公开(公告)号：US20070203366A1

公开(公告)日：2007-08-30

申请号：US11742863

申请日：2007-05-01

申请人： Daisuke SHIRAKAWA ,  Takashi Okazoe ,  Kazuya Oharu ,  Shu-zhong Wang ,  Koichi Murata ,  Kengo Kawahara

发明人： Daisuke SHIRAKAWA ,  Takashi Okazoe ,  Kazuya Oharu ,  Shu-zhong Wang ,  Koichi Murata ,  Kengo Kawahara

IPC分类号： C07C43/12

CPC分类号： C08G65/007 ,  C10M107/38 ,  C10M2213/043 ,  C10M2213/0606 ,  C10N2240/204

摘要： A novel perfluoropolyether derivative which is less likely to undergo decomposition, which is free from a problem of deterioration during its use, and which is useful as a lubricating oil or a coating agent, is provided. A compound represented by the following formula (1): HO—(CH2CH2O)r•(CH2CH(OH)CH2O)p—CH2CF2O(CF2CF2O)mCF2CH2O—(CH2CH(OH)CH2O)q•(CH2CH2O)s—H  Formula (1) wherein m represents an integer of from 3 to 200, and each of p, q, r and s which are independent of one another, represents an integer of from 0 to 100, provided that when each of p, q, r and s which are independent of one another, is an integer of at least 1, the arrangement of —(CH2CH2O)— and —(CH2CH(OH)CH2O)— units is not particularly limited, and when one of r and p is an integer of at least 2 and the other is an integer of at least 1, or when one of q and s is an integer of at least 2 and the other is an integer of at least 1, these units may be arranged in a block form or at random.

摘要翻译： 提供了一种不太可能分解的新型全氟聚醚衍生物，其在使用中没有劣化的问题，并且其可用作润滑油或涂层剂。 由下式（1）表示的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> HO-（CH 2 CH 2 （CH 2 CH（OH）CH 2 O）CH 2 CH（OH）CH 2 CH 2 2 CF 2 O 2（CF 2 CF 2 O）CF 2 O（CF 2 O 2 CF 2） 2 CH 2 CH 2 O - （CH 2 CH 2 OH（CH 2 OH）CH 2 O）q （CH 2 CH 2 CH 2）n -H（式（1））＆lt;线内公式描述=“在线式 “end =”tail“？>其中m表示3〜200的整数，彼此独立的p，q，r和s各自表示0〜100的整数，条件是， 彼此独立的p，q，r和s是至少为1的整数， - （CH 2 CH 2 CH 2 O） - 和 - （CH 2 CH（OH）CH 2 O） - 单元没有特别限制，当r和p中的一个为至少2的整数，另一个为 至少为1的整数，或者q和s之一的整数 至少为2的整数，另一个为至少为1的整数，这些单元可以以块形式或随机排列。

公开(公告)号：US20050197408A1

公开(公告)日：2005-09-08

申请号：US11107980

申请日：2005-04-18

申请人： Daisuke Shirakawa ,  Takashi Okazoe ,  Kazuya Oharu ,  Shu-zhong Wang ,  Koichi Murata ,  Kengo Kawahara

发明人： Daisuke Shirakawa ,  Takashi Okazoe ,  Kazuya Oharu ,  Shu-zhong Wang ,  Koichi Murata ,  Kengo Kawahara

IPC分类号： A61K31/08 ,  C08G65/00 ,  C10M107/38

CPC分类号： C08G65/007 ,  C10M107/38 ,  C10M2213/043 ,  C10M2213/0606 ,  C10N2240/204

摘要： A novel perfluoropolyether derivative which is less likely to undergo decomposition, which is free from a problem of deterioration during its use, and which is useful as a lubricating oil or a coating agent, is provided. A compound represented by the following formula (1): HO—(CH2CH2O)r.(CH2CH (OH)CH2O)p—CH2CF2O(CF2CF2O)mCF2CH2O——(CH2CH(OH)CH2O)q.(CH2CH2O)s—H  Formula (1) wherein m represents an integer of from 3 to 200, and each of p, q, r and s which are independent of one another, represents an integer of from 0 to 100, provided that when each of p, q, r and s which are independent of one another, is an integer of at least 1, the arrangement of —(CH2CH2O)— and —(CH2CH(OH)CH2O)— units is not particularly limited, and when one of r and p is an integer of at least 2 and the other is an integer of at least 1, or when one of q and s is an integer of at least 2 and the other is an integer of at least 1, these units may be arranged in a block form or at random.

