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公开(公告)号：US06680414B2
公开(公告)日：2004-01-20
申请号：US10014517
申请日：2001-12-14
申请人： Cord Knoop , Bernhard Scholz , Alfred Kaizik , Dietmar Gubisch , Joachim Schuler , Walter Tötsch , Wilfried Büschken
发明人： Cord Knoop , Bernhard Scholz , Alfred Kaizik , Dietmar Gubisch , Joachim Schuler , Walter Tötsch , Wilfried Büschken
IPC分类号： C07C2700
CPC分类号： C07C29/141 , C07C31/125
摘要： The present invention provides a process, which includes: in a homogeneous liquid phase including water, and over a fixed-bed catalyst, continuously hydrogenating at least one hydroformylation product obtained from a hydroformylation of one or more C4-16 olefins to produce at least one output mixture; wherein the fixed-bed catalyst includes at least one element of transition group eight of the Periodic Table of the Elements; wherein the output mixture includes at least one corresponding alcohol and from 0.05 to 10% by weight of water; and wherein in a steady-state operation of the process, from 3 to 50% more hydrogen is fed to the hydrogenation than is consumed by the hydrogenation.
摘要翻译： 本发明提供了一种方法，其包括：在均匀的液相中包括水，并且在固定床催化剂上，连续氢化由一种或多种C 4-6-16烯烃的加氢甲酰化得到的至少一种加氢甲酰化产物，以产生至少一种 输出混合物;其中固定床催化剂包括元素周期表第八族中至少一种元素;其中所述输出混合物包括至少一种相应的醇和0.05至10重量％的水;并且其中在 该方法的稳态操作，比氢化消耗更多的氢被加入到氢化中3至50％。
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公开(公告)号：US6015928A
公开(公告)日：2000-01-18
申请号：US991005
申请日：1997-12-15
IPC分类号： B01J23/75 , C07B61/00 , C07C29/141 , C07C29/16 , C07C31/125 , C07C45/50 , C07C47/02 , C08K5/10 , C07C27/22
CPC分类号： C07C29/141 , C07C29/16 , C07C45/50
摘要： A single-stage process is described that includes simultaneously, in a mixture containing an olefin; synthesis gas; a cobalt catalyst in an organic phase; and an aqueous cobalt salt solution; hydroformylating the olefin, and forming and extracting into the organic phase the cobalt catalyst from the aqueous cobalt salt solution. An apparatus is also described that includes a means for carrying out the process. The process is particularly suitable for preparing aldehydes and alcohols.
摘要翻译： 描述了在含有烯烃的混合物中同时进行的单阶段方法; 合成气; 有机相中的钴催化剂; 和钴盐水溶液; 对烯烃进行加氢甲酰化，并从钴盐水溶液中形成和提取钴催化剂到有机相中。 还描述了一种包括用于执行该过程的装置的装置。 该方法特别适用于制备醛和醇。
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公开(公告)号：US08022244B2
公开(公告)日：2011-09-20
申请号：US12140316
申请日：2008-06-17
IPC分类号： C07C69/78
摘要： A process for preparing benzoic esters whose alkoxy groups have from 7 to 13 carbon atoms by reacting benzoic acid with at least one alcohol having from 7 to 13 carbon atoms, the water of reaction formed being removed during the esterification reaction by distillation, and the alcohol not converted in the esterification reaction being removed after the esterification reaction, in which the reaction takes place in the presence of a tin(II) compound as catalyst and, without treatment with a base, the catalyst and/or its derivatives is/are separated off by filtering or by centrifuging from the reaction mixture which remains after the unconverted alcohol has been separated off.
摘要翻译： 通过使苯甲酸与至少一种具有7至13个碳原子的醇反应制备烷氧基具有7至13个碳原子的苯甲酸酯的方法，在酯化反应期间通过蒸馏除去形成的反应水，和醇 在酯化反应后不转化的酯化反应被转化，其中反应在锡（II）化合物作为催化剂的存在下进行，并且不用碱处理，催化剂和/或其衍生物被分离 通过过滤或通过从未转化的醇已经分离后残留的反应混合物离心而离心。
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公开(公告)号：US20080245996A1
公开(公告)日：2008-10-09
申请号：US12140316
申请日：2008-06-17
IPC分类号： C09K3/00
摘要： A process for preparing benzoic esters whose alkoxy groups have from 7 to 13 carbon atoms by reacting benzoic acid with at least one alcohol having from 7 to 13 carbon atoms, the water of reaction formed being removed during the esterification reaction by distillation, and the alcohol not converted in the esterification reaction being removed after the esterification reaction, in which the reaction takes place in the presence of a tin(II) compound as catalyst and, without treatment with a base, the catalyst and/or its derivatives is/are separated off by filtering or by centrifuging from the reaction mixture which remains after the unconverted alcohol has been separated off.
