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    HIGHLY FLUORESCENT PYRROLE-BF2 CHROMOPHORES
    1.
    发明申请
    HIGHLY FLUORESCENT PYRROLE-BF2 CHROMOPHORES 审中-公开
    高荧光PYRROLE-BF2色素

    公开(公告)号：US20160272657A1

    公开(公告)日：2016-09-22

    申请号：US15034706

    申请日：2014-11-20

    申请人： Christopher J. Ziegler ,  Ingrid-Suzy Tamgho

    发明人： Christopher J. Ziegler ,  Ingrid-Suzy Tamgho

    IPC分类号： C07F5/02

    CPC分类号： C07F5/022 ,  C09B23/105 ,  C09B23/166 ,  C09B55/005 ,  C09B57/00 ,  C09K9/02 ,  C09K2211/1029 ,  C09K2211/1059 ,  C12Q1/00 ,  H01G9/2059 ,  H01L51/008

    摘要： Fluorescent chromophores nicknamed BOPHY are provided. The chromophores may be readily synthesized in two steps from readily available reagents via the coupling of a pyrrole aldehyde or ketone with hydrazine, followed by reaction with BF3. The resultant symmetric and dimeric tetracycle is comprised of two BF2 units in six-member chelate rings, appended by pyrrole units on the periphery. The quantum yield of fluorescence for the unmodified compound and the tetramethyl variant are near unity, with values 95 and 92% respectively in CH2Cl2.

    摘要翻译： 提供绰号为BOPHY的荧光发色团。 发色团可以通过吡咯醛或酮与肼的偶联，随后与BF 3反应，从容易获得的试剂两步容易地合成。 所得到的对称和二聚四环由六元螯合环中的两个BF 2单元组成，外围由吡咯单元附加。 未改性化合物和四甲基变体的荧光的量子产率接近一致，CH 2 Cl 2中分别为95和92％。

    HALF-PHTHALOCYANINE-LIKE CHELATES AND SYNTHESIS THEREOF
    4.
    发明申请
    HALF-PHTHALOCYANINE-LIKE CHELATES AND SYNTHESIS THEREOF 有权
    半卤素 - 类似的螯合物及其合成

    公开(公告)号：US20150203520A1

    公开(公告)日：2015-07-23

    申请号：US14561955

    申请日：2014-12-05

    申请人： Christopher J. Ziegler ,  Laura Crandall ,  Richard S. Herrick

    发明人： Christopher J. Ziegler ,  Laura Crandall ,  Richard S. Herrick

    IPC分类号： C07F13/00 ,  C07F5/02

    CPC分类号： C07F13/00 ,  C07F5/02 ,  C07F9/6521 ,  C07F15/06

    摘要： Half-phthalocyanine-like chelates, such as bis(iminoisoindolinyl)azomethene (BIAM), bis(oxoisoindolinyl) azomethene (BOAM), are provided, as well as chelates based thereon. Methods for synthesizing and synthetically modifying the novel chelate compounds are also provided. The half-phthalocyanine-like chelates have useful properties, particularly with regard to UV-visible absorption and emission as well as electron or energy transfer.

    摘要翻译： 提供半酞菁样螯合物，例如双（亚氨基二吲哚啉基）偶氮甲烷（BIAM），双（氧代异吲哚啉基）偶氮甲烷（BOAM），以及基于其的螯合物。 还提供了合成和合成改性新螯合物的方法。 半酞菁类螯合物具有有用的特性，特别是在紫外可见吸收和发射以及电子或能量转移方面。

    Coordination complexes, and methods for preparing by combinatorial methods, assaying and using the same
    5.
    发明授权
    Coordination complexes, and methods for preparing by combinatorial methods, assaying and using the same 失效
    配位络合物，以及通过组合方法制备方法，测定和使用它们

