公开(公告)号：US3749739A

公开(公告)日：1973-07-31

申请号：US3749739D

申请日：1971-12-07

Applicant: DOW CHEMICAL CO

Inventor： HATCH M ,  SCHMIDT D ,  SMITH H

IPC: C07D333/46 ,  C08G65/00 ,  C08G75/00 ,  C08G75/12 ,  C07D63/04 ,  C07D65/04

CPC classification number: C08G65/00 ,  C07D333/46 ,  C08G75/00 ,  C08G75/12

Abstract: POLY(HYDROXYARYLPOLYMETHYLENESULFONIUM) SALTS OF FORMULA I:

HO-PHENYLENE))X-(Z-((R'')A,((-CH2-A-(B)C-CH2-)>S(+)-),HO-

(((-CH2-A-(B)C-CH2-)>S(+)-),R,(R'')A,HO-PHENYL)-(Z-((R'')A,

PHENYLENE))Y-R (X(-))2

N IS 0-6 AND $(X+Y)=1, ARE PREPARED BY CONDENSATION OF A POLYNUCLEAR PHENOL WITH A CYCLIC SULFIDE. THESE SALTS CAN BE CONVERTED INTO A CYCLIC SULFONIUM HYDROXIDE INNER SALT OR ZWITTERIONIC MONOMER (II). THESE REACTIVE CYCLIC SULFONIUM ZWITTERION MONOMERS THERMALLY POLYMERIZE TO YIELD WATER-INSOLUBLE, THERMOSET RESINS USEFUL AS ADHESIVES, COATINGS, FILMS, AND IMPREGNANTS. APPLIED TO NONPOROUS SURFACES, SUCH AS GLASS AND WIRE, HARD SURFACE COATINGS WITH HIGH IMPACT RESISTANCE COUPLED WITH GOOD WATER AND CHEMICAL RESISTANCE ARE OBTAINED.

公开(公告)号：US3767622A

公开(公告)日：1973-10-23

申请号：US3767622D

申请日：1972-04-18

Applicant: DOW CHEMICAL CO

Inventor： SMITH H ,  HATCH M ,  SCHMIDT D

IPC: C08G75/12 ,  C08G23/00

CPC classification number: C08G75/12 ,  Y10T428/294 ,  Y10T428/31938

Abstract: POLY (HYDROXYARYLPOLYMETHYLENESULFONIUM) SALTS (I), PREPARED BY CONDENSATION OF A POLYPHENOLIC RESIN WITH A CYCLIC SULFIDE, ARE CONVERTED INTO A SULFONIUM HYDROXIDE INNER SALT (II) A REACTIVE ZWITTERIONIC MONOMER. THESE ZWITTERIONIC MONOMERS THERMALLY POLYMERIZE TO YIELD WATER-INSOLUBLE, THERMOSET RESINS USEFUL AS ADHESIVES, COATINGS, FILMS, AND IMPREGNANTS. APPLIED TO NON-POROUS SURFACE, SUCH AS GLASS AND WIRE, HARD SURFACE COATINGS WITH HIGH IMPACT RESISTANCE COUPLER WITH GOOD WATER AND CHEMICAL RESISTANCE ARE OBTAINED.

(((-CH2-(B)C-A-CH2-)>S(+)-),R,HO,(R'')A-PHENYL)-(Z-(HO,(R'')A-

PHENYLENE))X-(Z-(HO,(R'')A,(-CH2-(B)C-A-CH2-)>S(+)-PHENYL-

ENE))Y-R (A(-))2

公开(公告)号：US3749738A

公开(公告)日：1973-07-31

申请号：US3749738D

申请日：1971-12-07

Applicant: DOW CHEMICAL CO

Inventor： SMITH H ,  HATCH M ,  SCHMIDT D

IPC: C07D333/46 ,  C08G75/00 ,  C08G75/12 ,  C07D63/04 ,  C07D65/04

CPC classification number: C08G75/12 ,  C07D333/46 ,  C08G75/00

Abstract: POLY-(HYDROXYARLYPOLYMETHYLENESULFONIUM) SALTS OF FORMULA I:

(((-CH2-A-(B)C-CH2-)>S(+)-),R,(R'')A,HO-PHENYL)-(Z-((R'')A,

HO-PHENYLENE))X-(Z-((R'')A,((-CH2-A-(B)C-CH2-)>S(+)-),HO-

PHENYLENE))Y-R (X(-))2

WHERE Z IS -CH2- AND $(X+Y)-1-20, ARE PREPARED BY CONDENSATION OF A POLYNUCLEAR PHENOL WITH A CYCLIC SULFIDE. THESE SALTS CAN BE CONVERTED INTO A CYCLIC SULFONIUM HYDROXIDE INNER SALT OR ZWITTERIONIC MONOMER (II). THESE REACTIVE CYCLIC SULFONIUM ZWITTERION MONOMERS THERMALLY POLYMERIZE TO YIELD WATER-INSOLUBLE, THERMOSET RESINS USEFUL AS ADHESIVES, COATINGS, FILMS, AND IMPREGNANTS. APPLIED TO NONPOROUS SURFACES, SUCH AS GLASS AND WIRE, HARD SURFACE COATINGS WITH HIGH IMPACT RESISTANCE COUPLED WITH GOOD WATER AND CHEMICAL RESISTANCE ARE OBTAINED.

