公开(公告)号：US20150218291A1

公开(公告)日：2015-08-06

申请号：US14420911

申请日：2013-08-15

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Oliver Petermann ,  Matthias Sprehe ,  Warren K. Miller

IPC: C08B13/00

Abstract: In a process for preparing an esterified cellulose ether a cellulose ether is esterified with (i) an aliphatic monocarboxylic acid anhydride or (ii) a dicarboxylic acid anhydride or (iii) a combination of an aliphatic monocarboxylic acid anhydride and a dicarboxylic acid anhydride in the presence of an alkali metal carboxylate and an aliphatic carboxylic acid, wherein the molar ratio [alkali metal carboxylate/anhydroglucose units of cellulose ether] is not more than [1.20/1] and the molar ratio [aliphatic carboxylic acid/anhydroglucose units of cellulose ether] is from [3.55/1] to [9.0/1].

Abstract translation: 在制备酯化纤维素醚的方法中，将纤维素醚与（i）脂族单羧酸酐或（ii）二羧酸酐或（iii）脂肪族单羧酸酐和二羧酸酐的组合在 碱金属羧酸盐和脂族羧酸的存在，其中[碱金属羧酸盐/纤维素醚的脱水葡萄糖单元]的摩尔比不超过[1.20 / 1]，摩尔比[纤维素醚的脂肪族羧酸/脱水葡萄糖单元 ]从[3.55 / 1]到[9.0 / 1]。

公开(公告)号：US10730957B2

公开(公告)日：2020-08-04

申请号：US14420911

申请日：2013-08-15

Applicant: Dow Global Technologies LLC

Inventor： Oliver Petermann ,  Matthias Sprehe ,  Warren K. Miller

IPC: C08B13/00 ,  C08B11/20

Abstract: In a process for preparing an esterified cellulose ether a cellulose ether is esterified with (i) an aliphatic monocarboxylic acid anhydride or (ii) a dicarboxylic acid anhydride or (iii) a combination of an aliphatic monocarboxylic acid anhydride and a dicarboxylic acid anhydride in the presence of an alkali metal carboxylate and an aliphatic carboxylic acid, wherein the molar ratio [alkali metal carboxylate/anhydroglucose units of cellulose ether] is not more than [1.20/1] and the molar ratio [aliphatic carboxylic acid/anhydroglucose units of cellulose ether] is from [3.55/1] to [9.0/1].

公开(公告)号：US20150218197A1

公开(公告)日：2015-08-06

申请号：US14420921

申请日：2013-08-15

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Oliver Petermann ,  Matthias Sprehe ,  Robert L. Schmitt ,  Andrew C. Arthur ,  Warren K. Miller ,  David K. Lyon

IPC: C07H3/06

CPC classification number: C07H3/06 ,  C08B11/20 ,  C08B13/00

Abstract: Two or more esters of a cellulose ether, each having the same ether and ester substituents but different weight average molecular weights are prepared in a process which comprises the steps of esterifying a cellulose ether with (i) an aliphatic monocarboxylic acid anhydride or (ii) a dicarboxylic acid anhydride or (iii) a combination of an aliphatic monocarboxylic acid anhydride and a dicarboxylic acid anhydride in the presence of an aliphatic carboxylic acid as a reaction diluent in two or more separate reactions, wherein in each reaction a different molar ratio [aliphatic carboxylic acid/anhydroglucose units of cellulose ether] is used to produce esters of the cellulose ether of different weight average molecular weights.

Abstract translation: 在包括以下步骤的方法中制备两种或更多种纤维素醚的酯，它们各自具有相同的醚和酯取代基但不同的重均分子量，该方法包括以下步骤：（i）脂肪族单羧酸酐或（ii） 二羧酸酐或（iii）脂肪族单羧酸酐和二羧酸酐在脂肪族羧酸作为反应稀释剂的存在下在两个或更多个分开的反应中的组合，其中在每个反应中不同的摩尔比[脂族 纤维素醚的羧酸/脱水葡萄糖单元]用于生产不同重均分子量的纤维素醚的酯。