公开(公告)号：US10717817B2

公开(公告)日：2020-07-21

申请号：US15980769

申请日：2018-05-16

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G71/04 ,  C08G65/333 ,  C09D175/12 ,  C08L75/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a divalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times two equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US10005723B2

公开(公告)日：2018-06-26

申请号：US14912157

申请日：2014-08-15

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Daryoosh Beigzadeh ,  Duane Romer ,  Thomas Clark ,  Peter Margl ,  Congcong Lu

IPC: C07C271/00 ,  C07C269/00 ,  C08G65/333 ,  C08G71/04 ,  C07C271/10 ,  C09D7/12 ,  C09D175/04 ,  C09D7/63

CPC classification number: C07C269/00 ,  C07C271/10 ,  C08G65/33303 ,  C08G65/33324 ,  C08G71/04 ,  C09D7/63 ,  C09D175/04

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a trivalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times three equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US20160222164A1

公开(公告)日：2016-08-04

申请号：US14912160

申请日：2014-08-15

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, JR. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G71/04 ,  C09D175/12

CPC classification number: C08G71/04 ,  C08G65/33306 ,  C08G65/33324 ,  C09D175/04 ,  C09D175/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a tetravalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times four equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

Abstract translation: 一种制备聚氨酯的方法，包括在至少一种选自具有下式MmZn的化合物的催化剂存在下将多元醇加入到多元醇中; 其中M是四价金属，Z是阴离子官能团或能够与M形成共价键的官能团，并且其中Z的数量等于X和m的四倍等于Y，其中X的绝对值等于绝对值 提供了Y值。 还提供了根据该方法制备的聚氨酯和包含聚氨酯的涂料组合物。

公开(公告)号：US10131746B2

公开(公告)日：2018-11-20

申请号：US14912160

申请日：2014-08-15

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G71/00 ,  C08G71/04 ,  C08G65/333 ,  C09D175/04 ,  C09D175/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a tetravalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times four equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US10457777B2

公开(公告)日：2019-10-29

申请号：US14855426

申请日：2015-09-16

Applicant: Dow Global Technologies LLC

Inventor： Daryoosh Beigzadeh ,  Thomas P. Clark ,  Paul Foley ,  Congcong Lu ,  Peter Margl ,  Duane R. Romer

IPC: C08G73/00 ,  C08G71/04 ,  C08L33/06

Abstract: The present invention provides carbamylation compositions of one or more urea compounds, one or more polyols and a monovalent transition metal or alkali metal catalyst (i), such as lithium ethylhexanoate, which compositions are substantially isocyanate free, enjoy reduced toxicity in comparison to tin catalysts, and which are useful in making polycarbamates which themselves provide compositions for making crosslinked polyurethanes.

公开(公告)号：US20180265458A1

公开(公告)日：2018-09-20

申请号：US15986271

申请日：2018-05-22

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, JR. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C07C269/00 ,  C09D7/63 ,  C07C271/10 ,  C08G65/333 ,  C08G71/04 ,  C09D175/04

CPC classification number: C07C269/00 ,  C07C271/10 ,  C08G65/33303 ,  C08G65/33324 ,  C08G71/04 ,  C09D7/63 ,  C09D175/04

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a trivalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times three equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US20180258224A1

公开(公告)日：2018-09-13

申请号：US15980769

申请日：2018-05-16

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, JR. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G71/04 ,  C08G65/333 ,  C09D175/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a divalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times two equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US10343983B2

公开(公告)日：2019-07-09

申请号：US15986271

申请日：2018-05-22

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C09D7/63 ,  C07C269/00 ,  C08G65/333 ,  C08G71/04 ,  C07C271/10 ,  C09D175/04

Abstract: A polycarbamate comprising having less than 5 wt % total of biuret, cyanuric acid, and polyallophanate; and has a Gardner level of equal or greater than 3 is provided. A coating comprising the polycarbamate is also provided.

公开(公告)号：US10000610B2

公开(公告)日：2018-06-19

申请号：US14912161

申请日：2014-08-15

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G73/00 ,  C08G71/04 ,  C09D175/12 ,  C08G65/333

CPC classification number: C08G71/04 ,  C08G65/33306 ,  C08G65/33324 ,  C09D175/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a divalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times two equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US20160200871A1

公开(公告)日：2016-07-14

申请号：US14912161

申请日：2014-08-15

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Xinrui Yu ,  Ylyong He ,  John W. Hull, JR. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G71/04 ,  C09D175/12

CPC classification number: C08G71/04 ,  C08G65/33306 ,  C08G65/33324 ,  C09D175/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a divalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times two equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

Abstract translation: 一种制备聚氨酯的方法，包括在至少一种选自具有下式MmZn的化合物的催化剂存在下将多元醇加入到多元醇中; 其中M是二价金属，Z是阴离子官能团或能够与M形成共价键的官能团，并且其中Z的数量等于X并且m倍的2倍等于Y，其中X的绝对值等于绝对值 提供了Y值。 还提供了根据该方法制备的聚氨酯和包含聚氨酯的涂料组合物。