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1.发明申请公开(公告)号：US20150129485A1
公开(公告)日：2015-05-14
申请号：US14406994
申请日：2013-07-03
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Abhishek Roy , Tina L. Arrowood , Robert C. Cieslinski , David D. Hawn , Steven D. Jons , Mou Paul , Martin H. Peery , XiaoHua Qiu , Steven Rosenberg , Ian A. Tomlinson , Chengli Zu
CPC classification number: B01D67/0006 , B01D61/025 , B01D67/0002 , B01D69/10 , B01D69/12 , B01D69/125 , B01D71/56 , B01D2323/00 , B01D2323/38 , B01D2323/40 , B01D2325/20
Abstract: A thin film composite membrane including a porous support and a thin film polyamide layer characterized by having a dissociated carboxylate content of at least 0.45 moles/kg at pH 9.5 and a method for making a composite polyamide applying a polar solution comprising a polyfunctional amine monomer and a non-polar solution comprising a polyfunctional amine-reactive monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is characterized by the non-polar solution comprising at least 0.025 wt % of an acid compound including at least one carboxylic acid moiety and at least one amine-reactive moiety selected from acyl halide and anhydride.
Abstract translation: 一种薄膜复合膜，其包括多孔载体和薄膜聚酰胺层，其特征在于在pH9.5下具有至少0.45摩尔/ kg的解离的羧酸盐含量，以及制备复合聚酰胺的方法，所述方法包括施加包含多官能胺单体的极性溶液和 一种非极性溶液，其包含多官能胺反应性单体到所述多孔载体的表面，并且将所述单体界面聚合以形成薄膜聚酰胺层，其中该方法的特征在于非极性溶液包含至少0.025wt％ 包含至少一个羧酸部分和至少一个选自酰卤和酸酐的胺反应性部分的酸化合物。
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公开(公告)号：US09925500B2
公开(公告)日：2018-03-27
申请号：US14407013
申请日：2013-07-03
Applicant: Dow Global Technologies LLC
Inventor： Mou Paul , Tina L. Arrowood , Robert C. Cieslinski , Steven D. Jons , Steven Rosenberg , Abhishek Roy , Ian A. Tomlinson
CPC classification number: B01D67/0006 , B01D61/025 , B01D67/0002 , B01D69/10 , B01D69/12 , B01D69/125 , B01D71/56 , B01D2323/00 , B01D2323/38 , B01D2323/40 , B01D2325/20
Abstract: A method for making a composite polyamide membrane including a porous support and a thin film polyamide layer including the steps of applying a polyfunctional amine monomer and a combination amine-reactive compounds to a surface of the porous support and reacting the constituents to form a thin film polyamide layer, wherein the amine-reactive compounds include: i) a polyfunctional amine-reactive monomer including two to three amine-reactive moieties selected from acyl halide, sulfonyl halide and anhydride, ii) a polyfunctional amine-reactive monomer including at least four amine-reactive moieties selected from acyl halide, sulfonyl halide and anhydride, and iii) an acid compound including at least on carboxylic acid moiety or salt thereof and at least one amine-reactive moiety selected from acyl halide and sulfonyl halide.
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公开(公告)号：US09610542B2
公开(公告)日：2017-04-04
申请号：US14406994
申请日：2013-07-03
Applicant: Dow Global Technologies LLC
Inventor： Abhishek Roy , Tina L. Arrowood , Robert C. Cieslinski , David D. Hawn , Steven D. Jons , Mou Paul , Martin H. Peery , XiaoHua Qiu , Steven Rosenberg , Ian A. Tomlinson , Chengli Zu
CPC classification number: B01D67/0006 , B01D61/025 , B01D67/0002 , B01D69/10 , B01D69/12 , B01D69/125 , B01D71/56 , B01D2323/00 , B01D2323/38 , B01D2323/40 , B01D2325/20
Abstract: A thin film composite membrane including a porous support and a thin film polyamide layer characterized by having a dissociated carboxylate content of at least 0.45 moles/kg at pH 9.5 and a method for making a composite polyamide applying a polar solution comprising a polyfunctional amine monomer and a non-polar solution comprising a polyfunctional amine-reactive monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is characterized by the non-polar solution comprising at least 0.025 wt % of an acid compound including at least one carboxylic acid moiety and at least one amine-reactive moiety selected from acyl halide and anhydride.
