) water, (ii) a polyhydric alcohol having 2 to 4 carbon atoms, (iii) a di- (C.sub.3 or C.sub.4) glycol, (iv) a tri-(C.sub.2 -C.sub.4) glycol, (v) a mono- or poly-alkylene glycol alkyl ether of the formula (I)R(OR.sup.1).sub.x OR.sup.2 (I)wherein R is a C.sub.1 to C.sub.6 alkyl group, R.sup.1 is an alkylene group, R.sup.2 is hydrogen or a C.sub.1 to C.sub.6 alkyl group and x is an integer from 1 to 6, (vi) a C.sub.1 to C.sub.20 monohydric alcohol, (vii) a C.sub.1 to C.sub.20 ketone, (viii) a C.sub.1 to C.sub.10 carboxylic acid ester, or (ix) a C.sub.1 to C.sub.20 ether,component (D) a lubricating oil,component (E) carbon dioxide added subsequent to the, or each, addition of component (B),component (F) a defined carboxylic acid or derivative,component (G) at least one compound which is (i) an inorganic halide or (ii) an ammonium alkanoate or a mono-, di-, tri- or tetra-alkyl ammonium formate or alkanoate provided that when component (G) is (ii), component (F) is not an acid chloride,the weight ratios of all components being such as to produce a concentrate having a TBN greater than 300.

摘要翻译： 一种生产TBN大于300的润滑油添加剂浓缩物的方法，该方法包括在升高的温度下将组分（A）与选自定义的硫化或非硫化酸或其钙盐的限定混合物反应，组分（B） （C）至少一种化合物，其为（i）水，（ii）具有2至4个碳原子的多元醇 ，（iii）二（C3或C4）二醇，（iv）三（C2-C4）二醇，（v）式（I）R（OR1）的单 - 或聚 - 亚烷基二醇烷基醚， xOR 2（I）其中R为C1至C6烷基，R1为亚烷基，R2为氢或C1至C6烷基，x为1至6的整数，（vi）C1至C20一元醇， （vii）C1至C20酮，（viii）C1至C10羧酸酯，或（ix）C1至C20醚，组分（D）润滑油，组分（E）碳二 组分（B），组分（F），所定义的羧酸或衍生物，组分（G），至少一种化合物（i）无机卤化物或（ii）链烷酸铵 或（C）是（ⅱ）组分（F）不是酰基氯，所有组分的重量比例如 产生TBN大于300的浓缩物。

公开(公告)号：US5716914A

公开(公告)日：1998-02-10

申请号：US410758

申请日：1995-03-27

申请人： Charles Cane ,  John Crawford ,  Sean Patrick O'Connor

发明人： Charles Cane ,  John Crawford ,  Sean Patrick O'Connor

IPC分类号： C10M159/22

CPC分类号： C10M159/20 ,  C10M159/22 ,  C10M2201/082 ,  C10M2203/10 ,  C10M2207/021 ,  C10M2207/022 ,  C10M2207/04 ,  C10M2207/046 ,  C10M2207/122 ,  C10M2207/126 ,  C10M2209/108 ,  C10N2210/02 ,  C10N2230/04 ,  C10N2230/52 ,  C10N2270/02

摘要： Process for producing an additive concentrate having a viscosity of less than 1000 cSt at 100 EC, by reacting at elevated temperature and in the presence of an inorganic halide or calcium acetate catalyst (A) either (i) a hydrocarbyl phenol or (ii) a hydrocarbyl phenol and sulphur, (B) an alkaline earth metal base added in either a single addition or in a plurality of additions during the reaction, (C) either a polyhydric alcohol having from 2 to 4 carbon atoms, a di- or tri- C.sub.2 to C.sub.4 glycol, an alkylene glycol alkyl ether or a polyalkylene glycol alkyl ether, (D) a lubricating oil, (E) carbon dioxide added subsequent to the, or each, addition of compound (B), and (F) sufficient to provide from 12 to less than 40% by weight based on the weight of the concentrate of either (i) a carboxylic acid having the formula RCH(R')COOH, wherein R is a C.sub.10 to C.sub.24 alkyl or alkenyl group and R is either hydrogen, a C.sub.1 to C.sub.4 alkyl group or a --CH.sub.2 --COOH group, or an anhydride, acid chloride or ester thereof or (ii) a di- or polycarboxylic acid containing from 36 to 100 carbon atoms or an anhydride, acid chloride or ester thereof, the weight ratios of components (A) to (F) being such as to produce a concentrate having a TBN greater than 350.