摘要翻译： 提供了一种不太可能分解的新型全氟聚醚衍生物，其在使用中没有劣化的问题，并且其可用作润滑油或涂层剂。 由下式（1）表示的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> HO-（CH 2 CH 2 （CH 2 CH（OH）CH 2 O）CH 2 CH（OH）CH 2 CH 2 2 CF 2 O 2（CF 2 CF 2 O）CF 2 O（CF 2 O 2 CF 2） 2 CH 2 - （CH 2 CH（OH）CH 2 O）q 其中m表示3〜200的整数，p，q，r和s彼此独立地表示0〜100的整数，条件是每当 彼此独立的p，q，r和s的整数为至少1的整数， - （CH 2 CH 2 CH 2 O）的排列 - 和 - （CH 2 CH（OH）CH 2 O） - 单元没有特别限制，当r和p中的一个为至少2的整数，另一个为 是至少为1的整数，或者q和s之一的整数 是至少为2的整数，另一个是至少为1的整数，这些单元可以以块形式或随机排列。

公开(公告)号：US07388114B2

公开(公告)日：2008-06-17

申请号：US11742863

申请日：2007-05-01

申请人： Daisuke Shirakawa ,  Takashi Okazoe ,  Kazuya Oharu ,  Shu-zhong Wang ,  Koichi Murata ,  Kengo Kawahara

发明人： Daisuke Shirakawa ,  Takashi Okazoe ,  Kazuya Oharu ,  Shu-zhong Wang ,  Koichi Murata ,  Kengo Kawahara

IPC分类号： C07C43/12

CPC分类号： C08G65/007 ,  C10M107/38 ,  C10M2213/043 ,  C10M2213/0606 ,  C10N2240/204

摘要： A novel perfluoropolyether derivative which is less likely to undergo decomposition, which is free from a problem of deterioration during its use, and which is useful as a lubricating oil or a coating agent, is provided.A compound represented by the following formula (1): HO—(CH2CH2O)r. (CH2CH(OH)CH2O)p—CH2CF2O(CF2CF2O)mCF2CH2O——(CH2CH(OH)CH2O)q. (CH2CH2O)s—H   Formula (1) wherein m represents an integer of from 3 to 200, and each of p, q, r and s which are independent of one another, represents an integer of from 0 to 100, provided that when each of p, q, r and s which are independent of one another, is an integer of at least 1, the arrangement of —(CH2CH2O)— and —(CH2CH(OH)CH2O)— units is not particularly limited, and when one of r and p is an integer of at least 2 and the other is an integer of at least 1, or when one of q and s is an integer of at least 2 and the other is an integer of at least 1, these units may be arranged in a block form or at random.

摘要翻译： 提供了一种不太可能分解的新型全氟聚醚衍生物，其在使用中没有劣化的问题，并且其可用作润滑油或涂层剂。 由下式（1）表示的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> HO-（CH 2 CH 2 O）。 （CH 2 CH（OH）CH 2 O）CH 2 CH 2 CH 2， （CF 2 O 2 CF 2）O 2 CF 2 CH 2 CH 2 O - （CH 2 CH 2 OH（CH 2 OH）CH 2 O）q。 （CH 2 CH 2 CH 2）H（式（1））＆lt;线内公式描述=“在线式” 其中m表示3〜200的整数，p，q，r和s彼此独立地表示0〜100的整数，条件是当p ，彼此独立的q，r和s是至少为1的整数， - （CH 2 CH 2 CH 2 O） - 和 - （ CH 2 OH（OH）CH 2 O） - 单元没有特别限制，当r和p中的一个为至少2的整数，另一个为 至少为1的整数，或当q和s之一为至少2的整数，另一个为至少为1的整数时，这些单元可以以块形式或随机排列。

