公开(公告)号：US3901946A

公开(公告)日：1975-08-26

申请号：US46216374

申请日：1974-04-18

Applicant: DYNAMIT NOBEL AG

Inventor： LENZ ARNOLD ,  ACKERMANN OTTO ,  BLEH OTTO

IPC: C07C43/32

CPC classification number: C07C43/32

Abstract: A method for the preparation of orthoformic acid trialkyl esters is disclosed. The process comprises continuously reacting chloroform and alkali alcoholates under anhydrous conditions at elevated temperatures and pressures.

公开(公告)号：US3699137A

公开(公告)日：1972-10-17

申请号：US3699137D

申请日：1970-12-08

Applicant: DYNAMIT NOBEL AG

Inventor： TERMIN ERICH ,  BLEH OTTO

IPC: C07C55/07 ,  C07C51/00 ,  C07C67/00 ,  C07F7/00 ,  C07F7/28 ,  C08F4/16

CPC classification number: C07F7/006

Abstract: Process for the production of potassium titanyl oxalate which comprises heating a tetraalkyl titanate with about three times the molar amount of water and twice the molar amount of potassium hydrogen oxalate. If desired, two thirds of the water is added initially and the balance subsequently. A solvent such as an alkanol may be employed. Advantageously the reaction, distillation of volatiles, crystallization and drying are all performed in the same vessel.

Abstract translation: 用于生产草酸氧钛钾的方法，其包括用约三倍摩尔量的水和两倍于草酸氢钾的摩尔量加热钛酸四烷基酯。 如果需要，最初加入三分之二的水，然后平衡。 可以使用溶剂如链烷醇。 有利的是，挥发物的反应，蒸馏，结晶和干燥都在相同的容器中进行。

公开(公告)号：US3895097A

公开(公告)日：1975-07-15

申请号：US34357973

申请日：1973-03-21

Applicant: DYNAMIT NOBEL AG

Inventor： LANGENHOFF FERDINAND ,  TERMIN ERICH ,  BLEH OTTO ,  KOLB RICO

IPC: B01J8/02 ,  C01G25/04 ,  C01G31/04 ,  C22B1/08 ,  C22B34/12 ,  C01G31/00 ,  C01B33/08 ,  C01G23/02

CPC classification number: C22B34/1222 ,  B01J8/0285 ,  B01J2208/00415 ,  B01J2208/00433 ,  B01J2208/00495 ,  C01G25/04 ,  C01G31/04 ,  C22B1/08 ,  Y02P10/23

Abstract: In a tubular reactor carrying a bed of solid material into which carbon electrodes project for heating the material upon passage of a current, the outside ends of said electrodes being connected to metallic conductors in turn connected to a supply of current, the invention involves pouring lead about the end of each electrode to effect improved contact between the electrode and its respective metallic conductor. The process involving use of such electrodes to react carbon with chlorine and the oxide of silicon or metals such as vanadium, titanium or zirconium is also covered.

Abstract translation: 在载有固体材料床的管状反应器中，碳电极在电流通过时突出加热材料，所述电极的外端连接到金属导体，并连接到电流供应，本发明涉及将铅 关于每个电极的端部以实现电极和其相应的金属导体之间的改善的接触。 涉及使用这种电极使碳与氯反应的方法以及硅或金属如钒，钛或锆的氧化物也被覆盖。

公开(公告)号：US3880915A

公开(公告)日：1975-04-29

申请号：US19113071

申请日：1971-10-20

Applicant: DYNAMIT NOBEL AG

Inventor： VON METNITZ HARALD ,  BLEH OTTO ,  LENZ ARNOLD

IPC: C07C51/36

CPC classification number: C07C51/36 ,  C07C61/22

Abstract: A method for preparing Delta 2,5-cyclohexadiene dicarboxylic acid-1,2 is disclosed. The process involves reduction of an alkali phthalate by means of an alkali metal amalgam. The disclosed method has particular utility in that an efficient means for selectively reducing phthalic acid to Delta 2,5cyclohexadiene dicarboxylic acid-1,2 is provided.

Abstract translation: 公开了一种制备DELTA 2,5-环己二烯二羧酸-1,2的方法。 该方法包括通过碱金属汞齐还原碱式邻苯二甲酸酯。 所公开的方法具有特别的用途，因为提供了选择性还原邻苯二甲酸至DELTA 2,5-环己二烯二羧酸-1,2的有效手段。

公开(公告)号：US3673159A

公开(公告)日：1972-06-27

申请号：US3673159D

申请日：1970-05-11

Applicant: DYNAMIT NOBEL AG

Inventor： DIJKHUIZEN WILLEM ,  TERMIN ERICH ,  BLEH OTTO ,  MORGENSTERN DIETER

IPC: C08G18/08 ,  C08G18/22 ,  C08G22/40

CPC classification number: C08G18/0885 ,  C08G18/222

Abstract: In the manufacture of a polyurethane by the reaction of a polyol with a polyisocyanate in the presence of a catalyst and in the absence of water, the catalyst used is an organic zirconium compound, preferably a zirconium alcoholate or phenolate, having the formula: (Y)mZr(YR)4 2m WHEREIN: Zr is a zirconium atom Y is an oxygen or sulfur atom R is an organic radical of up to 12 carbon atoms, which can be alike or different M IS 0 OR 1.

