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1.发明授权公开(公告)号：US08569546B2
公开(公告)日：2013-10-29
申请号：US13455593
申请日：2012-04-25
IPC分类号： C07C45/27
CPC分类号： C07C45/29 , B01J23/50 , B01J23/8926 , B01J35/0026 , B01J35/04 , B01J35/06 , C07C47/04
摘要： In a process for producing C1-C10 aldehydes by oxidative dehydrogenation of C1-C10 alcohols over a shaped catalyst body obtainable by three-dimensional shaping and/or arranging in space of silver-containing fibers and/or threads, the average diameter or the average diagonal length of an essentially rectangular or square cross section of these silver-containing fibers and/or threads is in the range from 30 μm to 200 μm.
摘要翻译： 在通过三维成形和/或在含银纤维和/或螺纹的空间中排列的成型催化剂体上通过C1-C10醇的氧化脱氢制备C1-C10醛的方法中，平均直径或平均值 这些含银纤维和/或线的基本上矩形或正方形横截面的对角线长度在30μm到200μm的范围内。
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2.发明申请公开(公告)号：US20120277473A1
公开(公告)日：2012-11-01
申请号：US13455593
申请日：2012-04-25
IPC分类号： C07C45/27
CPC分类号： C07C45/29 , B01J23/50 , B01J23/8926 , B01J35/0026 , B01J35/04 , B01J35/06 , C07C47/04
摘要： In a process for producing C1-C10 aldehydes by oxidative dehydrogenation of C1-C10 alcohols over a shaped catalyst body obtainable by three-dimensional shaping and/or arranging in space of silver-containing fibers and/or threads, the average diameter or the average diagonal length of an essentially rectangular or square cross section of these silver-containing fibers and/or threads is in the range from 30 μm to 200 μm.
摘要翻译： 在通过三维成形和/或在含银纤维和/或螺纹的空间中排列的成型催化剂体上通过C1-C10醇的氧化脱氢制备C1-C10醛的方法中，平均直径或平均值 这些含银纤维和/或线的基本上矩形或正方形截面的对角线长度在30μm至200μm的范围内。
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3.发明授权Precious metal catalysts with low metal loading for oxidative dehydrogenations 有权贵金属催化剂具有低的金属负载用于氧化脱氢公开(公告)号：US08680340B2
公开(公告)日：2014-03-25
申请号：US13457644
申请日：2012-04-27
CPC分类号： B01J37/349 , B01J23/40 , B01J23/48 , B01J23/50 , B01J35/0013 , B01J35/006 , B01J37/0219 , B01J37/0221 , B01J37/0223 , B82Y30/00 , C07C45/29 , C07C47/02
摘要： A method of production of a catalyst that has 0.05-0.25 wt. % of precious metal, preferably for the oxidative dehydrogenation of olefinically unsaturated alcohols, comprising the following steps a) producing a D.C. plasma, b) introducing the metal and support material into the plasma, c) evaporating the metal and support material or “shattering” the solid bodies of metal and support material in the plasma, and reaction of the particles, d) cooling, so that very small particles of composite material are obtained, e) applying the composite material on the catalyst support proper, the correspondingly produced catalyst and use thereof.
摘要翻译： 一种生产具有0.05-0.25wt。 ％的贵金属，优选用于烯属不饱和醇的氧化脱氢，包括以下步骤：a）制造DC等离子体，b）将金属和载体材料引入等离子体; c）蒸发金属和载体材料或“粉碎” 等离子体中的金属和支撑材料的固体物质和颗粒的反应，d）冷却，从而获得非常小的复合材料颗粒，e）将复合材料施加在催化剂载体上，相应产生的催化剂和 使用它。
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4.发明申请Precious metal catalysts with low metal loading for oxidative dehydrogenations 有权贵金属催化剂具有低的金属负载用于氧化脱氢公开(公告)号：US20120277476A1
公开(公告)日：2012-11-01
申请号：US13457644
申请日：2012-04-27
CPC分类号： B01J37/349 , B01J23/40 , B01J23/48 , B01J23/50 , B01J35/0013 , B01J35/006 , B01J37/0219 , B01J37/0221 , B01J37/0223 , B82Y30/00 , C07C45/29 , C07C47/02
摘要： A method of production of a catalyst that has 0.05-0.25 wt. % of precious metal, preferably for the oxidative dehydrogenation of olefinically unsaturated alcohols, comprising the following stepsa) producing a D.C. plasma, b) introducing the metal and support material into the plasma, c) evaporating the metal and support material or “shattering” the solid bodies of metal and support material in the plasma, and reaction of the particles, d) cooling, so that very small particles of composite material are obtained, e) applying the composite material on the catalyst support proper, the correspondingly produced catalyst and use thereof.
摘要翻译： 一种生产具有0.05-0.25wt。 ％的贵金属，优选用于烯属不饱和醇的氧化脱氢，包括以下步骤：a）制造DC等离子体，b）将金属和载体材料引入等离子体中，c）蒸发金属和载体材料或粉碎固体 等离子体中的金属和载体材料，以及颗粒的反应，d）冷却，从而获得非常小的复合材料颗粒，e）将复合材料施加在催化剂载体上，相应产生的催化剂及其用途 。
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公开(公告)号：US20120130071A1
公开(公告)日：2012-05-24
申请号：US13386781
申请日：2010-07-07
IPC分类号： C07F15/00 , C07C305/04
CPC分类号： B01J31/1815 , B01J2231/70 , B01J2531/0216 , B01J2531/0238 , C07C29/12 , C07C303/24 , Y02P20/52 , C07C31/04 , C07C305/04
摘要： Platinum(II) complexes and the use of these complexes for oxidation of methane to methyl sulfate are disclosed, the catalyst having, as ligands, a network based on aromatic N-heterocycles which has at least 2 coordinative nitrogen atoms per platinum atom, and the complex anion is selected from a halide, hydrogensulfate, hydrogensulfite, sulfate, sulfite, methylsulfate, methanol, water, hydroxide, carbon monoxide, hydrogencarbonate and carbonate. The catalyst enables a selective low-temperature oxidation of methane to methyl sulfate or methanol. The catalysts not only exhibit high activity, but can also be removed easily from the reaction mixture and reused over several runs without significant loss of activity.
摘要翻译： 公开了铂（II）配合物和这些配合物用于将甲烷氧化成甲基硫酸盐的用途，该催化剂具有作为配体的基于每铂原子具有至少2个配位氮原子的芳族N-杂环的网络，以及 络合阴离子选自卤化物，硫酸氢盐，亚硫酸氢盐，硫酸盐，亚硫酸盐，甲基硫酸盐，甲醇，水，氢氧化物，一氧化碳，碳酸氢盐和碳酸盐。 该催化剂使甲烷选择性低温氧化成甲硫酸盐或甲醇。 催化剂不仅表现出高活性，而且也可以容易地从反应混合物中除去并在多次运行中重复使用而没有显着的活性损失。
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