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公开(公告)号：US5523265A
公开(公告)日：1996-06-04
申请号：US434223
申请日：1995-05-04
CPC分类号： C03C13/00 , C03C3/078 , C03C2213/02
摘要： Fiberizable glass composition with increased levels of BaO are suitable for insulation. These glasses have physical properties which allow current processes to fabricate them into insulation. The glasses also meet proposed German regulations regarding KI.gtoreq.40.
摘要翻译： 具有提高BaO含量的可玻璃化玻璃组合物适用于绝缘。 这些玻璃具有允许当前工艺将其制成绝缘体的物理性质。 眼镜也符合德国关于KI> = = 40的规定。
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公开(公告)号：US6034014A
公开(公告)日：2000-03-07
申请号：US905494
申请日：1997-08-04
CPC分类号： C03C13/00 , C03C2213/02
摘要： The glass compositions of the present invention contain at least 2.0 wt % Al.sub.2 O.sub.3 to give resulting glass fiber an acceptable chemical durability for product performance, but no more than 3.0 wt % to ensure the fiber maintains a relatively high biosolubility. The compositions further include relatively high amount of Na.sub.2 O+K.sub.2 O+MgO+CaO, which tends to increase fiber biosolubility and allows for the use of reduced amounts of B.sub.2 O.sub.3 in the composition. The glass compositions have KI values that generally equal or exceed a KI value of 40 and are suitable for rotary processing. The compositions have liquidus temperatures below about 1800.degree. F. and viscosities above 300 Poise at the liquidus temperature. For higher B.sub.2 O.sub.3 compositions the liquidus temperatures are below 1650.degree. F., and the viscosities are above 1,000 Poises at the liquidus temperatures.
摘要翻译： 本发明的玻璃组合物含有至少2.0重量％的Al 2 O 3，以使所得的玻璃纤维具有可接受的产品性能的化学耐久性，但不超过3.0重量％以确保纤维保持较高的生物溶解性。 组合物还包括相对高量的Na 2 O + K 2 O + MgO + CaO，其倾向于增加纤维生物溶解性并允许在组合物中使用减少量的B 2 O 3。 玻璃组合物的KI值通常等于或超过KI值40，并且适用于旋转加工。 该组合物在液相线温度下的液相线温度低于约1800°F，粘度高于300泊。 对于较高的B2O3组成，液相线温度低于1650°F，液相线温度下粘度高于1,000泊。
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公开(公告)号：US5622903A
公开(公告)日：1997-04-22
申请号：US639656
申请日：1996-04-29
申请人： Charles F. Rapp , Russell M. Potter
发明人： Charles F. Rapp , Russell M. Potter
CPC分类号： C03C13/00 , C03C2213/02 , C03C2213/04
摘要： Irregularly shaped glass fibers and insulation therefrom comprise two different glasses having differing coefficients of thermal expansion. These glasses also have physical properties which allow current processes to fabricate them into insulation. The glasses also meet German recommendations regarding a KI value of 40 or above.
摘要翻译： 不规则形状的玻璃纤维和其绝缘材料包括具有不同热膨胀系数的两种不同的玻璃。 这些玻璃还具有物理性质，其允许当前工艺将其制造成绝缘体。 眼镜还符合德国关于KI值在40以上的建议。
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公开(公告)号：US5576252A
公开(公告)日：1996-11-19
申请号：US434620
申请日：1995-05-04
申请人： Charles F. Rapp , Neil M. Cameron , Ron W. Mayhew
发明人： Charles F. Rapp , Neil M. Cameron , Ron W. Mayhew
IPC分类号： C03B37/075 , C03C13/06 , C03C13/00
CPC分类号： C03B37/0753 , C03C13/06 , C03C2213/04
摘要： Irregularly-shaped glass fibers and insulation therefrom comprising two different glasses having differing coefficients of thermal expansion. The irregularly-shaped dual-glass fibers exhibit a substantially uniform volume filling nature, and provide improved recovery and thermal conductivity abilities even in the absence of a binder material.
摘要翻译： 不规则形状的玻璃纤维及其绝缘材料包括具有不同热膨胀系数的两种不同的玻璃。 不规则形状的双玻璃纤维表现出基本均匀的体积填充性质，并且即使在不存在粘合剂材料的情况下也提供改进的回收率和导热性能。
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公开(公告)号：US4836837A
公开(公告)日：1989-06-06
申请号：US121303
申请日：1987-11-16
申请人： Charles F. Rapp
发明人： Charles F. Rapp
摘要： Provided is a process for making metal coated non-crystallized, amorphous glass fibers. The process fiberizes a glass containing a metal oxide such as cuprous oxide. The process then heat-treats the fibers to form a semi-conductive layer of copper oxide on the surface. A subsequent reactive reduction step produces a semi-continuous film of metallic copper. This is conductive enough for many radar applications.
