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1.发明授权Method for hydroformylating olefins in the presence of organophosphoric compounds 失效在有机磷化合物存在下加氢甲酰化烯烃的方法公开(公告)号：US07495133B2
公开(公告)日：2009-02-24
申请号：US10593330
申请日：2005-01-27
申请人： Cornelia Borgmann , Detlef Selent , Armin Boerner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moeller , Dieter Hess
发明人： Cornelia Borgmann , Detlef Selent , Armin Boerner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moeller , Dieter Hess
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , C07F9/6578 , C07F9/65846 , C07F9/65848 , C07C47/02
摘要： (EN) The invention relates to the use of novel organophosphoric compounds and metal complexes thereof in catalytic reactions, and to the hydroformylation of olefins in the presence of these compounds.
摘要翻译： （EN）本发明涉及新型有机磷化合物及其金属络合物在催化反应中的应用，以及在这些化合物存在下烯烃加氢甲酰化的用途。
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2.发明申请Method for Hydroformylating Olefins in the Presence of Organophosphoric Compounds 失效在有机磷化合物存在下加氢甲酰化烯烃的方法公开(公告)号：US20070282130A1
公开(公告)日：2007-12-06
申请号：US10593330
申请日：2005-01-27
申请人： Cornelia Borgmann , Detlef Selent , Armin Borner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moller , Dieter Hess
发明人： Cornelia Borgmann , Detlef Selent , Armin Borner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moller , Dieter Hess
CPC分类号： C07C45/50 , C07F9/6578 , C07F9/65846 , C07F9/65848 , C07C47/02
摘要： (EN) The invention relates to the use of novel organophosphoric compounds and metal complexes thereof in catalytic reactions, and to the hydroformylation of olefins in the presence of these compounds.
摘要翻译： （EN）本发明涉及新型有机磷化合物及其金属络合物在催化反应中的应用，以及在这些化合物存在下烯烃的加氢甲酰基化。
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公开(公告)号：US08226829B2
公开(公告)日：2012-07-24
申请号：US12088041
申请日：2006-09-08
申请人： Klaus-Diether Wiese , Goetz Baumgarten , Franz-Felix Kuppinger , Oliver Moeller , Dagmara Ortmann , Cornelia Borgmann , Wilfried Bueschken
发明人： Klaus-Diether Wiese , Goetz Baumgarten , Franz-Felix Kuppinger , Oliver Moeller , Dagmara Ortmann , Cornelia Borgmann , Wilfried Bueschken
CPC分类号： B01D61/027 , B01D53/22 , B01D2311/2653 , B01D2313/143 , B01D2325/30 , B01D2325/38 , B01J31/1845 , B01J2231/321 , B01J2531/822 , Y02P20/582
摘要： Process for separating a dissolved complex catalyst of a metal of group 4, 5, 6, 7, 8, 9 or 10 of the Periodic Table of the Elements and/or any free organophosphorus ligand present from a nonaqueous hydroformylation reaction mixture which contains an aldehyde product and an organic solvent at least one membrane which is more permeable to the hydroformylation product than to the organophosphorus ligand, the separation being carried out under a carbon monoxide partial vapor pressure of more than 200 kPa.
