摘要:
A process for hydroformylating short-chain olefins, especially C2 to C5 olefins can be performed in at least one reactor in which the catalyst system is in heterogenized form on a support. The support is composed of a porous ceramic material, and the process steps a) to c) are conducted when the process is shut down.
摘要:
A porous material includes aggregate particles and a binding material. In the aggregate particles, oxide films containing cristobalite are provided on surfaces of particle bodies that are silicon carbide particles or silicon nitride particles. The binding material binds the aggregate particles together in a state where pores are provided therein. The porous material contains at least one of copper, calcium, and nickel as an ancillary component.
摘要:
A plugged honeycomb structure including: a pillar-shaped honeycomb structure body having porous partition walls made of a material including silicon carbide, and plugging portions, wherein a porosity of the partition walls is from 42 to 52%, a thickness of the partition walls is from 0.15 to 0.36 mm, a ratio of a volume of pores having pore diameters of 10 μm or less to a total pore volume of the partition walls is 41% or less, a ratio of a volume of pores having pore diameters in a range of 18 to 36 μm to the total pore volume is 10% or less, the pore diameter indicating a maximum value of the log differential pore volume is in a range of 10 to 16 μm, and a half-value width of a peak including the maximum value of the log differential pore volume is 5 μm or less.
摘要:
A method for producing polyHIPE porous monoliths, of the polyHIPE type or in the form of a rigid foam, by hardening solutions of condensed tannins in the presence of oil and/or air or in the presence of a non-water-miscible volatile solvent and/or air. Also disclosed is the use of these materials in the areas of catalysis, chromatography, heat and sound insulation, tissue engineering and medication release and as a floral foam.
摘要:
A novel method for catalytic dehydration of glycerol to acrolein is provided. A fixed bed reactor is used, which is placed in a microwave unit. The feedstock is introduced into the fixed bed reactor after being preheated and gasified. Continuous glycerol dehydration occurs in the presence of a microwave-absorbing catalyst in the fixed bed reactor to form acrolein. The microwave-absorbing catalyst is composed of an active component loaded on a core-shell structure which consists of microwave absorbent coated by an oxide. The uniformity of microwave heating can reduce the formation of hot spot during the reaction and hence improve the catalyst stability. The process and operation is simple, and the unit can steadily run for a long time.
摘要:
Catalytic cores for a wall-flow filter include juxtaposed channels extending longitudinally between an inlet side and an outlet side of the core, wherein the inlet channels are plugged at the outlet side and outlet channels are plugged at the inlet side. Longitudinal walls forming the inlet and outlet channels separate the inlet channels from the outlet channels. The walls include pores that create passages extending across a width of the walls from the inlet channels to the outlet channels. Catalysts are distributed across the width and length of the walls within internal surfaces of the pores in a manner such that the loading of each catalyst across the width varies by less than 50% from an average loading across the width.
摘要:
This invention relates to a method of preparing a mixed manganese ferrite coated catalyst, and a method of preparing 1,3-butadiene using the same, and more particularly, to a method of preparing a catalyst by coating a support with mixed manganese ferrite obtained by co-precipitation at 10˜40° C. using a binder and to a method of preparing 1,3-butadiene using oxidative dehydrogenation of a crude C4 mixture containing n-butene and n-butane in the presence of the prepared catalyst. This mixed manganese ferrite coated catalyst has a simple synthetic process, and facilitates control of the generation of heat upon oxidative dehydrogenation and is very highly active in the dehydrogenation of n-butene.
摘要:
A catalytic converter has a catalyst support that is heated due to supply of electricity, and a pair of electrodes that are disposed so as to contact an outer periphery of the catalyst support as seen in an orthogonal cross-section that is orthogonal to a direction in which exhaust flows. By making a volume resistivity of the electrodes be higher than that of electricity supplying portions of external cables that are connected to the electrodes respectively and are for supplying current to the electrodes, heat generated at the electrodes is provided to the catalyst support, and a generated heat amount of the catalyst support in vicinities of the electrodes is made to be large as compared with a generated heat amount at an inner portion of the catalyst support.
摘要:
A reducing agent injection device includes a honeycomb structure having a honeycomb structure body and a pair of electrode members arranged in a side surface of the honeycomb structure body and a urea spraying device spraying a urea water solution in mist form. The urea water solution sprayed from the urea spraying device is supplied inside cells from a first end face of the honeycomb structure body, and urea in the urea water solution supplied in the cells is heated and hydrolyzed inside the electrically heated honeycomb structure body to generate ammonia. The ammonia is discharged outside the honeycomb structure body from a second end face and injected outside. There is provided a reducing agent injection device that can generate and inject ammonia from a urea solution with less energy.
摘要:
Catalysts supports and catalysts capable of being used in heterogeneous catalysis. The catalyst support belongs to the porous supports based on silicon carbide (SiC), in particular, based on β-SiC, modified by a surface deposit of TiO2.