公开(公告)号：US07230140B2

公开(公告)日：2007-06-12

申请号：US11107980

申请日：2005-04-18

申请人： Daisuke Shirakawa ,  Takashi Okazoe ,  Kazuya Oharu ,  Shu-zhong Wang ,  Koichi Murata ,  Kengo Kawahara

发明人： Daisuke Shirakawa ,  Takashi Okazoe ,  Kazuya Oharu ,  Shu-zhong Wang ,  Koichi Murata ,  Kengo Kawahara

IPC分类号： C07C43/11

CPC分类号： C08G65/007 ,  C10M107/38 ,  C10M2213/043 ,  C10M2213/0606 ,  C10N2240/204

摘要： A novel perfluoropolyether derivative which is less likely to undergo decomposition, which is free from a problem of deterioration during its use, and which is useful as a lubricating oil or a coating agent, is provided.A compound represented by the following formula (1): HO—(CH2CH2O)r.(CH2CH(OH)CH2O)p—CH2CF2O(CF2CF2O)mCF2CH2O——(CH2CH(OH)CH2O)q.(CH2CH2O)s—H  Formula (1) wherein m represents an integer of from 3 to 200, and each of p, q, r and s which are independent of one another, represents an integer of from 0 to 100, provided that when each of p, q, r and s which are independent of one another, is an integer of at least 1, the arrangement of —(CH2CH2O)— and —(CH2CH(OH)CH2O)— units is not particularly limited, and when one of r and p is an integer of at least 2 and the other is an integer of at least 1, or when one of q and s is an integer of at least 2 and the other is an integer of at least 1, these units may be arranged in a block form or at random.

摘要翻译： 提供了一种不太可能分解的新型全氟聚醚衍生物，其在使用中没有劣化的问题，并且其可用作润滑油或涂层剂。 由下式（1）表示的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> HO-（CH 2 CH 2 （CH 2 CH（OH）CH 2 O）CH 2 CH（OH）CH 2 CH 2 2 CF 2 O 2（CF 2 CF 2 O）CF 2 O（CF 2 O 2 CF 2） 2 CH 2 - （CH 2 CH（OH）CH 2 O）q 其中m表示3〜200的整数，p，q，r和s彼此独立地表示0〜100的整数，条件是每当 彼此独立的p，q，r和s的整数为至少1的整数， - （CH 2 CH 2 CH 2 O）的排列 - 和 - （CH 2 CH（OH）CH 2 O） - 单元没有特别限制，当r和p中的一个为至少2的整数，另一个为 是至少为1的整数，或当q和s之一为整数时 至少为2的整数，另一个为至少为1的整数，这些单元可以以块形式或随机排列。

公开(公告)号：US20090176954A1

公开(公告)日：2009-07-09

申请号：US12091846

申请日：2006-10-25

申请人： Shu-zhong Wang ,  Koichi Murata ,  Kazuya Oharu ,  Yoshitomi Morizawa ,  Osamu Yokokoji ,  Naoko Shirota

发明人： Shu-zhong Wang ,  Koichi Murata ,  Kazuya Oharu ,  Yoshitomi Morizawa ,  Osamu Yokokoji ,  Naoko Shirota

IPC分类号： C08F18/20 ,  C07C17/361 ,  C07C29/36 ,  C07C67/14 ,  C07C31/44 ,  C07C69/65

CPC分类号： C07C31/44 ,  C07C17/361 ,  C07C23/38 ,  C07C29/38 ,  C07C67/14 ,  C07C69/653 ,  C07C2603/74 ,  C08F220/24

摘要： To provide a novel fluoroadamantane derivative, a novel polymerizable fluoroadamantane derivativeand a novel fluoropolymer, and processes for production thereof.To provide the following compound (3), the following compound (4), a polymer obtained by polymerizing the compound (4) and processes for production thereof: provided that Q represents —CHF— or —CF2— (provided that six Qs may be the same or different), Z represents —H, —F or —CH2OH (provided that three Zs may be the same or different), W represents —H or a C1-10 hydrocarbon group, R represents —H, —F, —CH3 or —CF3, and J represents —H, —F, —CHWOH or —CHWOCOCR═CH2 (provided that three Js may be the same or different).