摘要翻译： 通过在升高的温度和无机卤化物或乙酸钙催化剂（A）的存在下反应制备具有小于1000cSt的添加剂浓缩物的添加剂浓缩物的方法，（i）烃基苯酚或（ii） 烃基苯酚和硫，（B）在反应期间单次加成或多次添加的碱土金属碱，（C）具有2至4个碳原子的多元醇，二 - 或三 - C2至C4二元醇，亚烷基二醇烷基醚或聚亚烷基二醇烷基醚，（D）润滑油，（E）在化合物（B）添加或每次加入化合物（B）后加入的二氧化碳，和（F） 以（i）具有式RCH（R'）COOH的羧酸（其中R为C 10至C 24烷基或链烯基）的浓缩物的重量计，提供12至小于40重量％，R为 氢，C1〜C4烷基或-CH2-COOH基，或酸酐，酰氯或酯 或（ii）含有36至100个碳原子的二元或多元羧酸或其酸酐，酰氯或其酯，组分（A）至（F）的重量比应为产生具有TBN浓度的浓缩物 大于350。

公开(公告)号：US5281345A

公开(公告)日：1994-01-25

申请号：US556823

申请日：1990-07-23

申请人： John Crawford ,  Sean P. O'Connor ,  Charles Cane

发明人： John Crawford ,  Sean P. O'Connor ,  Charles Cane

IPC分类号： C10M125/06 ,  C10M125/10 ,  C10M129/08 ,  C10M129/10 ,  C10M129/26 ,  C10M131/04 ,  C10M159/20 ,  C10M159/22 ,  C10M159/24 ,  C10M177/00 ,  C10N10/04 ,  C10N30/04 ,  C10N40/25 ,  C10N70/00 ,  C10M159/02

CPC分类号： C10M159/20 ,  C10M159/22 ,  C10M159/24

摘要： A process for the production of a lubricating oil additive concentrate comprises reacting at elevated temperature the following components:component (A) a defined acidcomponent (B)--a calcium base added either in a single addition or in a plurality of additions at intermediate points during the reaction,component (C)--at least one compound which is (i) water, (ii) a polyhydric alcohol having 2 to 4 carbon atoms, (iii) a di- (C.sub.3 or C.sub.4) glycol, (iv) a tri-(C.sub.2 -C.sub.4) glycol, (v) a mono- or poly-alkylene glycol alkyl ether of the formula (I)R(OR.sup.1).sub.x OR.sup.2 (I) wherein R is a C.sub.1 to C.sub.6 alkyl group, R.sup.1 is an alkylene group, R.sup.2 is hydrogen or a C.sub.1 to C.sub.6 alkyl group and x is an integer from 1 to 6, (vi) a C.sub.1 to C.sub.20 monohydric alcohol, (vii) a C.sub.1 to C.sub.20 ketone, (viii) a C.sub.1 to C.sub.10 carboxylic acid ester, or (ix) a C.sub.1 to C.sub.20 ether, optionally,component (D)--a lubricating oil,component (E)--carbon dioxide added subsequent to the, or each, addition of component (B), andcomponent (F)--a compound of formula IIR.sup.3 X (II) wherein X is a halogen and R.sup.3 is an alkyl, alkenyl or alkaryl group or halo derivative thereof.

摘要翻译： 用于生产润滑油添加剂浓缩物的方法包括在升高的温度下使以下组分反应：组分（A）所定义的酸组分（B） - 在中间点以单次添加或多次添加的钙碱 在反应期间，组分（C） - 至少一种化合物，其为（i）水，（ii）具有2至4个碳原子的多元醇，（iii）二（C3或C4）二醇，（iv） 三（C 2 -C 4）二醇，（v）式（I）R（OR 1）x OR 2（I）的单 - 或聚 - 亚烷基二醇烷基醚，其中R是C1至C6烷基，R1是亚烷基 基团，R 2是氢或C 1至C 6烷基，x是1至6的整数，（vi）C 1至C 20一元醇，（vii）C 1至C 20酮，（viii）C 1至C 10羧酸 酯，或（ix）C1至C20醚，任选的组分（D） - 在组分（B）添加或每次加入组分（B）和组分（F）后加入的润滑油，组分（E） - 二氧化碳， - 式I化合物 I R3X​​（II）其中X是卤素，R3是烷基，烯基或烷芳基或其卤代衍生物。