摘要翻译： 分离元素周期表第4,5,6,7,8,9或10族金属的溶解络合物催化剂的方法和/或从含有醛的非水加氢甲酰化反应混合物中存在的任何游离有机磷配体 产物和有机溶剂至少一种对加氢甲酰化产物比对有机磷配体更可渗透的膜，该分离是在大于200kPa的一氧化碳部分蒸气压下进行的。
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公开(公告)号：US20080251456A1
公开(公告)日：2008-10-16
申请号：US12088041
申请日：2006-09-08
申请人： Klaus-Diether Wiese , Gotz Baumgarten , Franz-Felix Kuppinger , Oliver Moeller , Dagmara Ortmann , Cornelia Borgmann , Wilfried Buschken
发明人： Klaus-Diether Wiese , Gotz Baumgarten , Franz-Felix Kuppinger , Oliver Moeller , Dagmara Ortmann , Cornelia Borgmann , Wilfried Buschken
CPC分类号： B01D61/027 , B01D53/22 , B01D2311/2653 , B01D2313/143 , B01D2325/30 , B01D2325/38 , B01J31/1845 , B01J2231/321 , B01J2531/822 , Y02P20/582
摘要： Process for separating a dissolved complex catalyst of a metal of group 4, 5, 6, 7, 8, 9 or 10 of the Periodic Table of the Elements and/or any free organophosphorus ligand present from a nonaqueous hydroformylation reaction mixture which contains an aldehyde product and an organic solvent at least one membrane which is more permeable to the hydroformylation product than to the organophosphorus ligand, the separation being carried out under a carbon monoxide partial vapor pressure of more than 200 kPa.
摘要翻译： 分离元素周期表第4,5,6,7,8,9或10族金属的溶解络合物催化剂的方法和/或从含有醛的非水加氢甲酰化反应混合物中存在的任何游离有机磷配体 产物和有机溶剂至少一种对加氢甲酰化产物比对有机磷配体更可渗透的膜，该分离是在大于200kPa的一氧化碳部分蒸气压下进行的。
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公开(公告)号：US07495134B2
公开(公告)日：2009-02-24
申请号：US12065091
申请日：2006-06-02
申请人： Dieter Hess , Dagmara Ortmann , Oliver Moeller , Klaus-Diether Wiese , Dirk Fridag , Wilfried Bueschken
发明人： Dieter Hess , Dagmara Ortmann , Oliver Moeller , Klaus-Diether Wiese , Dirk Fridag , Wilfried Bueschken
CPC分类号： C07C45/50 , B01J31/0237 , B01J31/0247 , B01J31/24 , B01J2231/321 , C07F9/65744 , C07C47/02
摘要： The invention relates to a process for reaction of a carbonylatable compound using a metal complex catalyst comprising a metal of transition group VIII and an organophosphorus ligand and in the presence of a stabilizer based on a sterically hindered secondary amine.
摘要翻译： 本发明涉及使用包含过渡族VIII金属和有机磷配体的金属络合物催化剂和基于空间位阻仲胺的稳定剂存在下使羰基化化合物反应的方法。
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公开(公告)号：US20080188686A1
公开(公告)日：2008-08-07
申请号：US12065091
申请日：2006-06-02
申请人： Dieter Hess , Dagmara Ortmann , Oliver Moeller , Klaus-Diether Wiese , Dirk Fridag , Wilfried Buschken
发明人： Dieter Hess , Dagmara Ortmann , Oliver Moeller , Klaus-Diether Wiese , Dirk Fridag , Wilfried Buschken
CPC分类号： C07C45/50 , B01J31/0237 , B01J31/0247 , B01J31/24 , B01J2231/321 , C07F9/65744 , C07C47/02
摘要： The invention relates to a process for reaction of a carbonylatable compound using a metal complex catalyst comprising a metal of transition group VIII and an organophosphorus ligand and in the presence of a stabilizer based on a sterically hindered secondary amine.
摘要翻译： 本发明涉及使用包含过渡族VIII金属和有机磷配体的金属络合物催化剂和基于空间位阻仲胺的稳定剂存在下使羰基化化合物反应的方法。
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公开(公告)号：US07345185B2
公开(公告)日：2008-03-18
申请号：US10584492
申请日：2004-10-27
IPC分类号： C07F9/02
CPC分类号： C07F9/65746 , C07F9/65719 , C07F9/65742 , C07F9/65744
摘要： The present invention relates to a process for preparing organophosphites, organosphonites and organophosphinites by condensing phosphorus trihalides or organophosphorus halides with organic compounds bearing hydroxyl groups in the presence of polymeric basic ion exchange resins.The process according to the invention makes possible in a simple manner the preparation of trivalent organophosphorus compounds which may serve, for example, as ligands in rhodium complexes which may be used as a catalyst in hydroformylation.