摘要翻译： 通过使苯甲酸与至少一种具有7至13个碳原子的醇反应制备烷氧基具有7至13个碳原子的苯甲酸酯的方法，在酯化反应期间通过蒸馏除去形成的反应水，和醇 在酯化反应后不转化的酯化反应被转化，其中反应在锡（II）化合物作为催化剂的存在下进行，并且不用碱处理，催化剂和/或其衍生物被分离 通过过滤或通过从未转化的醇已经分离后残留的反应混合物离心而离心。
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5.发明授权Process for the preparation of 2-ethylhexanol by liquid-phase catalytic hydrogenation of 2-ethylhexenal, and catalyst 失效通过2-乙基己烯醛和催化剂的液相催化氢化制备2-乙基己醇的方法
公开(公告)号：US4968849A
公开(公告)日：1990-11-06
申请号：US279078
申请日：1988-12-02
IPC分类号： B01J23/86 , C07B61/00 , C07C27/00 , C07C29/141 , C07C29/17 , C07C31/125 , C07C67/00
CPC分类号： B01J23/866 , B01J23/86 , C07C29/175 , B01J21/08
摘要： A process for preparing 2-ethylhexanol by the liquid-phase catalytic hydrogenation of 2-ethylhexenal and a catalyst for preforming this catalytic hydrogenation are disclosed.
摘要翻译： 公开了通过2-乙基己烯醛的液相催化氢化制备2-乙基己醇的方法和用于预先形成该催化氢化的催化剂。
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公开(公告)号：US06916950B2
公开(公告)日：2005-07-12
申请号：US09945736
申请日：2001-09-05
申请人： Dietmar Gubisch , Uwe Ernst , Wilfried Bueschken
发明人： Dietmar Gubisch , Uwe Ernst , Wilfried Bueschken
IPC分类号： C07B61/00 , C07C67/08 , C07C67/54 , C07C69/80 , C07C67/36 , C07C67/00 , C07C67/12 , C07C69/52
摘要： Carboxylic esters are prepared by a process, which comprises reacting dicarboxylic or polycarboxylic acids or their anhydrides with alcohols in a liquid medium with the concomitant removal of water formed by the esterification reaction by azeotropic distillation together with the alcohol in the medium, wherein the amount of liquid removed from the reaction medium by azeotropic distillation is replaced in whole or in part with the alcohol.
摘要翻译： 羧酸酯通过一种方法制备，该方法包括在液体介质中使二羧酸或多元羧酸或其酸酐与醇反应，同时通过与介质中的醇共沸蒸馏与酯化反应形成的水一起除去，其中， 通过共沸蒸馏从反应介质中除去的液体全部或部分地被醇代替。
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公开(公告)号：US20070060768A1
公开(公告)日：2007-03-15
申请号：US10575100
申请日：2004-08-20
IPC分类号： C07C69/76
摘要： A process for preparing benzoic esters whose alkoxy groups have from 7 to 13 carbon atoms by reacting benzoic acid with at least one alcohol having from 7 to 13 carbon atoms, the water of reaction formed being removed during the esterification reaction by distillation, and the alcohol not converted in the esterification reaction being removed after the esterification reaction, in which the reaction takes place in the presence of a tin(II) compound as catalyst and, without treatment with a base, the catalyst and/or its derivatives is/are separated off by filtering or by centrifuging from the reaction mixture which remains after the unconverted alcohol has been separated off.
摘要翻译： 通过使苯甲酸与至少一种具有7至13个碳原子的醇反应制备烷氧基具有7至13个碳原子的苯甲酸酯的方法，在酯化反应期间通过蒸馏除去形成的反应水，和醇 在酯化反应后不转化的酯化反应被转化，其中反应在锡（II）化合物作为催化剂的存在下进行，并且不用碱处理，催化剂和/或其衍生物被分离 通过过滤或通过从未转化的醇已经分离后残留的反应混合物离心而离心。
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公开(公告)号：US06184424B2
公开(公告)日：2001-02-06
申请号：US09396367
申请日：1999-09-15
IPC分类号： C07C2916
CPC分类号： C07C31/125 , C07C29/141 , C07C29/16
摘要： A process for the hydrogenation of reaction mixtures from the hydroformylation of C5 to C24 olefins using hydrogen on fixed catalysts at elevated temperature, in which the aldehydes, alcohols, formates and low-boilers are evaporated from the reaction mixture and passed in the vapor state over a support-free Cu/Cr catalyst.
摘要翻译： 使用氢气在固定催化剂上升高的温度下从C5加氢甲酰化C5至C24烯烃的反应混合物的氢化方法，其中醛，醇，甲酸酯和低沸点物从反应混合物中蒸发并在蒸汽状态下通过 无支撑的Cu / Cr催化剂。
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