公开(公告)号：US10183916B2

公开(公告)日：2019-01-22

申请号：US15571113

申请日：2016-05-12

Applicant: DSM IP ASSETS B.V.

Inventor： Nadine Greiner ,  Sandro Schmid ,  René Tobias Stemmler

IPC: C07D251/24 ,  C07B49/00 ,  C07B63/00 ,  C07D251/20 ,  C07F3/02

Abstract: The invention relates to an improved process for the manufacture of bis-resorcinyl triazines of formula (I) wherein R1 is a C1C18alkyl group or C2-C18alkenyl group as well as the respective alkyl substituted bis-resorcinyl derivatives of formula (II) wherein R1 is a C1-C18alkyl group or C2-C18alkenyl group and R2 and R3 are independently of each other a C1-C18alkyl group or a C2-C18alkenyl group.

公开(公告)号：US09765002B2

公开(公告)日：2017-09-19

申请号：US14651510

申请日：2013-12-18

Applicant: DSM IP ASSETS B.V.

Inventor： René Tobias Stemmler ,  Nadine Greiner

IPC: C07C43/313 ,  C07C321/30 ,  C07C45/67 ,  C07D319/06

CPC classification number: C07C43/313 ,  C07B2200/09 ,  C07C45/67 ,  C07C321/30 ,  C07D319/06 ,  C07C49/203

Abstract: The present invention relates to a process of a cis/trans isomerization of an unsaturated compound A being selected from the group consisting of unsaturated ketones, unsaturated ketals, unsaturated aldehydes, unsaturated acetals, unsaturated carboxylic acids, esters of an unsaturated carboxylic acid and amides of an unsaturated carboxylic acid using polythiol as cis/trans isomerization catalyst. It has been observed that the isomerization is very efficient and fast.

公开(公告)号：US10179772B2

公开(公告)日：2019-01-15

申请号：US15571104

申请日：2016-05-12

Applicant: DSM IP ASSETS B.V.

Inventor： Nadine Greiner ,  Sandro Schmid ,  René Tobias Stemmler

IPC: C07D251/24

Abstract: The invention relates to an improved process for the manufacture of bis-resorcinyl triazines of formula (I), wherein R1 is hydrogen, a C1-C18 alkyl group or a C2-C18 alkenyl group and R2 is a C1-C18 alkyl group or a C2-C18 alkenyl group. (I)

公开(公告)号：US09434671B2

公开(公告)日：2016-09-06

申请号：US14652286

申请日：2013-12-18

Applicant: DSM IP ASSETS B.V.

Inventor： René Tobias Stemmler ,  Nadine Greiner ,  Angela Wildermann

IPC: C07C45/67 ,  C07C29/56 ,  C07C33/02 ,  C07C43/313 ,  C07C49/203

CPC classification number: C07C43/313 ,  C07B2200/09 ,  C07C29/56 ,  C07C33/02 ,  C07C45/67 ,  C07C49/203

Abstract: The present invention relates to a process of a cis/trans isomerization of an unsaturated compound A being selected from the group consisting of unsaturated ketones, unsaturated ketals, unsaturated aldehydes, unsaturated acetals, unsaturated carboxylic acids, esters of an unsaturated carboxylic acid and amides of an unsaturated carboxylic acid using nitrogen monoxide as cis/trans isomerization catalyst. It has been observed that the isomerization is very efficient and fast.

Abstract translation: 本发明涉及不饱和化合物A的顺式/反式异构化方法，其选自不饱和酮，不饱和缩酮，不饱和醛，不饱和缩醛，不饱和羧酸，不饱和羧酸的酯和酰胺的酰胺 使用一氧化氮作为顺式/反式异构化催化剂的不饱和羧酸。 已经观察到异构化非常有效和快速。