摘要翻译： 提供新的氟金刚烷衍生物，新型聚合性氟金刚烷衍生物和新型含氟聚合物及其制备方法。 为了提供以下化合物（3），以下化合物（4），通过使化合物（4）聚合而得到的聚合物及其制造方法：Q表示-CHF-或-CF2-（只要6个Q可以 相同或不同），Z表示-H，-F或-CH 2 OH（条件是三个Z可以相同或不同），W表示-H或C1-10烃基，R表示-H，-F， - CH 3或-CF 3，并且J表示-H，-F，-CHWOH或-CHWOCOCR-CH 2（条件是三个可以相同或不同）。

公开(公告)号：US07649065B2

公开(公告)日：2010-01-19

申请号：US12091846

申请日：2006-10-25

申请人： Shu-zhong Wang ,  Koichi Murata ,  Kazuya Oharu ,  Yoshitomi Morizawa ,  Osamu Yokokoji ,  Naoko Shirota

发明人： Shu-zhong Wang ,  Koichi Murata ,  Kazuya Oharu ,  Yoshitomi Morizawa ,  Osamu Yokokoji ,  Naoko Shirota

IPC分类号： C08F18/20

CPC分类号： C07C31/44 ,  C07C17/361 ,  C07C23/38 ,  C07C29/38 ,  C07C67/14 ,  C07C69/653 ,  C07C2603/74 ,  C08F220/24

摘要： To provide a novel fluoroadamantane derivative, a novel polymerizable fluoroadamantane derivative and a novel fluoropolymer, and processes for production thereof. To provide the following compound (3), the following compound (4), a polymer obtained by polymerizing the compound (4) and processes for production thereof: provided that Q represents —CHF— or —CF2— (provided that six Qs may be the same or different), Z represents —H, —F or —CH2OH (provided that three Zs may be the same or different), W represents —H or a C1-10 hydrocarbon group, R represents —H, —F, —CH3 or —CF3, and J represents —H, —F, —CHWOH or —CHWOCOCR═CH2 (provided that three Js may be the same or different).

摘要翻译： 提供新的氟金刚烷衍生物，新型聚合性氟金刚烷衍生物和新型含氟聚合物及其制备方法。 为了提供以下化合物（3），以下化合物（4），通过使化合物（4）聚合而得到的聚合物及其制造方法：Q表示-CHF-或-CF2-（只要6个Q可以 相同或不同），Z表示-H，-F或-CH 2 OH（条件是三个Z可以相同或不同），W表示-H或C1-10烃基，R表示-H，-F， - CH 3或-CF 3，并且J表示-H，-F，-CHWOH或-CHWOCOCR-CH 2（条件是三个可以相同或不同）。