公开(公告)号：US6090760A

公开(公告)日：2000-07-18

申请号：US991547

申请日：1997-12-16

申请人： Charles Cane ,  John Crawford ,  Sean Patrick O'Connor

发明人： Charles Cane ,  John Crawford ,  Sean Patrick O'Connor

IPC分类号： C10M159/22

CPC分类号： C10M159/22

摘要： An additive concentrate suitable for incorporation into a finished lubricating oil composition is disclosed. The additive concentrate comprises: (a) a lubricating oil; (b) a lubricating oil soluble sulphurized alkaline earth metal hydrocarbyl phenate modified by incorporation of from greater than 2 to 35% by weight based on the weight of the composition of either (i) at least one carboxylic acid having formula (I), ##STR1## wherein R is C.sub.10 to C.sub.24 alkyl or alkenyl group and R.sup.1 is either hydrogen, a C.sub.1 to C.sub.4 alkyl group or a --CH.sub.2 --COOH group, or an anhydride, acid chloride or ester thereof or (ii) a di- or polycarboxylic acid containing from 36 to 100 carbon atoms or an anhydride, acid chloride or ester thereof, the composition having a TBN greater than 300. A process for making the foregoing additive concentrate is disclosed. A finished lubricating oil composition containing the foregoing additive concentrate is also disclosed.

摘要翻译： 公开了适于掺入成品润滑油组合物中的添加剂浓缩物。 添加剂浓缩物包括：（a）润滑油; （b）基于组合物的重量，通过掺入大于2至35重量％的（i）至少一种具有式（I）的羧酸的重量来润滑油溶性硫化碱土金属烃基酚盐，其中 R为C 10至C 24烷基或烯基，R 1为氢，C 1至C 4烷基或-CH 2 -COOH基，或其酸酐，酰氯或其酯，或（ⅱ）二 36至100个碳原子或酸酐，酰氯或其酯，组合物的TBN大于300.公开了制备上述添加剂浓缩物的方法。 还公开了含有上述添加剂浓缩物的成品润滑油组合物。

公开(公告)号：US5714443A

公开(公告)日：1998-02-03

申请号：US339650

申请日：1994-11-14

申请人： Charles Cane ,  John Crawford ,  Sean Patrick O'Connor

发明人： Charles Cane ,  John Crawford ,  Sean Patrick O'Connor

IPC分类号： C10M159/22

CPC分类号： C10M159/22

摘要： An additive concentrate suitable for incorporation into a into a finished lubricating oil composition, the additive concentrate comprising: (a) a lubricating oil; (b) a lubricating oil soluble sulphurised alkaline earth metal hydrocarbyl phenate modified by incorporation of from greater than 2 to 35% by weight based on the weight of the composition of either (i) at least one carboxylic acid having formula (I), wherein R is C.sub.10 to C.sub.24 alkyl or alkenyl group and R.sup.1 is either hydrogen, a C.sub.1 to C.sub.4 alkyl group or a --CH.sub.2 --COOH group, or an anhydride, acid chloride or ester thereof or (ii) a di- or polycarboxylic acid containing from 36 to 100 carbon atoms or an anhydride, acid chloride or ester thereof, the composition having a TBN greater than 300.

摘要翻译： 适用于加入成品润滑油组合物中的添加剂浓缩物，所述添加剂浓缩物包含：（a）润滑油; （b）基于组合物的重量，通过掺入大于2至35重量％的（i）至少一种具有式（I）的羧酸的重量来润滑油溶性硫化碱土金属烃基酚盐，其中 R为C 10至C 24烷基或烯基，R 1为氢，C 1至C 4烷基或-CH 2 -COOH基，或其酸酐，酰氯或其酯，或（ⅱ）二 36至100个碳原子或酸酐，酰氯或其酯，该组合物的TBN大于300。

公开(公告)号：US5451331A

公开(公告)日：1995-09-19

申请号：US207222

申请日：1994-03-04

申请人： Sean P. O'Connor ,  John Crawford ,  Charles Cane

发明人： Sean P. O'Connor ,  John Crawford ,  Charles Cane

IPC分类号： C10M159/20 ,  C10M125/00 ,  C10M125/10 ,  C10M125/18 ,  C10M125/20 ,  C10M129/08 ,  C10M129/16 ,  C10M129/38 ,  C10M129/54 ,  C10M129/70 ,  C10M135/30 ,  C10M159/22 ,  C10N10/04 ,  C10N20/02 ,  C10N60/10 ,  C10N70/00