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公开(公告)号：US20160317977A1
公开(公告)日：2016-11-03
申请号：US15104023
申请日：2014-12-15
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Abhishek Roy , Nicholas S. Beck , Robert C. Cieslinski , Bruce B. Gerhart , David D. Hawn , Duane Jacobson , Mou Paul , Carl W. Reinhardt , Katmerka Tabakovic , Ian A. Tomlinson
CPC classification number: B01D69/125 , B01D67/0006 , B01D71/56 , B01D2323/40
Abstract: A method for making a composite polyamide membrane including the step of applying a polar solution including a polyfunctional amine monomer and a non-polar solution comprising a polyfunctional acyl halide monomer to a surface of a porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is characterized by including a tri-hydrocarbyl phosphate within the polar coating solution. The thin film polyamide layer is characterized by possessing an equilibrium water swelling factor of greater than 35% as measured by PFT-AFM.
Abstract translation: 一种制备复合聚酰胺膜的方法，包括以下步骤：将包含多官能胺单体的极性溶液和包含多官能酰卤单体的非极性溶液施加到多孔载体的表面并使单体界面聚合以形成薄膜 聚酰胺层，其中该方法的特征在于在极性涂层溶液中包含磷酸三烃基酯。 薄膜聚酰胺层的特征在于通过PFT-AFM测量的平衡水膨胀系数大于35％。
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5.发明申请公开(公告)号：US20150174534A1
公开(公告)日：2015-06-25
申请号：US14407013
申请日：2013-07-03
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Mou Paul , Tina L. Arrowood , Robert C. Cieslinski , Steven D. Jons , Steven Rosenberg , Abhishek Roy , Ian A. Tomlinson
IPC: B01D67/00
CPC classification number: B01D67/0006 , B01D61/025 , B01D67/0002 , B01D69/10 , B01D69/12 , B01D69/125 , B01D71/56 , B01D2323/00 , B01D2323/38 , B01D2323/40 , B01D2325/20
Abstract: A method for making a composite polyamide membrane including a porous support and a thin film polyamide layer including the steps of applying a polyfunctional amine monomer and a combination amine-reactive compounds to a surface of the porous support and reacting the constituents to form a thin film polyamide layer, wherein the amine-reactive compounds include: i) a polyfunctional amine-reactive monomer including two to three amine-reactive moieties selected from acyl halide, sulfonyl halide and anhydride, ii) a polyfunctional amine-reactive monomer including at least four amine-reactive moieties selected from acyl halide, sulfonyl halide and anhydride, and iii) an acid compound including at least on carboxylic acid moiety or salt thereof and at least one amine-reactive moiety selected from acyl halide and sulfonyl halide.
Abstract translation: 一种制造包括多孔载体和薄膜聚酰胺层的复合聚酰胺膜的方法，包括以下步骤：将多官能胺单体和组合胺反应性化合物施加到多孔载体的表面，并使组分反应形成薄膜 聚酰胺层，其中胺反应性化合物包括：i）包含选自酰基卤，磺酰卤和酸酐的两个至三个胺反应性部分的多官能胺反应性单体，ii）包含至少四个胺的多官能胺反应性单体 - 选自酰基卤，磺酰卤和酸酐的反应性部分，和iii）至少包含羧酸部分或其盐以及至少一种选自酰卤和磺酰卤的胺反应性部分的酸化合物。
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Patent Agency Ranking
公开(公告)号：US09981227B2
公开(公告)日：2018-05-29
申请号：US15102882
申请日：2014-12-15
Applicant: Dow Global Technologies LLC
Inventor： Mou Paul , Robert C. Cieslinski , Bruce B. Gerhart , David D. Hawn , XiaoHua Qiu , Mark A. Rickard , Steven Rosenberg , Abhishek Roy , Ian A. Tomlinson , Chengli Zu
CPC classification number: B01D71/56 , B01D67/0006 , B01D67/0093 , B01D67/0095 , B01D67/0097 , B01D69/02 , B01D69/125 , B01D2323/36 , B01D2323/40
Abstract: A thin film composite polyamide membrane comprising a porous support and a thin film polyamide layer characterized by possessing: i) an azo (—N═N—) content of from 0.40% to 1.00%, as measured by pyrolysis gas chromatography; and ii) a dissociated carboxylate content of at least 0.40 mol/kg as measured by RBS at pH 9.5.