公开(公告)号：US20060111584A1

公开(公告)日：2006-05-25

申请号：US11318978

申请日：2005-12-28

申请人： Koichi Murata ,  Takashi Okazoe ,  Eisuke Murotani

发明人： Koichi Murata ,  Takashi Okazoe ,  Eisuke Murotani

IPC分类号： C07C309/78

CPC分类号： C07C303/02 ,  C07C303/22 ,  C07C309/84

摘要： The present invention provides a process for producing a fluorinated sulfonyl fluoride useful as e.g. a material for an ion exchange resin, and a novel chemical substance useful as an intermediate in the production process. That is, to provide a process comprising oxidizing Y—S—RA-E-RB by means of an oxidizing agent essentially containing a halogen atom to obtain XSO2—RA-E-RB, and in a case that X is a fluorine atom, reacting the compound with fluorine in a liquid phase as it is, and in a case that X is a halogen atom other than a fluorine atom, converting X into a fluorine atom, and then reacting the obtained compound with fluorine in a liquid phase to obtain FSO2—RAF-EF-RBF, and then decomposing it to obtain FSO2—RAF—COF (wherein RA is a bivalent organic group such as an alkylene group, RB is a monovalent organic group such as a perfluoroalkyl group, E is —CH2OCO—, Y is a monovalent organic group such as a cyano group or the like, X is a halogen atom, RAF is a bivalent organic group having RA fluorinated or the like, RBF is the same group as RB or the like, and EF is —CF2OCO—).

摘要翻译： 本发明提供了用于制备氟化磺酰氟的方法。 用于离子交换树脂的材料，以及可用作生产过程中的中间体的新型化学物质。 也就是说，提供一种方法，该方法包括通过基本上含有卤素原子的氧化剂氧化YSR A A - B B - 以获得XSO 2 - 在X为氟原子的情况下，使化合物与氟在液相中原样反应，并且在如下情况下： X是除氟原子以外的卤素原子，将X转化为氟原子，然后使所得化合物与氟在液相中反应，得到FSO 2 R AF AF / 然后将其分解，得到FSO 2 -R AF AFO-COF（ 其中R A是二价有机基团，例如亚烷基，R B是一价有机基团，例如全氟烷基，E是-CH 2， OCO-，Y为一价有机基团，例如氰基等，X为卤素原子，R AF为具有R A 2 O 2的二价有机基团 >氟化等，R BF P>与R B等基团相同，并且E F是-CF 2 OCO-）。

公开(公告)号：US20060106252A1

公开(公告)日：2006-05-18

申请号：US11322396

申请日：2006-01-03

申请人： Koichi Murata ,  Takashi Okazoe ,  Eisuke Murotani

发明人： Koichi Murata ,  Takashi Okazoe ,  Eisuke Murotani

IPC分类号： C07C309/80

CPC分类号： C07C303/16 ,  C07C303/22 ,  C07C309/82 ,  C07C309/84

摘要： It is an object of the present invention to solve difficulty in production and to provide a process to obtain fluorinated sulfonyl fluoride compound having various molecular structures efficiently at a low cost. That is, the present invention provides a process which comprises reacting (FSO2—)nRA(-E-RB)m (1F) with fluorine in a liquid phase to form (FSO2—)nRAF(-EF-RBF)m (2), and decomposing this compound to obtain (FSO2—)nRAF(-EF1)m (3), provided that RA is a (n+m)valent organic group having at least two carbon atoms, RAF is a group having RA fluorinated, or the like, each of RB and RBF is a fluorinated monovalent organic group, or the like, E is —COOCH2— or the like, EF is —COOCF2— or the like, EFl is —COF or the like, n is an integer of at least 2, and m is an integer of at least 1.

摘要翻译： 本发明的目的在于解决生产难题，提供以低成本有效地获得具有各种分子结构的氟化磺酰氟化合物的方法。 也就是说，本发明提供了一种方法，该方法包括使（FSO 2 - ） - （C 1 -C 6） （1F）与氟在液相中形成（FSO 2 - ）n R AF AF / （2），并分解该化合物，得到（FSO 2 （3），其中R 1，R 2，R 3，R 3，R 3， A是具有至少两个碳原子的（n + m）价有机基团，R AF是​​具有氟化A的基团等， R B和R B各自为氟化一价有机基团等，E为-COOCH 2 - 等，E F为-COOCF 2 - 等，E为FOF等，n为至少2的整数，以及 m是至少为1的整数。

