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    Brominated anionic styrenic polymers and their preparation
    4.
    发明授权
    Brominated anionic styrenic polymers and their preparation 有权
    溴化阴离子苯乙烯聚合物及其制备

    公开(公告)号：US08071688B2

    公开(公告)日：2011-12-06

    申请号：US12636250

    申请日：2009-12-11

    申请人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    发明人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    IPC分类号： C08F12/08

    CPC分类号： C08F8/20 ,  C08F8/22 ,  C08F12/00 ,  C08F12/08

    摘要： Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.

    摘要翻译： 同时加入保持在约10℃或更低的反应区域的是溴化剂，卤化铝催化剂和具有大约2000-30,000的GPC Mn的阴离子苯乙烯聚合物溶液。 这些组件至少有两个单独的进料流。 进料成比例以维持（a）基于所加入的聚合物中芳族单体单元的量，以约0.8摩尔％或更少的量加入卤化铝的量，和（b）溴化剂和未溴化聚合物的量 反应区，其产生含有约60-71重量％溴的最终洗涤和干燥的聚合物产物。 催化剂失活，溴化物离子和催化剂残余物从反应混合物中洗去，回收溴化阴离子苯乙烯聚合物并干燥。 干燥的聚合物具有约600ppm（wt / wt）或更低的挥发性溴苯含量以及其它有益特性。

    Brominated anionic styrenic polymers and their preparation
    5.
    发明授权
    Brominated anionic styrenic polymers and their preparation 有权
    溴化阴离子苯乙烯聚合物及其制备

    公开(公告)号：US07638583B2

    公开(公告)日：2009-12-29

    申请号：US11612991

    申请日：2006-12-19

    申请人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    发明人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    IPC分类号： C08F12/08

    CPC分类号： C08F8/20 ,  C08F8/22 ,  C08F12/00 ,  C08F12/08

    摘要： Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.

    摘要翻译： 同时加入保持在约10℃或更低的反应区域的是溴化剂，卤化铝催化剂和具有大约2000-30,000的GPC Mn的阴离子苯乙烯聚合物溶液。 这些组件至少有两个单独的进料流。 进料成比例以维持（a）以所加入的聚合物中的芳族单体单元的量为基准，以约0.8摩尔％或更少的量加入卤化铝的量，和（b）溴化剂和未溴化聚合物的量 反应区，其产生含有约60-71重量％溴的最终洗涤和干燥的聚合物产物。 催化剂失活，溴化物离子和催化剂残余物从反应混合物中洗去，回收溴化阴离子苯乙烯聚合物并干燥。 干燥的聚合物具有约600ppm（wt / wt）或更低的挥发性溴苯含量以及其它有益特性。

    Brominated Anionic Styrenic Polymers and Their Preparation
    6.
    发明申请
    Brominated Anionic Styrenic Polymers and Their Preparation 有权
    溴化阴离子苯乙烯聚合物及其制备

    公开(公告)号：US20100087620A1

    公开(公告)日：2010-04-08

    申请号：US12636250

    申请日：2009-12-11

    申请人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    发明人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    IPC分类号： C08G79/00

    CPC分类号： C08F8/20 ,  C08F8/22 ,  C08F12/00 ,  C08F12/08

    摘要： Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.

    摘要翻译： 同时加入保持在约10℃或更低的反应区域的是溴化剂，卤化铝催化剂和具有大约2000-30,000的GPC Mn的阴离子苯乙烯聚合物溶液。 这些组件至少有两个单独的进料流。 进料成比例以维持（a）以所加入的聚合物中的芳族单体单元的量为基准，以约0.8摩尔％或更少的量加入卤化铝的量，和（b）溴化剂和未溴化聚合物的量 反应区，其产生含有约60-71重量％溴的最终洗涤和干燥的聚合物产物。 催化剂失活，溴化物离子和催化剂残余物从反应混合物中洗去，回收溴化阴离子苯乙烯聚合物并干燥。 干燥的聚合物具有约600ppm（wt / wt）或更低的挥发性溴苯含量以及其它有益特性。

