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    Bis-2-azomethine pigments, process for their manufacture and their use
    4.
    发明授权
    Bis-2-azomethine pigments, process for their manufacture and their use 失效
    双-2-偶氮甲碱颜料，其制造及其用途

    公开(公告)号：US3939194A

    公开(公告)日：1976-02-17

    申请号：US538429

    申请日：1975-01-02

    Applicant: Francois L'Eplattenier ,  Andre Pugin ,  Laurent Vuitel

    Inventor： Francois L'Eplattenier ,  Andre Pugin ,  Laurent Vuitel

    IPC: C08K5/00 ,  C09B55/00 ,  C07C119/10 ,  C07C101/76

    CPC classification number: C08K5/0091 ,  C09B55/005

    Abstract: Bis-azomethine pigments of the formula ##SPC1##Wherein X denotes an aromatic radical on which the imino groups are in the o-position, Y denotes a hydroxyl, alkoxy, cycloalkoxy, aralkoxy or aryloxy, amino, alkylamino or arylamino group and Z denotes a H or halogen atom or an alkoxy, nitro or nitrile group, the radical X having to be free of nitro groups if Y denotes an arylamino group and Z denotes a H atom, as well as metal complexes of these bis-azomethines are useful for coloring plastics and lacquers in yellow to red shades of good fastness properties.

    Abstract translation: 式WHEREIN X的双偶氮甲碱颜料表示亚氨基在其上的芳基，Y表示羟基，烷氧基，环烷氧基，芳烷氧基或芳氧基，氨基，烷基氨基或芳基氨基，Z表示H或 卤素原子或烷氧基，硝基或腈基，如果Y表示芳基氨基且Z表示H原子，则基团X不含硝基，以及这些双偶氮甲碱的金属络合物可用于着色塑料和 漆黄色至红色，色牢度好。

    SELF-ASSEMBLED OLEFIN POLYMERIZATION CATALYST
    5.
    发明申请
    SELF-ASSEMBLED OLEFIN POLYMERIZATION CATALYST 审中-公开
    自组装烯烃聚合催化剂

    公开(公告)号：US20110124831A1

    公开(公告)日：2011-05-26

    申请号：US12812942

    申请日：2008-01-14

    Applicant: He-Kuan Luo

    Inventor： He-Kuan Luo

    IPC: C08F4/76 ,  C07F7/28 ,  C07C251/24 ,  C07F7/00 ,  B01J31/12 ,  B01J31/14

    CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F2410/03 ,  C09B11/04 ,  C09B55/005 ,  C09B55/008 ,  C08F2500/03 ,  C08F4/64048

    Abstract: The present invention relates to a self-assembled olefin polymerization catalyst comprising a transition metal compound according to formula (I) LqMmXn wherein M is a transition metal selected from the group consisting of Group 3-11 of the periodic table; X is independently selected from the group consisting of H, halogen, CN, optionally substituted N(Ra)2, OH, optionally substituted C1-C20 alkyl, optionally substituted C1-C20 alkoxy, wherein Ra is independently selected from the group consisting of optionally substituted C1-C20 alkyl, optionally substituted C6-C20 aryl and halogen; q is an integer of at least 2; m is an integer of at least 2; n is an integer making (I) electrically neutral; L is independently a ligand which has at least two linked coordination units, wherein each coordination unit binds to a different transition metal. The present invention also relates to a process for the polymerization of olefins using the transition metal compound of the invention and to the polyolefins obtained from this polymerization process. Finally, the invention also relates to new ligands L present in the transition metal compound and to methods of making the ligand L.

    Abstract translation: 本发明涉及包含式（I）的过渡金属化合物LqMmXn的自组装烯烃聚合催化剂，其中M是选自周期表第3-11组的过渡金属; X独立地选自H，卤素，CN，任选取代的N（Ra）2，OH，任选取代的C 1 -C 20烷基，任选取代的C 1 -C 20烷氧基，其中R a独立地选自任选地 取代的C 1 -C 20烷基，任选取代的C 6 -C 20芳基和卤素; q是至少为2的整数; m为至少2的整数; n是使（I）电中性的整数; L独立地是具有至少两个连接的配位单元的配体，其中每个配位单元与不同的过渡金属结合。 本发明还涉及使用本发明的过渡金属化合物和由该聚合方法获得的聚烯烃聚合烯烃的方法。 最后，本发明还涉及过渡金属化合物中存在的新配体L和制备配体L的方法。