公开(公告)号：US07781612B2

公开(公告)日：2010-08-24

申请号：US11318978

申请日：2005-12-28

申请人： Koichi Murata ,  Takashi Okazoe ,  Eisuke Murotani

发明人： Koichi Murata ,  Takashi Okazoe ,  Eisuke Murotani

IPC分类号： C07C303/02

CPC分类号： C07C303/02 ,  C07C303/22 ,  C07C309/84

摘要： The present invention provides a process for producing a fluorinated sulfonyl fluoride useful as e.g. a material for an ion exchange resin, and a novel chemical substance useful as an intermediate in the production process.That is, to provide a process comprising oxidizing Y—S—RA-E-RB by means of an oxidizing agent essentially containing a halogen atom to obtain XSO2—RA-E-RB, and in a case that X is a fluorine atom, reacting the compound with fluorine in a liquid phase as it is, and in a case that X is a halogen atom other than a fluorine atom, converting X into a fluorine atom, and then reacting the obtained compound with fluorine in a liquid phase to obtain FSO2—RAF-EF-RBF, and then decomposing it to obtain FSO2—RAF—COF (wherein RA is a bivalent organic group such as an alkylene group, RB is a monovalent organic group such as a perfluoroalkyl group, E is —CH2OCO—, Y is a monovalent organic group such as a cyano group or the like, X is a halogen atom, RAF is a bivalent organic group having RA fluorinated or the like, RBF is the same group as RB or the like, and EF is —CF2OCO—).

摘要翻译： 本发明提供了用于制备氟化磺酰氟的方法。 用于离子交换树脂的材料，以及可用作生产过程中的中间体的新型化学物质。 也就是说，提供一种方法，其包括通过基本上含有卤素原子的氧化剂氧化Y-S-RA-E-RB以获得XSO 2 -RA-E-RB，并且在X为氟原子的情况下， 在液相中使化合物与氟反应，在X是除氟原子以外的卤素原子的情况下，将X转化为氟原子，然后使所得化合物与氟进行液相反应，得到 FSO 2 -RAF-EF-RBF，然后分解，得到FSO 2 -RAF-COF（其中RA为亚烷基等二价有机基团，RB为全氟烷基等一价有机基团，E为-CH 2 OCO- Y为一价的有机基团，例如氰基等，X为卤素原子，RAF为具有RA氟化等的二价有机基团，RBF为与RB等相同的基团，EF为 - CF2OCO-）。

公开(公告)号：US07297815B2

公开(公告)日：2007-11-20

申请号：US11322396

申请日：2006-01-03

申请人： Koichi Murata ,  Takashi Okazoe ,  Eisuke Murotani

发明人： Koichi Murata ,  Takashi Okazoe ,  Eisuke Murotani

IPC分类号： C07C309/00

CPC分类号： C07C303/16 ,  C07C303/22 ,  C07C309/82 ,  C07C309/84

摘要： It is an object of the present invention to solve difficulty in production and to provide a process to obtain fluorinated sulfonyl fluoride compound having various molecular structures efficiently at a low cost.That is, the present invention provides a process which comprises reacting (FSO2—)nRA(-E-RB)m (1F) with fluorine in a liquid phase to form (FSO2—)nRAF(-EF-RBF)m (2), and decomposing this compound to obtain (FSO2—)nRAF(-EF1)m (3), provided that RA is a (n+m) valent organic group having at least two carbon atoms, RAF is a group having RA fluorinated, or the like, each of RB and RBF is a fluorinated monovalent organic group, or the like, E is —COOCH2— or the like, EF is —COOCF2— or the like, EF1 is —COF or the like, n is an integer of at least 2, and m is an integer of at least 1.

摘要翻译： 本发明的目的在于解决生产难题，提供以低成本有效地获得具有各种分子结构的氟化磺酰氟化合物的方法。 也就是说，本发明提供了一种方法，该方法包括使（FSO 2 - ） - （C 1 -C 6） （1F）与氟在液相中形成（FSO 2 - ）n R AF AF / （2），并分解该化合物，得到（FSO 2 （3），其中R 1，R 2，R 3，R 3，R 3， A是具有至少两个碳原子的（n + m）价有机基团，R AF是​​具有氟化A的基团等， R B和R B各自为氟化一价有机基团等，E为-COOCH 2 - 等，E F是-COOCF 2 - 等，E F1是-COF等，n是至少2的整数，以及 m是至少为1的整数。