Dialkali salts of orthosilicic acid diesters and their preparation
    1.
    发明授权
    Dialkali salts of orthosilicic acid diesters and their preparation 失效
    DIALKALI酸性硅酸盐及其制备方法

    公开(公告)号:US3679724A

    公开(公告)日:1972-07-25

    申请号:US3679724D

    申请日:1970-10-27

    CPC classification number: C07F7/04

    Abstract: Dialkali salts of orthosilicic acid diesters, e.g. disodium orthosilicic acid dimethyl ester, are obtained by reaction of an alkali hydroxide with an orthosilicic acid tetraester. The dialkali salts of orthosilicic acid diesters are useful products for surface treatment of glass plates or glass fibers by tackling or etching.

    Abstract translation: 正硅酸二酯的Dialkali盐,例如 正硅酸二钠二钠是通过碱金属氢氧化物与正硅酸四酯的反应获得的。 正硅酸二酯的二盐是通过处理或蚀刻对玻璃板或玻璃纤维进行表面处理的有用产品。

    Production of potassium titanyl oxalate
    2.
    发明授权
    Production of potassium titanyl oxalate 失效
    钛酸钾的生产

    公开(公告)号:US3699137A

    公开(公告)日:1972-10-17

    申请号:US3699137D

    申请日:1970-12-08

    CPC classification number: C07F7/006

    Abstract: Process for the production of potassium titanyl oxalate which comprises heating a tetraalkyl titanate with about three times the molar amount of water and twice the molar amount of potassium hydrogen oxalate. If desired, two thirds of the water is added initially and the balance subsequently. A solvent such as an alkanol may be employed. Advantageously the reaction, distillation of volatiles, crystallization and drying are all performed in the same vessel.

    Abstract translation: 用于生产草酸氧钛钾的方法,其包括用约三倍摩尔量的水和两倍于草酸氢钾的摩尔量加热钛酸四烷基酯。 如果需要,最初加入三分之二的水,然后平衡。 可以使用溶剂如链烷醇。 有利的是,挥发物的反应,蒸馏,结晶和干燥都在相同的容器中进行。

    Process for the preparation of phosphorus-containing compounds
    3.
    发明授权
    Process for the preparation of phosphorus-containing compounds 失效
    含磷化合物的制备方法

    公开(公告)号:US3927151A

    公开(公告)日:1975-12-16

    申请号:US32879973

    申请日:1973-02-01

    Abstract: Phosphorus-containing compounds, especially alkyl phosphates, of the formula
    wherein A is oxygen or sulfur, g and n are 0 or 1, and R1, R2 and R3, which may be the same or different, are alkyl, cycloalkyl or aryl wherein R1 may be substituted with one or more halogen atoms; are formed from the corresponding halo- or halo-alkoxyphosphorus compounds and a hydroxy-containing organic compound by reaction therebetween under gradual increase of temperature and simultaneous decrease in pressure, over an organo oxy compound catalyst comprising an element of Group II, IV or V of the Periodic System having an atomic number of between 12 and 83, in amounts of from 0.001 to 2 per cent by weight, based on the amount of starting phosphorus compound reactant.

    Abstract translation: 含有磷的化合物,特别是烷基磷酸酯,其通式为R 1 - (O)n | R2-O-P =(A)q | R3-O其中A为氧或硫,g和n为0或 1,R 1,R 2和R 3可以相同或不同,为烷基,环烷基或芳基,其中R 1可被一个或多个卤素原子取代; 由相应的卤代或卤代 - 烷氧基 - 磷化合物和含羟基的有机化合物通过在逐渐升高的温度下同时降低压力而相对于包含II,IV族元素的有机氧化合物催化剂而形成, 基于起始磷化合物反应物的量,周期性体系的V为原子序数为12至83,其量为0.001至2重量%。

    Vanadium oxytrialcoholates
    4.
    发明授权
    Vanadium oxytrialcoholates 失效
    VANADIUM OXYTRIALCOLOLATES

    公开(公告)号:US3652617A

    公开(公告)日:1972-03-28

    申请号:US3652617D

    申请日:1969-12-09

    CPC classification number: C07F9/005

    Abstract: PREPARATION OF ALCOHOLATES OF ORTHOVANADIC ACID, CALLED VANADIUM OXY ESTERS OR VANDYL ESTERS, HAVING THE GENERAL FORMULA:

    VO(OR)3

    IN WHICH R REPRESENTS ALKYL OR CYCLOALKYL RADICALS, ESPECIALLY THOSE HAVING 1 TO 5 CARBON ATOMS IN THE ALKYL RADICAL, BY THE REACTION OF VANADIUM PENTOXIDE WITH ANHYDROUS ALCOHOLS.

    Manufacture of polyurethanes using organic zirconium compounds as catalysts
    6.
    发明授权
    Manufacture of polyurethanes using organic zirconium compounds as catalysts 失效
    使用有机ZIRCONIUM化合物作为催化剂制备聚氨酯

    公开(公告)号:US3673159A

    公开(公告)日:1972-06-27

    申请号:US3673159D

    申请日:1970-05-11

    CPC classification number: C08G18/0885 C08G18/222

    Abstract: In the manufacture of a polyurethane by the reaction of a polyol with a polyisocyanate in the presence of a catalyst and in the absence of water, the catalyst used is an organic zirconium compound, preferably a zirconium alcoholate or phenolate, having the formula: (Y)mZr(YR)4 2m WHEREIN: Zr is a zirconium atom Y is an oxygen or sulfur atom R is an organic radical of up to 12 carbon atoms, which can be alike or different M IS 0 OR 1.

    Abstract translation: 在通过多元醇与多异氰酸酯在催化剂存在下和不存在水的情况下反应制备聚氨酯时,所用的催化剂是具有下式的有机锆化合物,优选醇锆或酚盐,具有下式:(Y )mZr(YR)4-2mWHEEIN:

    Production of vanadium oxytrichloride
    7.
    发明授权
    Production of vanadium oxytrichloride 失效
    生产氧化亚铁(VANADIUM OXYTRICHLORIDE)

    公开(公告)号:US3684433A

    公开(公告)日:1972-08-15

    申请号:US3684433D

    申请日:1970-07-22

    CPC classification number: C01G31/04

    Abstract: IN THE PRODUCTION OF VANADIUM OXYTRICHLORIDE WHEREIN VANADIUM PENTOXID, CARBON AND CHLORINE ARE REACTED, THE IMPROVEMENT WHICH COMPRISES EFFECTING THE REACTION BY CONTACTING A MIXTURE OF FINE-GRAINED VANADIUM PENTOXIDE AND CARBON IN THE FORM OF A GAS PERMEABLE LAYER ABOUT 0.5 TO 20 CM. HIGH WITH CHLORINE AT A TEMPERATURE OF ABOUT 350 TO 750*C. PREFERABLY THE PROCESS IS CARRIED OUT CONTINUOUSLY AND THE REACTION TEMPERATURE IS MAINTAINED AND CONTROLLED BY REGULATING THE RATE OF ADDITION OF THE REACTANTS. THE RESULTING VANADIUM OXYTRICHLORIDE IS VOLATILIZED AT A TEMPERATURE OF ABOUT 150*C. AND IS THEREAFTER CONDENSED.

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