    公开(公告)号：US07651979B2

    公开(公告)日：2010-01-26

    申请号：US10928929

    申请日：2004-08-27

    申请人： Stephen J. Lippard ,  Christopher J. Ziegler

    发明人： Stephen J. Lippard ,  Christopher J. Ziegler

    IPC分类号： C40B40/18

    CPC分类号： C07F15/0093

    摘要： The present invention relates to novel coordination complexes, methods for synthesizing and identifying coordination complexes, using combinatorial techniques, and assaying their activity. In certain embodiments, the invention relates to a library comprising a plurality of platinum-containing coordination complexes represented by the general formula {PtLnA(4-n)}, wherein, independently for each occurrence, each L is a non-labile ligand under standard conditions, each n is equal to 1, 2 or 3; each A is a labile ligand under standard conditions; and each Pt is Pt(II) or Pt(IV); provided that when Pt is Pt(IV), two additional ligands in the trans axial positions of the general formula depicted are present; and at least one of the plurality of platinum-containing coordination complexes is represented by the formula wherein, independently for each occurrence: X represents halogen or other labile ligand under standard conditions; W represents S, N, or P; Y represents —OR7, —SR7, a halogen or —N(R9)R10; R9 and R10, each independently, represent —H, alkyl, alkenyl, —(CH2)n—R7, or R9 and R10, taken together with the N atom to which they are attached complete a heterocycle having from 4 to about 8 atoms in the ring structure, all optionally substituted; L represents a non-labile ligand under standard conditions; R7 represents —H, alkyl, aryl, cycloalkyl, cycloalkenyl, heterocycle or polycycle; the ligand V comprises W, Y, and a heterocycle having from 4 to about 8 atoms in the ring structure, optionally aromatic and optionally substituted; and the symbol represents a single or a double bond.

    摘要翻译： 本发明涉及新的配位络合物，合成和鉴定配位络合物的方法，使用组合技术和测定其活性。 在某些实施方案中，本发明涉及包含多个由通式{PtLnA（4-n）}表示的含铂配位络合物的文库，其中，对于每次出现，每个L独立地为标准下的非不稳定配体 条件，每个n等于1,2或3; 每个A在标准条件下是不稳定的配体; 并且每个Pt是Pt（II）或Pt（IV）; 条件是当Pt是Pt（IV）时，存在在所示通式的反式轴位的两个另外的配体; 并且所述多个含铂配位络合物中的至少一个由下式表示：其中独立地为每次出现：X在标准条件下代表卤素或其它不稳定配体; W表示S，N或P; Y表示-OR7，-SR7，卤素或-N（R9）R10; R 9和R 10各自独立地表示-H，烷基，链烯基， - （CH 2）n -R 7或R 9和R 10与它们所连接的N原子一起形成具有4至约8个原子的杂环， 环结构，全部可以被取代; L在标准条件下代表非不稳定配体; R 7表示-H，烷基，芳基，环烷基，环烯基，杂环或多环; 配体V包括W，Y和在环结构中具有4至约8个原子的杂环，任选是芳族和任选取代的; 符号表示单键或双键。

    Boron-based organic cations and related methods
    8.
    发明授权
    Boron-based organic cations and related methods 失效
    硼基有机阳离子及相关方法

    公开(公告)号：US07417151B2

    公开(公告)日：2008-08-26

    申请号：US11010222

    申请日：2004-12-10

    申请人： Christopher J. Ziegler

    发明人： Christopher J. Ziegler

    IPC分类号： C07D249/04 ,  C07D403/00 ,  C07D233/00 ,  C07D231/10

    CPC分类号： C07F5/022

    摘要： Generally disclosed are boron-based organic cations, a method for their manufacture, a method for their use in ionic liquids, and a method for their use as phase-transfer catalysts. More specifically, the boron-based organic cations have an charge of 1+, 2+, or 3+.

    摘要翻译： 通常公开的是硼基有机阳离子，其制备方法，其用于离子液体的方法，以及用作相转移催化剂的方法。 更具体地，硼基有机阳离子具有1 +，2+或3+的电荷。