公开(公告)号：US20160317977A1

公开(公告)日：2016-11-03

申请号：US15104023

申请日：2014-12-15

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Abhishek Roy ,  Nicholas S. Beck ,  Robert C. Cieslinski ,  Bruce B. Gerhart ,  David D. Hawn ,  Duane Jacobson ,  Mou Paul ,  Carl W. Reinhardt ,  Katmerka Tabakovic ,  Ian A. Tomlinson

IPC: B01D69/12 ,  B01D67/00 ,  B01D71/56

CPC classification number: B01D69/125 ,  B01D67/0006 ,  B01D71/56 ,  B01D2323/40

Abstract: A method for making a composite polyamide membrane including the step of applying a polar solution including a polyfunctional amine monomer and a non-polar solution comprising a polyfunctional acyl halide monomer to a surface of a porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is characterized by including a tri-hydrocarbyl phosphate within the polar coating solution. The thin film polyamide layer is characterized by possessing an equilibrium water swelling factor of greater than 35% as measured by PFT-AFM.

Abstract translation: 一种制备复合聚酰胺膜的方法，包括以下步骤：将包含多官能胺单体的极性溶液和包含多官能酰卤单体的非极性溶液施加到多孔载体的表面并使单体界面聚合以形成薄膜 聚酰胺层，其中该方法的特征在于在极性涂层溶液中包含磷酸三烃基酯。 薄膜聚酰胺层的特征在于通过PFT-AFM测量的平衡水膨胀系数大于35％。