RUTHENIUM COMPLEXES WITH TRIDENTATE HETEROCYCLIC LIGAND AND DYE-SENSITIZED SOLAR CELLS USING THE SAME
    2.
    发明申请
    RUTHENIUM COMPLEXES WITH TRIDENTATE HETEROCYCLIC LIGAND AND DYE-SENSITIZED SOLAR CELLS USING THE SAME 有权
    具有三元杂环配体和染料敏感的太阳能电池的钌复合物

    公开(公告)号:US20080114174A1

    公开(公告)日:2008-05-15

    申请号:US11939559

    申请日:2007-11-14

    IPC分类号: C07D401/14

    摘要: A ruthenium complex having a chemical formula of RuL1L2X is provided. The chemical formula includes a structural formula represented by the following Formula (I): in which, X is a monodentate anion ligand, L1 and L2 respectively represent a heterocyclic tridentate ligand with a structure shown in the following structural formula (II): and a bipyridine ligand derivative with a structure shown in the following structural formula (III): in which R1, R2, R4 and R5 of L1 and L2 are the same or different substituents and represent alkyl, alkoxy, aminoalkyl, haloalkanes or substituted phenyl group, carboxylic acid group or acid radical salt thereof, sulfonic acid group or acid radical salt thereof, phosphoric acid group or acid radical salt thereof or hydrogen atom. R3 represents perhalogenated alkyl group, alkoxy, alkyl, amino, halogens, or hydrogen atom. The ruthenium complexes are suitable for being used as dye-sensitizers for fabricating dye-sensitized solar cells.

    摘要翻译: 提供化学式为RuL 1 L 2 X的钌络合物。 化学式包括由下式(I)表示的结构式:其中X是单齿阴离子配体,L 1和L 2分别表示杂环三齿 具有以下结构式(II)所示结构的配体和具有如下结构式(III)所示结构的联吡啶配体衍生物:其中R 1,R 2, ,L 1和L 2的R 4和R 5都是相同或不同的取代基和/或 代表烷基,烷氧基,氨基烷基,卤代烷基或取代的苯基,羧酸基团或其酸基盐,磺酸基或其酸基盐,磷酸基或其酸基盐或氢原子。 R 3表示全卤代烷基,烷氧基,烷基,氨基,卤素或氢原子。 钌配合物适用于染料敏化剂制造染料敏化太阳能电池。