公开(公告)号：US3723386A

公开(公告)日：1973-03-27

申请号：US3723386D

申请日：1971-03-29

Applicant: DOW CHEMICAL CO

Inventor： HATCH M ,  YOSHIMINE M ,  SMITH H ,  SCHMIDT D

IPC: C07D333/46 ,  C08G75/12 ,  C08G23/00 ,  C08G25/00

CPC classification number: C08G75/12 ,  C07D333/46

Abstract: HYDROXYARYLPOLYMETHYLENESULFONIUM SALTS OF FORMULA 1, PREPARED BY CONDENSATION OF A PHENOL AND A POLYMETHYLENESULFIDE, CAN BE CONVERTED INTO A SULFONIUM HYDROXIDE INNER SALT II AND THEN THERMALLY POLYMERIZED TO YIELD POLYMERS CONTAINING A PLURALITY OF GROUPS OF FORMULA III:

(4-(HO-),R,R'',R"-PHENYL)-S+
(4-(-O+),R,R'',R"-PHENYL)-S
(-O-(R,R'',R"-PHENYLENE)-S-CH2-A-(B)N-CH2-) III

THESE POLYMERS AND COPOLYMERS ARE USEFUL WATER RESISTANT THERMOPLASTIC RESINS AND IMPREGNANTS.

公开(公告)号：US3813413A

公开(公告)日：1974-05-28

申请号：US12911871

申请日：1971-03-29

Applicant: DOW CHEMICAL CO

Inventor： HATCH M ,  YOSHIMINE M ,  SMITH H ,  SCHMIDT D

IPC: C07D333/46 ,  C07D333/72 ,  C08G75/00 ,  C08G75/12 ,  C07D63/08

CPC classification number: C07D333/46 ,  C07D333/72 ,  C08G75/00 ,  C08G75/12

Abstract: HYDROXYARYLPOLYMETHYLENESULFONIUM SALTS OF FORMULA I, PREPARED BY CONDENSATION OF A PHENOL AND A POLYMETHYLENESULFIDE, CAN BE CONVERTED INTO A SULFONIUM HYDROXIDE INNER SALT II AND THEN THERMALLY POLYMERIZED TO YIELD POLYMERS CONTAINING A PLURALITY OF GROUPS OF FORMULA III:

(I) ((-CH2-A-(B)A-CH2-)>S(+)-),R,R'',R"-PHENOL X(-)

(II) ((-CH2-A-(B)A-CH2-)>S(+)-),((-)O-),R,R'',R"-BENZENE

(III) -O-(R,R'',R"-PHENYLENE)-S-CH2-A-(B)A-CH2-

THESE POLYMERS AND COPOLYMERS ARE USEFUL WATER RESISTANT THERMOPLASTIC RESINS AND IMPREGNANTS.

公开(公告)号：US3749737A

公开(公告)日：1973-07-31

申请号：US3749737D

申请日：1971-12-07

Applicant: DOW CHEMICAL CO

Inventor： HATCH M ,  SCHMIDT D ,  SMITH H

IPC: C07D333/46 ,  C08G75/00 ,  C08G75/12 ,  C07D63/04 ,  C07D65/04

CPC classification number: C08G75/12 ,  C07D333/46 ,  C08G75/00

Abstract: POLY(HYDROXYARYLPOLYMETHYLENESULFONIUM) SALTS OF FORMULA I:

(((-CH2-A-(B)C-CH2-)>S(+)-),R,(R'')A,HO-PHENYL)-(Z-((R'')A,

HO-PHENYLENE))X-(Z-((R'')A,((-CH2-A-(B)C-CH2-)>S(+)-),HO-

PHENYLENE))Y-R (X(-))2

WHERE Z IS -C(C1-C4 ALKYL)2- AND $(X+Y)=1, ARE PREPARED BY CONDENSATION OF A POLYNUCLEAR PHENOL WITH A CYCLIC SULFIDE. THESE SALTS CAN BE CONVERTED INTO A CYCLIC SULFONIUM HYDROXIDE INNER SALT OR ZWITTERIONIC MONOMER (II). THESE REACTIVE CYCLIC SULFONIUM ZWITTERION MOMOMERS THERMALLY POLYMERIZE TO YIELD WATER-INSOLUBLE, THERMOSET RESINS USEFUL AS ADHESIVES, COATINGS, FILMS, AND IMPREGNANTS. APPLIED TO NONPOROUS SURFACES, SUCH AS GLASS AND WIRE, HARD SURFACE COATINGS WITH HIGH IMPACT RESISTANCE COUPLED WITH GOOD WATER AND CHEMICAL RESISTANCE ARE OBTAINED.