METHODS FOR SYNTHESIZING METAL-CARBON COMPOSITE OF A CORE-SHELL STRUCTURE

    公开(公告)号:US20230064413A1

    公开(公告)日:2023-03-02

    申请号:US17409830

    申请日:2021-08-24

    IPC分类号: C01B32/15 C03C17/38

    摘要: The present invention provides a metal-carbon composite of a core-shell structure and a method of synthesizing the same. The method includes preparing a first polymer-covered glass substrate with a nano-thickness metal film deposited thereon; immersing the first polymer-covered glass substrate with the metal film to delaminate one or more 2D freestanding organic-metal nanosheets from the first polymer-covered glass substrate; transferring the one or more 2D freestanding organic-metal nanosheets onto a second target substrate; and annealing the one or more 2D freestanding organic-metal nanosheets to decompose an organic portion of the organic-metal nanosheet into an amorphous carbon-containing shell forming a metal-carbon nanocomposite of a core-shell structure.

    ETCH-FREE ULTRAFAST FABRICATION OF SELF-ROLLED METALLIC NANOSHEETS WITH CONTROLLABLE TWISTING

    公开(公告)号:US20230063446A1

    公开(公告)日:2023-03-02

    申请号:US17462106

    申请日:2021-08-31

    摘要: The present invention provides a method of forming a self-rolled metallic nanosheet. The method includes providing a bendable polymeric substrate and forming a hydrogel-based separation layer on the bendable polymeric substrate. A thin-film metallic nanosheet is deposited on the hydrogel-based separation layer, the thin-film metallic nanosheet having a thickness of approximately 150 nm or less to form a nanosheet-hydrogel-polymer composite. Channel cracks are induced in the nanosheet-hydrogel-polymer composite. The hydrogel layer is swelled to delaminate the metallic nanosheet employing the induced channel cracks to form one or more nano-morphology structures selected from scroll morphology, ribbon morphology, spiral morphology, or helix morphology.