公开(公告)号：US20040158112A1

公开(公告)日：2004-08-12

申请号：US10364177

申请日：2003-02-10

Applicant: ConocoPhillips Company

Inventor： Sriram Ramani ,  Joe D. Allison ,  Lisa M. Carmichael ,  Zhen Chen

IPC: C07C005/373 ,  C07C005/327 ,  B01J027/224

CPC classification number: B01J27/224 ,  B01J23/626 ,  B01J35/04 ,  C07C5/48 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/46 ,  C07C2523/62 ,  C07C2523/64 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/02

Abstract: A catalyst useful for the production of olefins from alkanes via oxidative dehydrogenation (ODH) is disclosed. The catalyst includes a silicon carbide support. The catalyst may optionally include a base metal, metal oxide, or combination thereof. A base metal is herein defined as a non-Group VIII metal, with the exception of iron, cobalt and nickel. Suitable base metals include Group IB-VIIB metals, Group IIIA-VA metals, Lanthanide metals, iron, cobalt and nickel. Suitable metal oxides include alumina, stabilized aluminas, zirconia, stabilized zirconias (PSZ), titania, ytteria, silica, niobia, and vanadia. Additionally, the catalyst may optionally include a Group VIII promoter. Suitable Group VIII promoters include Ru, Rh, Pd, Os, Ir, and Pt.

Abstract translation: 公开了一种可用于通过氧化脱氢（ODH）从烷烃生产烯烃的催化剂。 催化剂包括碳化硅载体。 催化剂可任选地包括贱金属，金属氧化物或其组合。 本文将贱金属定义为非Ⅷ族金属，铁，钴和镍除外。 合适的贱金属包括IB-VIIB族金属，IIIA-VA族金属，镧系金属，铁，钴和镍。 合适的金属氧化物包括氧化铝，稳定化的氧化铝，氧化锆，稳定的氧化锆（PSZ），二氧化钛，氧化钇，二氧化硅，氧化铌和氧化钒。 另外，催化剂可任选地包括VIII族促进剂。 合适的VIII族促进剂包括Ru，Rh，Pd，Os，Ir和Pt。

公开(公告)号：US20040140245A1

公开(公告)日：2004-07-22

申请号：US10346427

申请日：2003-01-17

Applicant: ConocoPhillips Company

Inventor： Sriram Ramani ,  Alfred E. Keller ,  Joe D. Allison ,  Zhen Chen

IPC: C07C005/32

CPC classification number: C07C5/48 ,  B01J23/56 ,  B01J37/20 ,  C10G2400/20

Abstract: A process and catalyst are disclosed for reducing coking in hydrocarbon processing reactions. The preferred embodiments employ a sulfur-containing material such as hydrogen sulfide to reduce catalyst susceptibility to deactivation from carbon deposits formed during processing.

Abstract translation: 公开了一种用于在烃处理反应中减少焦化的方法和催化剂。 优选的实施方案使用含硫材料如硫化氢以降低催化剂对在加工期间形成的碳沉积物失活的敏感性。

公开(公告)号：US20040176656A1

公开(公告)日：2004-09-09

申请号：US10806882

申请日：2004-03-23

Applicant: ConocoPhillips Company

Inventor： Joe D. Allison ,  Sriram Ramani ,  Zhen Chen ,  Lisa M. Carmichael ,  Shang Y. Chen ,  Steve R. McDonald ,  Anne Gaffney

IPC: C07C005/327 ,  C07C005/373

CPC classification number: C07C5/48 ,  B01J23/10 ,  B01J23/63 ,  C07C2523/10 ,  C07C2523/56 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/04

Abstract: Catalysts and methods useful for the production of olefins from alkanes via oxidative dehydrogenation (ODH) are disclosed. The ODH catalysts include a base metal selected from the group consisting of lanthanide metals, their oxides, and combinations thereof. The base metal is more preferably selected from the group consisting of samarium, cerium, praseodymium, terbium, their corresponding oxides and combinations thereof. The base metal loading is preferably between about 0.5 and about 20 weight percent and more preferably between about 2 and about 10 weight percent. Optionally, the ODH catalysts are further comprised of a Group VIII promoter metal present at trace levels. The Group VIII promoter metal is preferably platinum, palladium or a combination thereof and is preferably present at a promoter metal loading of between about 0.005 and about 0.1 weight percent. Optionally, the ODH catalyst is supported on a refractory support.

Abstract translation: 公开了可用于通过氧化脱氢（ODH）从烷烃生产烯烃的催化剂和方法。 ODH催化剂包括选自镧系金属，其氧化物及其组合的贱金属。 贱金属更优选选自钐，铈，镨，铽，它们相应的氧化物及其组合。 贱金属负载量优选为约0.5至约20重量％，更优选约2至约10重量％。 任选地，ODH催化剂还包含痕量存在的VIII族助催化剂金属。 VIII族助催化剂金属优选为铂，钯或其组合，优选以约0.005至约0.1重量％的助催化剂金属负载存在。 任选地，ODH催化剂负载在耐火载体上。

公开(公告)号：US20040202607A1

公开(公告)日：2004-10-14

申请号：US10828598

申请日：2004-04-21

Applicant: ConocoPhillips Company

Inventor： Zhen Chen ,  Kevin L. Ricketson ,  Baili Hu ,  Harold A. Wright ,  Joe D. Allison

IPC: C01B003/26

CPC classification number: C22B3/10 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/1064 ,  C01B2203/1082 ,  C22B11/026 ,  C22B11/048 ,  Y02P10/214 ,  Y02P10/234

Abstract: A method for the recovery of rhodium from spent supported catalysts. In one embodiment, a method for recovering rhodium from a host material includes roasting the host material in air at a temperature sufficient to convert at least a portion of rhodium to Rh2O3, leaching the host material in a solution with a leaching constituent which is reactive with Rh2O3 to form a first intermediate species, reacting the first intermediate species in a solution with an acidifying constituent or complexing agent to form a second intermediate species, and purifying the second intermediate species. Preferably, the roasting temperature is approximately from 600null C. to 800null C. for 0.5 to 10 hours. In some embodiments, the host material is ground to particles in the range of 0.1 to 10 mm.

公开(公告)号：US20040171900A1

公开(公告)日：2004-09-02

申请号：US10377356

申请日：2003-02-28

Applicant: ConocoPhillips Company

Inventor： Daxiang Wang ,  Chad Ricketson ,  Gloria I. Straguzzi ,  Harold A. Wright ,  Larry D. Swinney ,  Joe D. Allison ,  Zhen Chen ,  Kevin L. Ricketson ,  Shang Y. Chen ,  Steven R. McDonald

IPC: C07C005/32 ,  C07C002/00 ,  B01J008/02

CPC classification number: C10G2/32 ,  B01J8/0438 ,  B01J8/048 ,  B01J23/63 ,  B01J35/0006 ,  B01J2208/00176 ,  B01J2208/00309 ,  B01J2208/00415 ,  B01J2208/00716 ,  C01B3/386 ,  C01B2203/00 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1604 ,  C10G2/331 ,  C10G2300/4031 ,  Y02P20/52

Abstract: The present invention includes methods and apparatus for start-up a chemical reactor wherein at least a portion of the igniter is downstream from the reaction zone which needs to be ignited. Particularly, embodiments of the present invention include a partial oxidation reactor with an igniter downstream of the partial oxidation zone.

Abstract translation: 本发明包括用于启动化学反应器的方法和装置，其中至少一部分点火器位于需要点燃的反应区的下游。 特别地，本发明的实施方案包括在部分氧化区下游具有点火器的部分氧化反应器。