摘要翻译： 本发明涉及在聚合碱性离子交换树脂存在下，通过将三卤化磷或有机磷卤化物与带有羟基的有机化合物相结合来制备有机亚磷酸酯，有机硅和有机磷腈的方法。 根据本发明的方法可以以简单的方式制备三价有机磷化合物，其可以用作例如可用作加氢甲酰化中的催化剂的铑络合物中的配体。
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公开(公告)号：US20070117995A1
公开(公告)日：2007-05-24
申请号：US10584492
申请日：2004-10-27
IPC分类号： C07F9/02
CPC分类号： C07F9/65746 , C07F9/65719 , C07F9/65742 , C07F9/65744
摘要： The present invention relates to a process for preparing organophosphites, organosphonites and organophosphinites by condensing phosphorus trihalides or organophosphorus halides with organic compounds bearing hydroxyl groups in the presence of polymeric basic ion exchange resins. The process according to the invention makes possible in a simple manner the preparation of trivalent organophosphorus compounds which may serve, for example, as ligands in rhodium complexes which may be used as a catalyst in hydroformylation.
摘要翻译： 本发明涉及在聚合碱性离子交换树脂存在下，通过将三卤化磷或有机磷卤化物与带有羟基的有机化合物相结合来制备有机亚磷酸酯，有机硅和有机磷腈的方法。 根据本发明的方法可以以简单的方式制备三价有机磷化合物，其可以用作例如可用作加氢甲酰化中的催化剂的铑络合物中的配体。
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公开(公告)号：US20090203858A1
公开(公告)日：2009-08-13
申请号：US12307600
申请日：2007-05-11
申请人： Michael Grass , Franz Nierlich , Walter Kaminsky , Stefanie Derlin , Klaus-Diether Wiese , Dagmara Ortmann
发明人： Michael Grass , Franz Nierlich , Walter Kaminsky , Stefanie Derlin , Klaus-Diether Wiese , Dagmara Ortmann
IPC分类号： C08F4/42 , C08F210/08 , B01J31/12
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F210/14 , C08F2500/03 , C08F2500/20
摘要： The present invention relates to a copolymer which contains 3-methylbut-1-ene as a comonomer and which contains ethene or propene as a further monomer, the proportion of the incorporated 3-methylbut-1-ene being 0.1 to 40 mol %, and to a process for preparing such copolymers, the polymerization being performed in the presence of a catalyst which comprises at least one cyclopentadienyl group.
摘要翻译： 本发明涉及包含3-甲基丁-1-烯作为共聚单体并且含有乙烯或丙烯作为另外的单体的共聚物，引入的3-甲基丁-1-烯的比例为0.1-40mol％，和 涉及制备这种共聚物的方法，该聚合是在包含至少一个环戊二烯基的催化剂的存在下进行的。
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公开(公告)号：US08202959B2
公开(公告)日：2012-06-19
申请号：US13095541
申请日：2011-04-27
申请人： Michael Grass , Franz Nierlich , Walter Kaminsky , Stefanie Derlin , Klaus-Diether Wiese , Dagmara Ortmann
发明人： Michael Grass , Franz Nierlich , Walter Kaminsky , Stefanie Derlin , Klaus-Diether Wiese , Dagmara Ortmann
IPC分类号： C08F4/642 , C08F4/6592 , C08F210/14
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F210/14 , C08F2500/03 , C08F2500/20
摘要： The present invention relates to a copolymer which contains 3-methylbut-1-ene as a comonomer and which contains ethene or propene as a further monomer, the proportion of the incorporated 3-methylbut-1-ene being 0.1 to 40 mol %, and to a process for preparing such copolymers, the polymerization being performed in the presence of a catalyst which comprises at least one cyclopentadienyl group.
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