    Preparation of brominated styrenic polymers or resins
    7.
    发明授权
    Preparation of brominated styrenic polymers or resins 有权
    制备溴化苯乙烯聚合物或树脂

    公开(公告)号：US07446153B2

    公开(公告)日：2008-11-04

    申请号：US11612705

    申请日：2006-12-19

    申请人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    发明人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    IPC分类号： C08F8/18

    CPC分类号： C08F8/20 ,  C08F12/16 ,  C08F12/00

    摘要： Bromination of styrenic polymer is carried out in a closed reaction system to retain HX coproduct (where HX is HBr or HCl, or both) in the bromination reaction mixture at superatmospheric pressure. Preferably, the reaction mixture which includes the brominated styrenic polymer and substantially all of the HX coproduct formed is discharged into an aqueous quenching medium. By operating in this manner, the reaction is terminated and the brominated styrenic polymer of desired bromine content and substantially all HX coproduct are captured in the same operation, process equipment costs are reduced, and processing of the reaction mixture is facilitated.

    摘要翻译： 苯乙烯聚合物的溴化在闭合反应体系中进行，以在超大气压下在溴化反应混合物中保留HX副产物（其中HX为HBr或HCl或两者）。 优选地，将包含溴化苯乙烯聚合物和基本上所有形成的HX副产物的反应混合物排出到含水淬火介质中。 以这种方式操作，终止反应，并且在相同的操作中捕获所需溴含量和基本上所有HX副产物的溴化苯乙烯聚合物，降低了工艺设备成本，并且促进了反应混合物的加工。

    Catalyst recovery for halogen exchange reactions
    10.
    发明授权
    Catalyst recovery for halogen exchange reactions 失效
    用于卤素交换反应的催化剂回收

    公开(公告)号：US06215032B1

    公开(公告)日：2001-04-10

    申请号：US09021690

    申请日：1998-02-10

    申请人： Chi Hung Cheng ,  John F. Balhoff ,  Ronny W. Lin

    发明人： Chi Hung Cheng ,  John F. Balhoff ,  Ronny W. Lin

    IPC分类号： C07C2200

    CPC分类号： B01J31/0237 ,  B01J31/0268 ,  B01J31/0271 ,  B01J31/26 ,  B01J31/4053 ,  B01J2231/4277 ,  C07B39/00 ,  C07C17/208 ,  C07C17/38 ,  C07C45/63 ,  C07F9/025 ,  Y02P20/584 ,  C07C25/13

    摘要： It has been found possible to separate catalytically-active aminophosphonium catalysts from mixtures composed predominately of aminophosphonium catalyst residue(s) and heavy ends from a halogen exchange reaction conducted in an aprotic solvent/diluent by extracting such mixtures with a neutral or acidic aqueous extraction solvent medium. Various ways of isolating from the halogen exchange reaction product mixture a mixture composed predominately of aminophosphonium catalyst residue(s) and heavy ends are described. Halogen exchange processes in which the catalytically-active aminophosphonium catalysts are separated for reuse are also described. Since aminophosphonium catalysts are expensive, the present process technology fulfills a need which has existed for an effective way of recovering such catalysts in catalytically active form enabling reuse of such materials, especially as halogen exchange catalysts.

    摘要翻译： 已经发现有可能将催化活性的氨基鏻催化剂与主要由氨基鏻催化剂残余物和重馏分组成的混合物从在非质子溶剂/稀释剂中进行的卤素交换反应分离，通过用中性或酸性水性萃取溶剂萃取该混合物 中。 描述了从卤素交换反应产物混合物中分离出各种主要由氨基鏻催化剂残余物和重馏分组成的混合物的方式。 还描述了催化活性氨基鏻催化剂被分离用于再利用的卤素交换方法。 由于氨基鏻催化剂是昂贵的，因此本发明的工艺技术满足了一种需要有效的回收这种催化活性形式的催化剂的方法，使得能够重复使用这种材料，特别是作为卤素交换催化剂。