公开(公告)号：US20040176656A1

公开(公告)日：2004-09-09

申请号：US10806882

申请日：2004-03-23

Applicant: ConocoPhillips Company

Inventor： Joe D. Allison ,  Sriram Ramani ,  Zhen Chen ,  Lisa M. Carmichael ,  Shang Y. Chen ,  Steve R. McDonald ,  Anne Gaffney

IPC: C07C005/327 ,  C07C005/373

CPC classification number: C07C5/48 ,  B01J23/10 ,  B01J23/63 ,  C07C2523/10 ,  C07C2523/56 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/04

Abstract: Catalysts and methods useful for the production of olefins from alkanes via oxidative dehydrogenation (ODH) are disclosed. The ODH catalysts include a base metal selected from the group consisting of lanthanide metals, their oxides, and combinations thereof. The base metal is more preferably selected from the group consisting of samarium, cerium, praseodymium, terbium, their corresponding oxides and combinations thereof. The base metal loading is preferably between about 0.5 and about 20 weight percent and more preferably between about 2 and about 10 weight percent. Optionally, the ODH catalysts are further comprised of a Group VIII promoter metal present at trace levels. The Group VIII promoter metal is preferably platinum, palladium or a combination thereof and is preferably present at a promoter metal loading of between about 0.005 and about 0.1 weight percent. Optionally, the ODH catalyst is supported on a refractory support.

Abstract translation: 公开了可用于通过氧化脱氢（ODH）从烷烃生产烯烃的催化剂和方法。 ODH催化剂包括选自镧系金属，其氧化物及其组合的贱金属。 贱金属更优选选自钐，铈，镨，铽，它们相应的氧化物及其组合。 贱金属负载量优选为约0.5至约20重量％，更优选约2至约10重量％。 任选地，ODH催化剂还包含痕量存在的VIII族助催化剂金属。 VIII族助催化剂金属优选为铂，钯或其组合，优选以约0.005至约0.1重量％的助催化剂金属负载存在。 任选地，ODH催化剂负载在耐火载体上。

公开(公告)号：US20040158112A1

公开(公告)日：2004-08-12

申请号：US10364177

申请日：2003-02-10

Applicant: ConocoPhillips Company

Inventor： Sriram Ramani ,  Joe D. Allison ,  Lisa M. Carmichael ,  Zhen Chen

IPC: C07C005/373 ,  C07C005/327 ,  B01J027/224

CPC classification number: B01J27/224 ,  B01J23/626 ,  B01J35/04 ,  C07C5/48 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/46 ,  C07C2523/62 ,  C07C2523/64 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/02

Abstract: A catalyst useful for the production of olefins from alkanes via oxidative dehydrogenation (ODH) is disclosed. The catalyst includes a silicon carbide support. The catalyst may optionally include a base metal, metal oxide, or combination thereof. A base metal is herein defined as a non-Group VIII metal, with the exception of iron, cobalt and nickel. Suitable base metals include Group IB-VIIB metals, Group IIIA-VA metals, Lanthanide metals, iron, cobalt and nickel. Suitable metal oxides include alumina, stabilized aluminas, zirconia, stabilized zirconias (PSZ), titania, ytteria, silica, niobia, and vanadia. Additionally, the catalyst may optionally include a Group VIII promoter. Suitable Group VIII promoters include Ru, Rh, Pd, Os, Ir, and Pt.

Abstract translation: 公开了一种可用于通过氧化脱氢（ODH）从烷烃生产烯烃的催化剂。 催化剂包括碳化硅载体。 催化剂可任选地包括贱金属，金属氧化物或其组合。 本文将贱金属定义为非Ⅷ族金属，铁，钴和镍除外。 合适的贱金属包括IB-VIIB族金属，IIIA-VA族金属，镧系金属，铁，钴和镍。 合适的金属氧化物包括氧化铝，稳定化的氧化铝，氧化锆，稳定的氧化锆（PSZ），二氧化钛，氧化钇，二氧化硅，氧化铌和氧化钒。 另外，催化剂可任选地包括VIII族促进剂。 合适的VIII族促进剂包括Ru，Rh，Pd，Os，Ir和Pt。