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    Converting Brominated Anionic Styrenic Polymer Into Harder and Larger Form for Storage, Shipment, and Use
    5.
    发明申请
    Converting Brominated Anionic Styrenic Polymer Into Harder and Larger Form for Storage, Shipment, and Use 审中-公开
    将溴化阴离子苯乙烯聚合物转换成更硬和更大的存储，装运和使用形式

    公开(公告)号：US20100047577A1

    公开(公告)日：2010-02-25

    申请号：US12515420

    申请日：2007-07-18

    申请人： Douglas W. Luther ,  John F. Balhoff ,  Robert C. Herndon, JR. ,  Bruce C. Peters

    发明人： Douglas W. Luther ,  John F. Balhoff ,  Robert C. Herndon, JR. ,  Bruce C. Peters

    IPC分类号： B32B5/16 ,  B29B9/00

    CPC分类号： B29B9/10 ,  B29B9/12 ,  B29K2025/00 ,  C08F8/20 ,  C08J3/12 ,  C08J2325/18 ,  Y10T428/2982 ,  C08F12/08

    摘要： Granules/pastilles of unadulterated brominated anionic styrenic polymer are prepared and provided. They are made by forming a downward plug flow from an orifice in a manifold or nozzle in proximity to a cooled traveling planar member. Such member is impervious to cooling liquid. There is a gap between the lower end of the orifice and the planar member. A portion of a plug of the molten polymer either (i) bridges such gap or (ii) freely drops from the orifice and falls upon the planar member, in either case forming an individual granule/pastille on the planar member and solidifies thereon. The traveling member is cooled by a mist or spray of cooling liquid applied to the underside of the planar member. The granules/pastilles have superior properties.

    摘要翻译： 制备和提供未掺杂的溴化阴离子苯乙烯聚合物的颗粒/锭剂。 它们通过从歧管或喷嘴中的孔口形成向下的塞子流，靠近冷却的行进平面构件。 这种构件不会冷却液体。 在孔的下端和平面构件之间存在间隙。 （i）熔融聚合物的塞子的一部分（i）桥接这样的间隙或（ii）自由地从孔口落下并落在平面构件上，在任一情况下，在平面构件上形成单独的颗粒/糊料并在其上固化。 行进构件被施加到平面构件的下侧的冷却液体的雾或喷雾冷却。 颗粒/锭剂具有优异的性能。

    Brominated anionic styrenic polymers and their preparation
    6.
    发明授权
    Brominated anionic styrenic polymers and their preparation 有权
    溴化阴离子苯乙烯聚合物及其制备

    公开(公告)号：US08071688B2

    公开(公告)日：2011-12-06

    申请号：US12636250

    申请日：2009-12-11

    申请人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    发明人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    IPC分类号： C08F12/08

    CPC分类号： C08F8/20 ,  C08F8/22 ,  C08F12/00 ,  C08F12/08

    摘要： Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.

    摘要翻译： 同时加入保持在约10℃或更低的反应区域的是溴化剂，卤化铝催化剂和具有大约2000-30,000的GPC Mn的阴离子苯乙烯聚合物溶液。 这些组件至少有两个单独的进料流。 进料成比例以维持（a）基于所加入的聚合物中芳族单体单元的量，以约0.8摩尔％或更少的量加入卤化铝的量，和（b）溴化剂和未溴化聚合物的量 反应区，其产生含有约60-71重量％溴的最终洗涤和干燥的聚合物产物。 催化剂失活，溴化物离子和催化剂残余物从反应混合物中洗去，回收溴化阴离子苯乙烯聚合物并干燥。 干燥的聚合物具有约600ppm（wt / wt）或更低的挥发性溴苯含量以及其它有益特性。

    Brominated anionic styrenic polymers and their preparation
    7.
    发明授权
    Brominated anionic styrenic polymers and their preparation 有权
    溴化阴离子苯乙烯聚合物及其制备

    公开(公告)号：US07638583B2

    公开(公告)日：2009-12-29

    申请号：US11612991

    申请日：2006-12-19

    申请人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    发明人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    IPC分类号： C08F12/08

    CPC分类号： C08F8/20 ,  C08F8/22 ,  C08F12/00 ,  C08F12/08

    摘要： Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.

    摘要翻译： 同时加入保持在约10℃或更低的反应区域的是溴化剂，卤化铝催化剂和具有大约2000-30,000的GPC Mn的阴离子苯乙烯聚合物溶液。 这些组件至少有两个单独的进料流。 进料成比例以维持（a）以所加入的聚合物中的芳族单体单元的量为基准，以约0.8摩尔％或更少的量加入卤化铝的量，和（b）溴化剂和未溴化聚合物的量 反应区，其产生含有约60-71重量％溴的最终洗涤和干燥的聚合物产物。 催化剂失活，溴化物离子和催化剂残余物从反应混合物中洗去，回收溴化阴离子苯乙烯聚合物并干燥。 干燥的聚合物具有约600ppm（wt / wt）或更低的挥发性溴苯含量以及其它有益特性。

    Brominated styrenic polymers and their preparation
    8.
    发明授权
    Brominated styrenic polymers and their preparation 有权
    溴化苯乙烯聚合物及其制备方法