CPC分类号： C10M159/22

摘要： A process for the production of a lubricating oil additive concentrate having a TBN greater than 300 comprises reacting at elevated temperaturecomponent (A) a defined salicylic acid derivative,component (B) an alkaline earth metal base added either in a single addition or in a plurality of additions at internediate points during the reaction,component (C) at least one compound which is (i) water, (ii) a polyhydric alcohol having 2 to 4 carbon atoms, (iii) a di- (C.sub.3 or C.sub.4) glycol, (iv) a tri- (C.sub.2 -C.sub.4) glycol, (iv) a mono- or poly-alkylene glycol alkyl ether of the formula (I)R(OR.sup.1).sub.x OR.sup.2 (I)wherein R is a C.sub.1 to C.sub.6 alkyl group, R.sup.1 is an alkylene group R.sup.2 is hydrogen or a C.sub.1 to C.sub.6 alkyl group and x is an integer from 1 to 6, (vi) a C.sub.1 to C.sub.20 monohydric alcohol, (vii) a C.sub.1 to C.sub.20 ketone, (viii) a C.sub.1 to C.sub.10 carboxylic acid ester, or (ix) a C.sub.1 to C.sub.20 ether,component (D) a lubricating oil,component (E) carbon dioxide added subsequent to the, or each, addition of component (B),component (F) a defined carboxylic acid or derivative, andcomponent (G) at least one compound which is (i) an inorganic halide of (ii) an ammonium alkanoate or mono-, di-, tri- or tetra-alkyl ammonium formate or alkanoate provided that, when component (G) is (ii), component (F) is not an acid chloride,the weight ratios of all components being such as to produce a concentrate having a TBN greater than 300.

摘要翻译： 生产TBN大于300的润滑油添加剂浓缩物的方法包括在升高的温度下使组分（A）与定义的水杨酸衍生物，组分（B）一起添加的碱土金属碱反应， （C）至少一种化合物，其为（i）水，（ii）具有2至4个碳原子的多元醇，（iii）二（C3或C4）二醇 ，（iv）三 - （C 2 -C 4）二醇，（iv）式（I）R（OR 1）x OR 2（I）的单 - 或多 - 亚烷基二醇烷基醚，其中R是C1至C6烷基 R1为亚烷基R2为氢或C1〜C6烷基，x为1〜6的整数，（vi）C1〜C20一元醇，（vii）C1〜C20酮，（viii）C1 至（C）的碳酸酯，或（ix）C1至C20醚，组分（D）润滑油，组分（E）中添加的组分（B），组分（F） ）定义的羧酸或衍生物，和组分（G）至少一种化合物，其是（i）无机卤化物，（ii）烷基铵或烷基甲酸烷基酯或烷酸烷基酯的单，二，三或四烷基铵 当组分（G）为（ⅱ）时，组分（F）不是酰氯，所有组分的重量比都要产生TBN大于300的浓缩物。

公开(公告)号：US5384053A

公开(公告)日：1995-01-24

申请号：US202665

申请日：1994-02-25

申请人： Charles Cane ,  John Crawford ,  Sean P. O'Connor

发明人： Charles Cane ,  John Crawford ,  Sean P. O'Connor

IPC分类号： C10M159/20 ,  C07G99/00 ,  C10M159/24 ,  C10N10/04 ,  C10N20/02 ,  C10N40/25 ,  C10N70/00

CPC分类号： C10M159/24 ,  C07G17/004 ,  C10M2201/082 ,  C10M2203/10 ,  C10M2207/021 ,  C10M2207/022 ,  C10M2207/04 ,  C10M2207/046 ,  C10M2207/08 ,  C10M2207/126 ,  C10M2207/281 ,  C10M2209/108 ,  C10N2210/02 ,  C10N2230/04 ,  C10N2230/06 ,  C10N2230/52 ,  C10N2240/102 ,  C10N2270/02

摘要： A process for the production of a lubricating oil additive concentrate comprises reacting at elevated temperaturecomponent (A) a calcium hydrocarbyl-substituted sulphonate,component (B) an alkaline earth metal base added either in a single addition or in a plurality of additions at intermediate points during the reaction,component (C) at least one compound which is (i) a polyhydric alcohol having 2 to 4 carbon atoms, (ii) a di- (C.sub.3 or C.sub.4) glycol, (iii) a tri- (C.sub.2 -C.sub.4) glycol, (iv) a mono- or poly-alkylene glycol alkyl ether of the formula (I)R(OR.sup.1).sub.x OR.sup.2 (I)wherein R is a C.sub.1 to C.sub.6 alkyl group, R.sup.1 is an alkylene group, R.sup.2 is hydrogen or a C.sub.1 to C.sub.6 alkyl group and x is an integer from 1 to 6, (v) a C.sub.1 to C.sub.20 monohydric alcohol, (vi) a C.sub.1 to C.sub.20 ketone, (vii) a C.sub.1 to C.sub.10 carboxylic acid ester, or (viii) a C.sub.1 to C.sub.20 ether,component (D) a lubricating oil,component (E) carbon dioxide added subsequent to the, or each, addition of component (B),component (F) a defined carboxylic acid or derivative, component (G) at least one compound which is (i) an inorganic halide or (ii) an ammonium alkanoate or a mono-, di-, tri-, or tetra-alkyl ammonium formate or alkanoate provided that, when component (G) is (it), component (F) is not an acid chloride.

