PROCESS FOR PREPARING RIGID POLYISOCYANURATE FOAMS USING NATURAL-OIL POLYOLS
    1.
    发明申请
    PROCESS FOR PREPARING RIGID POLYISOCYANURATE FOAMS USING NATURAL-OIL POLYOLS 有权
    使用天然油多酚制备刚性聚异氰酸酯酯的方法

    公开(公告)号:US20090306236A1

    公开(公告)日:2009-12-10

    申请号:US12132722

    申请日:2008-06-04

    IPC分类号: C08J9/14 C08G18/02

    摘要: The present invention provides a process for producing a rigid polyisocyanurate foam involving reacting at an isocyanate index of from about 175 to about 400, a polyisocyanate with at least one natural-oil polyol containing at least about 35 wt. %, based on the weight of the polyol, of natural oil, having a hydroxyl number from about 175 to about 375 and a hydroxyl functionality of about 2.0 to about 2.8, in the presence of a blowing agent and optionally, in the presence of one or more of surfactants, flame retardants, pigments, catalysts and fillers, wherein the resulting foam has a renewable biobased content of at least 8% by weight. The foams provided by the inventive process possess properties similar to foams produced from petroleum-derived materials and may find use in wall or roof insulation systems. The high biobased content (>8%) may allow wall or roof insulation systems containing these foams to be considered for the U.S. Government's preferred procurement program.

    摘要翻译: 本发明提供了一种制备硬质聚异氰脲酸酯泡沫的方法,其包括使异氰酸酯指数为约175至约400的多异氰酸酯与至少一种含至少约35重量% %,基于多元醇的重量,天然油的羟值为约175至约375,羟基官能度为约2.0至约2.8,在发泡剂存在下,任选地,在一种 或更多的表面活性剂,阻燃剂,颜料,催化剂和填料,其中所得泡沫体具有至少8重量%的可再生生物基含量。 由本发明方法提供的泡沫具有类似于由石油衍生的材料制成的泡沫的性质,并且可以用于壁或屋顶绝缘系统中。 高生物基含量(> 8%)可能允许考虑美国政府首选采购计划的包含这些泡沫的墙体或屋顶保温系统。