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公开(公告)号：US09662615B2
公开(公告)日：2017-05-30
申请号：US14405711
申请日：2013-07-03
Applicant: Dow Global Technologies LLC
Inventor： Abhishek Roy , Tina L. Arrowood , Robert C. Cieslinski , Derek M. Stevens , David D. Hawn , Steven D. Jons , Mou Paul , Martin H. Peery , Steven Rosenberg , Ian A. Tomlinson
CPC classification number: B01D67/0006 , B01D61/025 , B01D67/0002 , B01D69/10 , B01D69/12 , B01D69/125 , B01D71/56 , B01D2323/00 , B01D2323/38 , B01D2323/40 , B01D2325/20
Abstract: A method for making a composite polyamide membrane comprising a porous support and a thin film polyamide layer, wherein the method includes the step of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the step of applying the polyfunctional acyl halide monomer to the porous support includes the step of combining the polyfunctional acyl halide monomer with a non-polar solvent at a concentration of at least 0.18 weight percent to form a coating solution which is applied to the surface of the porous support, and wherein the interfacial polymerization is conducted in the presence of a tri-hydrocarbyl phosphate compound which is provided in a molar ratio of at least 0.5:1 with the polyfunctional acyl halide monomer. Many additional embodiments are described including membranes made from the subject method and applications for such membranes.
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公开(公告)号：US09616392B2
公开(公告)日：2017-04-11
申请号：US15033936
申请日：2014-12-15
Applicant: Dow Global Technologies LLC
Inventor： Ian A. Tomlinson , Robert C. Cieslinski , Bruce B. Gerhart , David D. Hawn , Mou Paul , XiaoHua Qiu , Mark A. Rickard , Steven Rosenberg , Abhishek Roy , Chengli Zu
CPC classification number: B01D71/56 , B01D67/0093 , B01D69/125 , B01D2323/36 , B01D2323/40
Abstract: A thin film composite polyamide membrane comprising a porous support and a thin film polyamide layer characterized by possessing: i) an azo (—N═N—) content of from 0.30% to 0.80%, as measured by pyrolysis gas chromatography; and ii) a dissociated carboxylate content of at least 0.18 mol/kg as measured by RBS at pH 9.5.
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公开(公告)号：US09555378B2
公开(公告)日：2017-01-31
申请号：US15102879
申请日：2014-12-15
Applicant: Dow Global Technologies LLC
Inventor： Abhishek Roy , Robert C. Cieslinski , Bruce B. Gerhart , David D. Hawn , Mou Paul , XiaoHua Qiu , Mark A. Rickard , Steven Rosenberg , Ian A. Tomlinson , Chengli Zu
CPC classification number: B01D71/56 , B01D67/0006 , B01D69/125 , B01D2323/36 , B01D2323/40
Abstract: A thin film composite polyamide membrane comprising a porous support and a thin film polyamide layer characterized by possessing an azo (—N═N—) content of from 0.75% to 0.95%, as measured by pyrolysis gas chromatography.
Abstract translation: 一种薄膜复合聚酰胺膜，其包含多孔载体和薄膜聚酰胺层，其特征在于，通过热解气相色谱测定，其具有0.75％至0.95％的偶氮（-N = N - ）含量。
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公开(公告)号：US20160303520A1
公开(公告)日：2016-10-20
申请号：US15102879
申请日：2014-12-15
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Abhishek Roy , Robert C. Cieslinski , Bruce B. Gerhart , David D. Hawn , Mou Paul , XiaoHua Qiu , Mark A. Rickard , Steven Rosenberg , Ian A. Tomlinson , Chengli Zu
CPC classification number: B01D71/56 , B01D67/0006 , B01D69/125 , B01D2323/36 , B01D2323/40
Abstract: A thin film composite polyamide membrane comprising a porous support and a thin film polyamide layer characterized by possessing an azo (—N═N—) content of from 0.75% to 0.95%, as measured by pyrolysis gas chromatography.
Abstract translation: 一种薄膜复合聚酰胺膜，其包含多孔载体和薄膜聚酰胺层，其特征在于，通过热解气相色谱测定，其具有0.75％至0.95％的偶氮（-N = N - ）含量。
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