摘要翻译： 制备润滑油添加剂浓缩物的方法包括在升高的温度下使组分（A）烃基取代的烃磺酸钙，组分（B）在中间体中以单一添加剂或多种添加剂加入的碱土金属碱 （C）至少一种化合物，其为（i）具有2至4个碳原子的多元醇，（ii）二（C3或C4）二醇，（iii）三 - （C2- C4）二醇，（iv）式（I）R（OR1）xOR2（I）的单 - 或聚 - 亚烷基二醇烷基醚，其中R是C1-C6烷基，R1是亚烷基，R2是氢 或C1〜C6烷基，x为1〜6的整数，（v）C1〜C20一元醇，（vi）C1〜C20酮，（vii）C1〜C10羧酸酯或（viii） ）组分（D），组分（D）润滑油，组分（E）二氧化碳，在组分（B），组分（F）中加入或分别加入一种所定义的羧酸或de （G）至少一种化合物，其为（i）无机卤化物或（ii）烷基铵或单 - ，二 - ，三 - 或四 - 烷基甲酸铵或链烷酸铵，条件是当组分（ G）是（it），组分（F）不是酰氯。

公开(公告)号：US5441652A

公开(公告)日：1995-08-15

申请号：US158143

申请日：1993-11-24

申请人： Sean P. O'Connor ,  Charles Cane

发明人： Sean P. O'Connor ,  Charles Cane

IPC分类号： C10M159/20 ,  C07G99/00 ,  C10M125/00 ,  C10M125/10 ,  C10M125/14 ,  C10M125/18 ,  C10M129/04 ,  C10M129/16 ,  C10M129/38 ,  C10M129/70 ,  C10M159/22 ,  C10M177/00 ,  C10N10/04 ,  C10N20/02 ,  C10N40/25 ,  C10N70/00

CPC分类号： C07G17/002 ,  C10M159/22

摘要： A process for the production of a lubricating oil additive concentrate having a TBN greater than 300 which process comprises reactingcomponent (A) a defined derivative of phenolcomponent (B) an alkaline earth metal base added either in a single addition of in a plurality of additions at intermediate points during the reaction,component (C) at least one compound which is (i) water, (ii) a C.sub.1 to C.sub.10 monohydric alcohol, (iii) a C.sub.1 to C.sub.20 ketone, (iv) a C.sub.1 to C.sub.10 carboxylic acid ester or (v) a C.sub.1 to C.sub.20 ether,component (D) a lubricating oil,component (E) carbon dioxide added subsequent to the, or each, addition of component (B),component (F) a defined carboxylic acid or derivativecomponent (G) at least one compound which is (i) an inorganic halide or (ii) an ammonium alkanoate or a mono-, di-, tri, or tetra-alkyl ammonium formate or alkanoate provided that, when component (G) is (ii), component (F) is not an acid chloride,the weight ratios of all components being such as to produce a concentrate having a TBN greater than 300.

摘要翻译： 一种生产TBN大于300的润滑油添加剂浓缩物的方法，该方法包括将组分（A）定义为苯酚组分（B）的衍生物，碱金属碱添加在多个 在反应中的中间点添加，组分（C）至少一种化合物，其为（i）水，（ii）C1至C10一元醇，（iii）C1至C20酮，（iv）C1至C10羧酸 酸性酯或（v）C1至C20醚，组分（D）润滑油，组分（E）二氧化碳，在组分（B），组分（F）中加入或每次加入所定义的羧酸或 衍生物组分（G）至少一种化合物，其为（i）无机卤化物或（ii）烷基铵或单 - ，二 - ，三 - 或四 - 烷基铵甲酸铵或链烷酸酯，条件是当组分（G） 是（ⅱ）中，组分（F）不是酰氯，所有组分的重量比都要生成 TBN大于300的浓缩物。