摘要翻译： 提供了制造金属涂层的非结晶的无定形玻璃纤维的方法。 该方法使含有金属氧化物的玻璃如氧化亚铜纤维化。 然后，该过程热处理纤维以在表面上形成氧化铜的半导体层。 随后的反应还原步骤产生金属铜的半连续膜。 这对于许多雷达应用是足够导电的。
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公开(公告)号：US5081076A
公开(公告)日：1992-01-14
申请号：US604294
申请日：1990-10-29
申请人： Charles F. Rapp
发明人： Charles F. Rapp
IPC分类号： C03C3/32
CPC分类号： C03C3/325 , Y10S501/904
摘要： Crystallization-resistant, low liquidus, fluoride glasses are disclosed which consist essentially of ZrF.sub.4, optionally HfF.sub.4, BaF.sub.2, at least one of CsF or NaF, preferably AlF.sub.3 and LaF.sub.3, and at least one of InF.sub.3, YF.sub.3 and GaF.sub.3. The glasses are of utility as optical components because of their high IR transmission.
摘要翻译： 公开了耐结晶，低液相，氟化物玻璃，其基本上由ZrF 4，任选HfF 4，BaF 2，CsF或NaF，优选AlF 3和LaF 3中的至少一种以及InF 3，YF 3和GaF 3中的至少一种组成。 由于它们的高红外透射率，这种眼镜作为光学部件是有用的。
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公开(公告)号：US4631178A
公开(公告)日：1986-12-23
申请号：US485972
申请日：1983-04-18
申请人： Charles F. Rapp , Robert A. Herrick
发明人： Charles F. Rapp , Robert A. Herrick
CPC分类号： B01D53/46
摘要： A method of removing boron from gases which comprises passing the gas stream in contact with solid sodium bicarbonate.
摘要翻译： 一种从气体中除去硼的方法，包括使气流与固体碳酸氢钠接触。
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公开(公告)号：US4142986A
公开(公告)日：1979-03-06
申请号：US897990
申请日：1978-04-20
申请人： Charles F. Rapp
发明人： Charles F. Rapp
CPC分类号： C03C3/247 , C03C4/0071
摘要： Disclosed are phosphorus glasses containing beryllium and fluorine and Nd.sup.3+ as the active lasing species.
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9.发明授权Ion-exchangeable germanate method for strengthened germanate glass articles 失效用于强化锗酸盐玻璃制品的可离子交换的锗酸盐法
公开(公告)号：US4849002A
公开(公告)日：1989-07-18
申请号：US113936
申请日：1987-10-27
申请人： Charles F. Rapp
发明人： Charles F. Rapp
CPC分类号： C03C3/253 , C03C21/002
摘要： Ion exchangeable glass compositions containing from 50 to 90 mole percent GeO.sub.2, from 5 to 30 mole percent Al.sub.2 O.sub.3, from 3 to 30 mole percent Li.sub.2 O, up to 30 mole percent Na.sub.2 O and up to 30 mole percent K.sub.2 O are provided. In another aspect, minor amounts of anhydrous fluorides and chlorides corresponding to these oxides are added to the glass compositions to aid in water removal. Glass articles formed of the germanate glass compositions of the present invention are readily ion exchangeable when contacted with certain salts. Strengthened germanate glass articles are also provided having an inner tension region and an outer compressive surface layer which provide good mechanical strength for the formed glass article. The strengthened germanate glass articles are made using the ion exchangeable germanate glass compositions of the present invention. The compressive surface layer of the strengthened germanate glass articles are formed by contacting the surface of the glass article with a suitable salt, preferably a molten alkali salt, in an ion exchange process. The surface compressive layer of the strengthened germanate glass article has a lower concentration of lithium ions than the inner tension region and has a higher concentration of select ions provided by the salt bath.
摘要翻译： 提供了含有50至90摩尔％的GeO 2，5至30摩尔％的Al 2 O 3，3至30摩尔％的Li 2 O，至多30摩尔％的Na 2 O和至多30摩尔％的K 2 O的可离子交换玻璃组合物。 另一方面，将相当于这些氧化物的少量无水氟化物和氯化物加入到玻璃组合物中以有助于除水。 由本发明的锗酸盐玻璃组合物形成的玻璃制品在与某些盐接触时容易离子交换。 还提供了加强的锗酸盐玻璃制品，其具有内部张力区域和外部压缩表面层，其为所形成的玻璃制品提供良好的机械强度。 强化的锗酸盐玻璃制品使用本发明的可离子交换的锗酸盐玻璃组合物制成。 加强的锗酸盐玻璃制品的压缩表面层是通过在离子交换过程中使玻璃制品的表面与合适的盐，优选熔融的碱金属盐接触而形成的。 加强的锗酸盐玻璃制品的表面压缩层具有比内部张力区域低的锂离子浓度，并且具有由盐浴提供的更高浓度的选择离子。
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公开(公告)号：US4406681A
公开(公告)日：1983-09-27
申请号：US70596
申请日：1979-08-29
申请人： Charles F. Rapp
发明人： Charles F. Rapp
摘要： Disclosed is a process for preparing fluorescent inorganic glasses containing Nd.sub.2 O.sub.3 as a fluorescent species and containing MnO as a sensitizer but containing essentially no higher oxides of manganese. In the disclosed process an internal reducing agent is employed in the melting of the glass and such agent reduces the higher oxides of manganese upon cooling of the melt.
摘要翻译： 公开了一种制备含有Nd 2 O 3作为荧光物质并含有MnO作为敏化剂但基本上不含较高的锰的氧化物的荧光无机玻璃的方法。 在所公开的方法中，使用内部还原剂来熔化玻璃，并且这种试剂在熔化物冷却时还原了较高的锰氧化物。
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