Abstract translation: 在通过多元醇与多异氰酸酯在催化剂存在下和不存在水的情况下反应制备聚氨酯时，所用的催化剂是具有下式的有机锆化合物，优选醇锆或酚盐，具有下式：（Y ）mZr（YR）4-2mWHEEIN：

公开(公告)号：US3684433A

公开(公告)日：1972-08-15

申请号：US3684433D

申请日：1970-07-22

Applicant: DYNAMIT NOBEL AG

Inventor： LANGENHOFF FERDINAND ,  TERMIN ERICH ,  BLEH OTTO ,  LENZ ARNOLD

IPC: C01G31/00 ,  C01G31/04 ,  C22B59/00

CPC classification number: C01G31/04

Abstract: IN THE PRODUCTION OF VANADIUM OXYTRICHLORIDE WHEREIN VANADIUM PENTOXID, CARBON AND CHLORINE ARE REACTED, THE IMPROVEMENT WHICH COMPRISES EFFECTING THE REACTION BY CONTACTING A MIXTURE OF FINE-GRAINED VANADIUM PENTOXIDE AND CARBON IN THE FORM OF A GAS PERMEABLE LAYER ABOUT 0.5 TO 20 CM. HIGH WITH CHLORINE AT A TEMPERATURE OF ABOUT 350 TO 750*C. PREFERABLY THE PROCESS IS CARRIED OUT CONTINUOUSLY AND THE REACTION TEMPERATURE IS MAINTAINED AND CONTROLLED BY REGULATING THE RATE OF ADDITION OF THE REACTANTS. THE RESULTING VANADIUM OXYTRICHLORIDE IS VOLATILIZED AT A TEMPERATURE OF ABOUT 150*C. AND IS THEREAFTER CONDENSED.

公开(公告)号：US3682828A

公开(公告)日：1972-08-08

申请号：US3682828D

申请日：1970-06-22

Applicant: DYNAMIT NOBEL AG

Inventor： KEDDEINIS HEINRICH ,  LENZ ARNOLD ,  BLEH OTTO ,  TERMIN ERICH

IPC: C04B35/03 ,  H01B3/00 ,  H01B3/02 ,  H05B3/18 ,  H01B3/10 ,  H01B7/00 ,  H05B3/60

CPC classification number: H05B3/18 ,  C04B35/03 ,  H01B3/006 ,  H01B3/025

Abstract: AN ELECTRICAL INSULATING MATERIAL CONSISTS ESSENTIALLY OF: (1) A SINTERED MAGNESIA OF AT LEAST 94 WEIGHT PERCENT PURITY, AND (2) 0.1 TO 7 WEIGHT PERCENT OF A SILICA GEL HAVING A SPECIFIC SURFACE AREA IN THE RANGE OF 50 TO 1100 M.2/G., AND A SIZE LESS THAN 370U, PREFERABLY LESS THAN 70U. THIS INSULATING MATERIAL IS PARTICULARLY USEFUL IN THE MANUFACTURE OF TUBULAR HEATING COILS AND INSULATORS.

公开(公告)号：US3674716A

公开(公告)日：1972-07-04

申请号：US3674716D

申请日：1970-04-27

Applicant: DYNAMIT NOBEL AG

Inventor： DIJKHUIZEN WILLEM ,  TERMIN ERICH ,  BLEH OTTO ,  MORGENSTERN DIETER

IPC: C08G18/22 ,  C08G22/04 ,  C08G22/44

CPC classification number: C08G18/222

Abstract: In the manufacture of a polyurethane by the reaction of a polyol with a polyisocyanate in the presence of a catalyst and in the absence of water, the catalyst used is an organic vanadium compound, preferably a vanadium or vanadyl alcoholate or phenolate, having the formula: (Y)mV(YR)a 2m WHEREIN: V is a vanadium atom Y is an oxygen or sulfur atom R is an organic radical, which can be alike or different if the molecule contains more than one A IS 4 OR 5 M IS 0 OR 1 WHEN A IS 4, AND 1 WHEN A IS 5.

公开(公告)号：US3657361A

公开(公告)日：1972-04-18

申请号：US3657361D

申请日：1969-10-30

Applicant: DYNAMIT NOBEL AG

Inventor： LENZ ARNOLD ,  BLEH OTTO ,  TERMIN ERICH

IPC: C07C29/70 ,  C07C31/30 ,  C07C43/04

CPC classification number: C07C31/30 ,  C07C29/70

Abstract: COMPOUNDS OF THE FORMULA MG(OR)2-(ROH)N ARE PREPARED BY FIRST PRETREATING THE ALCOHOL, ROH, WITH THE ORTHOFORMIC ACID ESTER OF THAT ALCOHOL, AND THEN REACTING METALLIC MAGNESIUM WITH THE PRETREATED ALCOHOL, P-TOLUENESULFONIC ACID MAY ADDITIONALLY BE USED TO PRETREAT THE ALCOHOL.