    Process for the manufacture of bis-azomethine metal complex colorants
    6.
    发明授权
    Process for the manufacture of bis-azomethine metal complex colorants 失效
    制备双偶氮甲碱金属络合物着色剂的方法

    公开(公告)号：US4008225A

    公开(公告)日：1977-02-15

    申请号：US599444

    申请日：1975-07-28

    Applicant: Francois L'Eplattenier ,  Laurent Vuitel ,  Andre Pugin

    Inventor： Francois L'Eplattenier ,  Laurent Vuitel ,  Andre Pugin

    IPC: C09B55/00 ,  C07F3/06 ,  C07F3/08 ,  C07F15/00

    CPC classification number: C09B55/005

    Abstract: Process for the manufacture of bis-azomethine metal complex colorants of the formula ##STR1## wherein A denotes an isocyclic or heterocyclic aromatic radical, X denotes an isocyclic or heterocyclic aromatic radical to which the N-atoms are bonded in the o-position or peri-position, or an alkylene radical containing 2-8 C atoms, and M denotes a divalent transition metal ion, a zinc ion or cadmium ion, characterized in that an o-hydroxyaldimine compound of the formula ##STR2## wherein A has the abovementioned meaning and R denotes an alkyl, cycloalkyl or aryl radical, is reacted with a diamine of the formulaNH.sub.2 --X--NH.sub.2wherein X has the abovementioned meaning, in the molar ratio of 2:1, in the presence of a compound which donates a divalent transition metal cation, zinc ion or cadmium ion.

    Abstract translation: 制备下式的双偶氮甲碱金属络合物着色剂的方法其中A表示环状或杂环的芳族基团，X表示在O-位或邻位上键合有N-原子的环状或杂环的芳族基团 - 位或含有2-8个C原子的亚烷基，M表示二价过渡金属离子，锌离子或镉离子，其特征在于其中A具有上述含义的邻羟基二亚胺化合物 和R表示烷基，环烷基或芳基，与式NH2-X-NH2的二胺反应，其中X具有上述含义，摩尔比为2:1，在提供二价 过渡金属阳离子，锌离子或镉离子。

    HIGHLY FLUORESCENT PYRROLE-BF2 CHROMOPHORES
    9.
    发明申请
    HIGHLY FLUORESCENT PYRROLE-BF2 CHROMOPHORES 审中-公开
    高荧光PYRROLE-BF2色素

    公开(公告)号：US20160272657A1

    公开(公告)日：2016-09-22

    申请号：US15034706

    申请日：2014-11-20

    Applicant: Christopher J. Ziegler ,  Ingrid-Suzy Tamgho

    Inventor： Christopher J. Ziegler ,  Ingrid-Suzy Tamgho

    IPC: C07F5/02

    CPC classification number: C07F5/022 ,  C09B23/105 ,  C09B23/166 ,  C09B55/005 ,  C09B57/00 ,  C09K9/02 ,  C09K2211/1029 ,  C09K2211/1059 ,  C12Q1/00 ,  H01G9/2059 ,  H01L51/008

    Abstract: Fluorescent chromophores nicknamed BOPHY are provided. The chromophores may be readily synthesized in two steps from readily available reagents via the coupling of a pyrrole aldehyde or ketone with hydrazine, followed by reaction with BF3. The resultant symmetric and dimeric tetracycle is comprised of two BF2 units in six-member chelate rings, appended by pyrrole units on the periphery. The quantum yield of fluorescence for the unmodified compound and the tetramethyl variant are near unity, with values 95 and 92% respectively in CH2Cl2.

    Abstract translation: 提供绰号为BOPHY的荧光发色团。 发色团可以通过吡咯醛或酮与肼的偶联，随后与BF 3反应，从容易获得的试剂两步容易地合成。 所得到的对称和二聚四环由六元螯合环中的两个BF 2单元组成，外围由吡咯单元附加。 未改性化合物和四甲基变体的荧光的量子产率接近一致，CH 2 Cl 2中分别为95和92％。

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