    公开(公告)号：US07632893B2

    公开(公告)日：2009-12-15

    申请号：US11453542

    申请日：2006-06-14

    申请人： Charles H. Kolich ,  Jeffrey Todd Aplin ,  John F. Balhoff

    发明人： Charles H. Kolich ,  Jeffrey Todd Aplin ,  John F. Balhoff

    IPC分类号： C08F12/08

    CPC分类号： C08F8/20 ,  C08F8/22 ,  C08F12/08 ,  C08F12/16 ,  C08F12/00 ,  C08F4/48

    摘要： Preparing brominated styrenic polymer by maintaining a mixture formed from (i) brominating agent, (ii) a solvent solution of styrenic polymer, and (iii) aluminum halide catalyst, at −20 to +20° C., and terminating bromination in 20 minutes or less. New brominated anionic styrenic polymers have better melt flow and/or lower initial ΔE values than the best previously-known brominated anionic styrenic polymers. Other features of such new polymers include high thermal stabilities at 320° C. and/or very low initial color values. Brominated styrenic polymers, especially brominated anionic styrenic polymers, are useful as flame retardants for thermoplastic polymers.

    摘要翻译： 通过保持由（i）溴化剂，（ii）苯乙烯聚合物的溶剂溶液和（iii）卤化铝催化剂）在-20至+ 20℃形成的混合物，并在20分钟内终止溴化，制备溴化苯乙烯聚合物 或更少。 新的溴化阴离子苯乙烯聚合物具有比先前已知的溴代阴离子苯乙烯聚合物更好的熔体流动和/或较低的初始DeltaE值。 这种新聚合物的其它特征包括在320℃下的高热稳定性和/或非常低的初始颜色值。 溴化苯乙烯聚合物，特别是溴化阴离子苯乙烯聚合物，可用作热塑性聚合物的阻燃剂。

    Brominated Anionic Styrenic Polymers and Their Preparation
    9.
    发明申请
    Brominated Anionic Styrenic Polymers and Their Preparation 有权
    溴化阴离子苯乙烯聚合物及其制备

    公开(公告)号：US20100087620A1

    公开(公告)日：2010-04-08

    申请号：US12636250

    申请日：2009-12-11

    申请人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    发明人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    IPC分类号： C08G79/00

    CPC分类号： C08F8/20 ,  C08F8/22 ,  C08F12/00 ,  C08F12/08

    摘要： Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.

    摘要翻译： 同时加入保持在约10℃或更低的反应区域的是溴化剂，卤化铝催化剂和具有大约2000-30,000的GPC Mn的阴离子苯乙烯聚合物溶液。 这些组件至少有两个单独的进料流。 进料成比例以维持（a）以所加入的聚合物中的芳族单体单元的量为基准，以约0.8摩尔％或更少的量加入卤化铝的量，和（b）溴化剂和未溴化聚合物的量 反应区，其产生含有约60-71重量％溴的最终洗涤和干燥的聚合物产物。 催化剂失活，溴化物离子和催化剂残余物从反应混合物中洗去，回收溴化阴离子苯乙烯聚合物并干燥。 干燥的聚合物具有约600ppm（wt / wt）或更低的挥发性溴苯含量以及其它有益特性。

    Brominated Styrenic Polymers and Their Preparation
    10.
    发明申请
    Brominated Styrenic Polymers and Their Preparation 有权
    溴化苯乙烯聚合物及其制备

    公开(公告)号：US20100081762A1

    公开(公告)日：2010-04-01

    申请号：US12631333

    申请日：2009-12-04

    申请人： Charles H. Kolich ,  Jeffrey Todd Aplin ,  John F. Balhoff

    发明人： Charles H. Kolich ,  Jeffrey Todd Aplin ,  John F. Balhoff

    IPC分类号： C08L25/06 ,  C08F112/08

    CPC分类号： C08F8/20 ,  C08F8/22 ,  C08F12/08 ,  C08F12/16 ,  C08F12/00 ,  C08F4/48

    摘要： Preparing brominated styrenic polymer by maintaining a mixture formed from (i) brominating agent, (ii) a solvent solution of styrenic polymer, and (iii) aluminum halide catalyst, at −20 to +20° C., and terminating bromination in 20 minutes or less. New brominated anionic styrenic polymers have better melt flow and/or lower initial ΔE values than the best previously-known brominated anionic styrenic polymers. Other features of such new polymers include high thermal stabilities at 320° C. and/or very low initial color values. Brominated styrenic polymers, especially brominated anionic styrenic polymers, are useful as flame retardants for thermoplastic polymers.

    摘要翻译： 通过保持由（i）溴化剂，（ii）苯乙烯聚合物的溶剂溶液和（iii）卤化铝催化剂）在-20至+ 20℃形成的混合物，并在20分钟内终止溴化，制备溴化苯乙烯聚合物 或更少。 新的溴化阴离子苯乙烯聚合物具有比最先前已知的溴代阴离子苯乙烯聚合物更好的熔体流动和/或较低的初始＆Dgr; E值。 这种新聚合物的其它特征包括在320℃下的高热稳定性和/或非常低的初始颜色值。 溴化苯乙烯聚合物，特别是溴化阴离子苯乙烯聚合物，可用作热塑性聚合物的阻燃剂。